Introduction It is believed that the basic physical building blocks forming the world we live in may be categorized into particles of matter and carriers of force between matter. All known elementary constituents of matter and transmitters of force are quantized. For example, energy, momentum, and angular momentum take on discrete quantized values. The electron is an example of an elementary particle of matter, and the photon is an example of a transmitter of force. Neutrons, protons, and atoms are composite particles made up of elementary particles of matter and transmitters of force. These composite particles are also quantized. Because classical mechanics is unable to explain quantization, we must learn quantum mechanics in order to understand the microscopic properties of atoms – which, for example, make up solids such as crystalline semiconductors. Historically, the laws of quantum mechanics have been established by experiment. The most important early experiments involved light. Long before it was realized that light waves are quantized into particles called photons, key experiments on the wave properties of light were performed. For example, it was established that the color of visible light is associated with different wavelengths of light. Table 2.1 shows the range of wavelengths corresponding to different colors. The connection between optical and electrical phenomena was established by Maxwell in 1864. This extended the concept of light to include the complete electromagnetic spectrum. A great deal of effort was, and continues to be, spent gathering information on the behavior of light.
Introduction It is believed that the basic physical building blocks forming the world we live in may be categorized into particles of matter and carriers of force between matter. All known elementary constituents of matter and transmitters of force are quantized. For example, energy, momentum, and angular momentum take on discrete quantized values. The electron is an example of an elementary particle of matter, and the photon is an example of a transmitter of force. Neutrons, protons, and atoms are composite particles made up of elementary particles of matter and transmitters of force. These composite particles are also quantized. Because classical mechanics is unable to explain quantization, we must learn quantum mechanics in order to understand the microscopic properties of atoms – which, for example, make up solids such as crystalline semiconductors. Historically, the laws of quantum mechanics have been established by experiment. The most important early experiments involved light. Long before it was realized that light waves are quantized into particles called photons, key experiments on the wave properties of light were performed. For example, it was established that the color of visible light is associated with different wavelengths of light. Table 2.1 shows the range of wavelengths corresponding to different colors. The connection between optical and electrical phenomena was established by Maxwell in 1864. This extended the concept of light to include the complete electromagnetic spectrum. A great deal of effort was, and continues to be, spent gathering information on the behavior of light.
Elementary particles are found in two different situations: (i) bound to metastable states of matter, for which angular momentum is quantized, and (ii) free, for which, due to their high energy-momentum and leaving aside inner a.m. or spin, the h-quantization step is completely harmless. Perhaps Quantum Mechanics can be seen just as the simplest mathematical formalism where angular momentum (the magnitude of each of its three orthogonal projections) is by construction quantized: all possible values are taken from a discrete set. Indeed: (i) This idea finds support in very reasonable, completely classical physical arguments, if we place ourselves in the framework of Stochastic Electrodynamics (SED): there, all sustained periodic movement of a charge must satisfy a power balance that restricts the value of the average angular momentum, on each of its projections. (ii) It gives a natural explanation of the concept of "photon", as a constraint on the observable spectrum of energy-momentum exchanges between metastable physical states, in particular also for its discreteness. QM would be, in this picture, a semi-static theory, transparent to all the (micro)-dynamics taking place between apparently "discrete" events (transitions in the state of the system). For instance, (the magnitude of the projections of) quantum angular momentum would only reflect average values over a (classical) cyclic trajectory, a fact that we regard as almost obvious given the particularity of the corresponding addition rules in QM.
The Quantum theory deals with the microscopic structure of the Universe that describes the finer details of nature at the subatomic domain.To a physicist, quantum mechanics is one of the three great pillars supporting our intuition of evocative, bewildering and fascinating natural World as we continuously struggle with the inescapable strangeness of the subatomic domain as if something strange is always afoot.It is well accepted fact that quantum mechanics is a physical theory that describes the way things behave at subatomic level which is quite dazzling in its precision and explanatory power.A test of quantum electrodynamics, the oldest and best understood of the modern quantum theory that involves measuring the way an electron behaves in the vicinity of a magnetic force. Many of the technological and social changes that have revolutionized our lives have actually risen out of the fundamental theoretical research carried out with only motivation to understand the World in a better way than ever. For example, the invention of transistor actually came with the fundamental theoretical research on the Uncertainty Principle which states that the uncertainty of the position of a particle times the uncertainty of its velocity is always a constant. If we double the certainty of the position of the particle, we have to make half the certainty of its velocity and vice versa. Quantum theory is perhaps the prime example of the infinitely esoteric in the sense that it describes a World in which a particle really can be in several places at once and it moves from one place to another by exploring the entire Universe simultaneously-the theory of simultaneity. The diverse and complex Universe is actually made of a few tiny particles according to the rules of quantum theory which is so simple that can be summarized on the back of an envelope. The more we understand about the elemental nature of the Universe, the simpler it looks. We have already discovered that everything in the diverse and complex Universe is nothing but the different assemblies of atoms, and the wide variety of atoms are constructed using the three building blocks at the sub-atomic domain i.e. subatomic particles: protons, neutrons and electrons. We have also discovered that protons and neutrons ate made up of combination of three entities called quarks. And that is where things stop as far as recent discovery is concerned. But the recent progress in particle physics inspiring the quest for the ultimate unified theory of physics that can describe everything in the Universe in one go. The discovery of Boson particle certainty will revolutionaries the Newton's mass concept and gravity into whole new looks. To an optimistic point of view, we must hope the best out of the progress in physics.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.
