A particle of mass M moves in an infinite square well of width L (the “particle in a box”). Classically, the motion has period L2M/E, which depends on the initial condition through the energy E. Quantum mechanically, any wave function repeats exactly with period 4ML2/πℏ, independent of the initial condition. Given this qualitative difference, how can the classical motion possibly be the limit of the quantal time development? The resolution of this paradox involves the difference between the exact revival (recurrence) of the wave function and the approximate periodicity of expectation values such as 〈x(t)〉. (The latter may recur an odd integral number of times before the full wave function recurs.) The period of the expectation values does depend on the initial condition and can possess the expected classical limit. [An Appendix demonstrates that, under suitably quasiclassical conditions, the quantal time evolution of 〈x(t)〉 passes over to the classical result not only in period, but also in its exact functional form. Another Appendix proves four theorems concerning state-dependent exact revival times.]
A particle of mass M moves in an infinite square well of width L (the “particle in a box”). Classically, the motion has period L2M/E, which depends on the initial condition through the energy E. Quantum mechanically, any wave function repeats exactly with period 4ML2/πℏ, independent of the initial condition. Given this qualitative difference, how can the classical motion possibly be the limit of the quantal time development? The resolution of this paradox involves the difference between the exact revival (recurrence) of the wave function and the approximate periodicity of expectation values such as 〈x(t)〉. (The latter may recur an odd integral number of times before the full wave function recurs.) The period of the expectation values does depend on the initial condition and can possess the expected classical limit. [An Appendix demonstrates that, under suitably quasiclassical conditions, the quantal time evolution of 〈x(t)〉 passes over to the classical result not only in period, but also in its exact functional form. Another Appendix proves four theorems concerning state-dependent exact revival times.]
The temporal evolution of a wave packet ψ( x,t ) confined to an infinite square well (occupying the region 0 ≤ x ≤ L ), as manifested by fractional revivals of the probability density P ( x,t ) ≡ | ψ( x,t ) | 2 and the time-dependence of the expectation values of position, momentum and force ( X ( t ) ≡ ⟨ x ⟩ t , Π( t ) ≡ ⟨ ⟩ t and Φ( t ) ≡ ⟨ ⟩ t , respectively) are studied, using wave packets for which Π(0) = 0. In the region accessible to the wave packet (0 < x < L ), and the Hamiltonian Ĥ commute; still, is, in general, not a constant of the motion, and the three expectation values are all time-dependent, except when the initial packet has a definite parity, that is ψ( x ,0) = ±ψ( L - x , 0), which implies X ( t ) = L /2 and Π( t ) = 0 = Φ( t ). For a packet with no definite parity, Y ( t ) ≡ X ( t ) - L /2 stays, if the packet is sufficiently narrow at t = 0 close to zero nearly all the time, but executes large excursions in the neighbourhood of instants at which the probability density experiences a mirror revival or a revival. This behaviour, with no classical counterpart, can be understood by paying attention to the presence of infinite potential barriers (at x = 0 and x = L ) and taking account of the net force felt by an initially off-centred wave packet. It is shown that though plots (against time) of expectation values catch a glimpse of the revival structure of a wave packet, such plots fail to reveal some fractional revivals.
We describe the time evolution of a wave function in the infinite square well using a fractional revival formalism, and show that at all times the wave function can be described as a superposition of translated copies of the initial wave function. Using the model of a wave form propagating on a dispersionless string from classical mechanics to describe these translations, we connect the reflection symmetry of the square-well potential to a reflection symmetry in the locations of these translated copies, and show that they occur in a ``parity-conserving'' form. The relative phases of the translated copies are shown to depend quadratically on the translation distance along the classical path. We conclude that the time-evolved wave function in the infinite square well can be described in terms of translations of the initial wave-function shape, without approximation and without any reference to its energy eigenstate expansion. That is, the set of translated initial wave functions forms a Hilbert space basis for the time-evolved wave functions.
We examine the long-term time dependence of Gaussian wave packets in a circular infinite well (billiard) system and find that there are approximate revivals. For the special case of purely m=0 states (central wave packets with no momentum) the revival time is ${T}_{\mathrm{rev}}^{(m=0)}=8\ensuremath{\mu}{R}^{2}/\ensuremath{\Elzxh}\ensuremath{\pi},$ where $\ensuremath{\mu}$ is the mass of the particle, and the revivals are almost exact. For all other wave packets, we find that ${T}_{\mathrm{rev}}^{(m\ensuremath{\ne}0)}=({\ensuremath{\pi}}^{2}{/2)T}_{\mathrm{rev}}^{(m=0)}\ensuremath{\approx}{5T}_{\mathrm{rev}}^{(m=0)}$ and the nature of the revivals becomes increasingly approximate as the average angular momentum or number of $m\ensuremath{\ne}0$ states is increased. The dependence of the revival structure on the initial position, energy, and angular momentum of the wave packet and the connection to the energy spectrum is discussed in detail. The results are also compared to two other highly symmetrical two-dimensional infinite well geometries with exact revivals, namely, the square and equilateral triangle billiards. We also show explicitly how the classical periodicity for closed orbits in a circular billiard arises from the energy eigenvalue spectrum, using a WKB analysis.
Quantum revival phenomena, wherein the wave function of a quantum system periodically returns to its initial state after evolving in time, are investigated in this study. Focusing on electrons confined within a quantum box with an impurity, both weak- and strong-coupling regimes are explored, revealing intricate relationships between impurity parameters and temporal dynamics. This investigation considers the influence of impurity position, impurity strength, and external factors such as aluminum concentration, temperature and hydrostatic pressure on classical periods and revival times. Through analytical derivations and graphical analyses, this study elucidates the sensitivity of quantum revivals to these parameters, providing valuable insights into the fundamental aspects of quantum mechanics. While no specific physical applications are discussed, the findings offer implications for quantum heat engines and other quantum-based technologies, emphasizing the importance of understanding quantum revivals in confined quantum systems.
We present an analytical investigation of revival phenomena in the finite square-well potential. The classical motion, revival, and super-revival time scales are derived exactly for wave packets excited in the finite well. These time scales exhibit a richer dependence on wave-packet energy and on potential-well depth than has been found in other quantum systems: They explain, for example, the difficulties in exciting wave packets with strong classical features at the bottom of a finite well, or with clearly resolved super-revivals in a shallow well. In the proper regions of validity, the time scales predict the instances of wave-packet reformation extremely accurately. Revivals at the bottom of the well are explored as a ``universal'' limit of the general theory, which offers the clearest connection with the series of fractional and full revivals seen in the dynamics of the infinite square-well potential.
The rigid pendulum, both as a classical and as a quantum problem, is an interesting system as it has the exactly soluble harmonic oscillator and the rigid rotor systems as limiting cases in the low- and high-energy limits respectively. The energy variation of the classical periodicity (tau) is also dramatic, having the special limiting case of tautoinfty at the 'top' of the classical motion (i.e. the separatrix.) We study the time-dependence of the quantum pendulum problem, focusing on the behavior of both the (approximate) classical periodicity and especially the quantum revival and superrevival times, as encoded in the energy eigenvalue spectrum of the system. We provide approximate expressions for the energy eigenvalues in both the small and large quantum number limits, up to 4th order in perturbation theory, comparing these to existing handbook expansions for the characteristic values of the related Mathieu equation, obtained by other methods. We then use these approximations to probe the classical periodicity, as well as to extract information on the quantum revival and superrevival times. We find that while both the classical and quantum periodicities increase monotonically as one approaches the 'top' in energy, from either above or below, the revival times decrease from their low- and high-energy values until very near the separatrix where they increase to a large, but finite value.