Classical mechanics, which gives a fairly accurate description of large systems (e.g., solar system) as also of mechanical systems in our every day life, however, breaks down when applied to small (microscopic) systems such as molecules, atoms and nuclei. For example, (1) classical mechanics cannot even explain why the atoms are stable at all. A classical atom with electrons moving in circular or elliptic orbits around the nucleus would continuously radiate energy in the form of electromagnetic radiation because an accelerated charge does radiate energy. As a result the radius of the orbit would become smaller and smaller, resulting in instability of the atom. On the other hand, the atoms are found to be remarkably stable in practice. (2) Another fact of observation that classical mechanics fails to explain is wave particle duality in radiation as well as in material particles. It is well known that light exhibits the phenomena of interference, diffraction and polarization which can be easily understood on the basis of wave aspect of radiation. But light also exhibits the phenomena of photo-electric effect, Compton effect and Raman effect which can only be understood in terms of corpuscular or quantum aspect of radiation. The dual behavior of light, or radiation cannot be consistently understood on the basis of classical concepts alone or explained away by saying that light behaves as wave or particle depending on the kind of experiment we do with it (complementarity). Moreover, a beam of material particles, like electrons and neutrons, demonstrates wave-like properties (e.g., diffraction). A brief outline of phenomena that require quantum mechanics for their understanding follows.
The first objective of this chapter is to briefly review some of the basic ideas about the structure of matter, in particular the concepts of microscopic physics, in order to recall the knowledge gained in previous physics (and chemistry) courses and make it more precise. Our review will be very concise, and most statements will be made without any proof or detailed discussion. A second objective is to give a brief description of some of the crucial stages in the early development of quantum physics. We shall not follow the strict historical order of this development or present the arguments used at the beginning of the last century by the founding fathers of quantum mechanics; rather, we shall stress the concepts which we shall find useful later on. Our last objective is to give an elementary introduction to some of the basic ideas, like those of a quantum particle or energy level, that will reappear throughout this text. We shall base our review on the Bohr theory, which provides a simple, though far from convincing, explanation of how energy levels are quantized and how the spectrum of the hydrogen atom arises. This chapter should be reread later on, once the basic ideas of quantum mechanics have been made explicit and illustrated by examples. From the practical point of view, it is possible to skip the general considerations of Sections 1.1 and 1.2 at the first reading and begin with Section 1.3, returning to those two sections later on as needed.
Quantum mechanics is a theory to explain and predict the behavior of particles such as electrons, protons, neutrons, atomic nuclei, atoms, and molecules, as well as the photon–the particle associated with electromagnetic radiation or light. From quantum theory we obtain the laws of chemistry as well as explanations for the properties of materials, such as crystals, semiconductors, superconductors, and superfluids. Applications of quantum behavior give us transistors, computer chips, lasers, and masers. The relatively new field of molecular biology, which leads to our better understanding of biological structures and life processes, derives from quantum considerations. Thus, quantum behavior encompasses a large fraction of modern science and technology. Quantum theory was developed during the first half of the twentieth century through the efforts of many scientists. In 1926, E. Schrödinger interjected wave mechanics into the array of ideas, equations, explanations, and theories that were prevalent at the time to explain the growing accumulation of observations of quantum phenomena. His theory introduced the wave function and the differential wave equation that it obeys. Schrödinger's wave mechanics is now the backbone of our current conceptional understanding and our mathematical procedures for the study of quantum phenomena. Our presentation of the basic principles of quantum mechanics is contained in the first three chapters. Chapter 1 begins with a treatment of plane waves and wave packets, which serves as background material for the subsequent discussion of the wave function for a free particle.