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Canadian Journal of Physics

The experimental status on the question of a phase transition in spin glasses

Gwyn Williams

Published Oct 1, 1987• 4 citations
Publisher

Abstract

Following a brief introduction to spin-glass systems, the current status of experimental evidence on the occurrence of a phase transition is reviewed. Recent analyses of dynamical properties of spin glasses are discussed in terms of several model predictions, including the conclusion of a divergent relaxation time τ at a finite temperature, although with large, non-mean-field indices z and v. The role of regular terms (leading to corrections to scaling) in the nonlinear response are reviewed, stressing their influence on the evaluation of the susceptibility and order-parameter exponents γ′ and β′.

DOI
10.1139/p87-200

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Following a brief introduction to spin-glass systems, the current status of experimental evidence on the occurrence of a phase transition is reviewed. Recent analyses of dynamical properties of spin glasses are discussed in terms of several model predictions, including the conclusion of a divergent relaxation time τ at a finite temperature, although with large, non-mean-field indices z and v. The role of regular terms (leading to corrections to scaling) in the nonlinear response are reviewed, stressing their influence on the evaluation of the susceptibility and order-parameter exponents γ′ and β′.
A general phenomenological theory of spin-glasses is presented, which predicts the weak singularities (like cusps) of susceptibilities and specific heat near the transition point TSG and also predicts generally the divergence of the second derivative of the nonlinear susceptibility with respect to a magnetic field in zero field at TSG. A similar second derivative of specific heat is also shown to diverge at TSG except for the molecular field theory. Scaling equations of state for magnetization m and spin-glass order-parameter q are derived, which yield new scaling relations of critical exponents for m(T), q(T), χ0(T), C0(T) and the corresponding nonlinear quantities. These general results explain qualitatively very well the magnetic field dependence of magnetization and specific heat observed experimentally. A non-uniform phenomenological Hamiltonian is also proposed for the renormalization group approach, which yields the critical dimensionality dc = 6, as usual. Intermediate random statistics and real replica method are proposed. There is also presented an exactly soluble model showing a spin-glass like phase transition.
I present an analysis of the dynamic behavior of short-range Ising spin glasses observed in stochastic simulations. The time dependence of the order parameter q(t)=〈Sx{S}_{x}Sx​(0)Sx{S}_{x}Sx​(t)〉\ifmmode\bar\else\textasciimacron\fi{}---which is the same as that of the structure factor---and the time dependence of the related dynamic correlation functions have been recorded with good statistics and very long observation times. The spin-glass model with a symmetric distribution of discrete nearest-neighbor \ifmmode\pm\else\textpm\fi{}J interactions on a simple-cubic lattice was used. Simulations were performed with a special fast computer, allowing for the first-time investigation of the equilibrium dynamics for a wide range of temperatures (0.7\ensuremath{\le}kT/J\ensuremath{\le}5.0) and lattice sizes (83{8}^{3}83, 163{16}^{3}163, 323{32}^{3}323, and 643{64}^{3}643). I have found that the empirical formula q(t)=${\mathrm{ct}}^{\mathrm{\ensuremath{-}}x}$exp(-\ensuremath{\omega}${t}^{\ensuremath{\beta}}$) with temperature-dependent exponents x(T) and \ensuremath{\beta}(T) describes the decay very well at all temperatures above the spin-glass transition. In the spin-glass phase, only the algebraic decay q(t)=${\mathrm{ct}}^{\mathrm{\ensuremath{-}}x}$ could be observed, with different temperature dependences of the exponent x(T). The dynamic scaling hypothesis and finite-size scaling explain well the observed temperature and size dependence of the data, and the functional form of the correlation functions is com- patible with the scaling form if corrections to scaling are taken into account. The scaling behavior and the dynamic and static critical exponents found in my simulations are in reasonable agreement with recent experiments performed on insulating spin glasses, showing that despite its simplicity the discrete model of spin glasses analyzed in this work displays behavior similar to that seen in nature.
We investigate the balanced M=4M=4M=4, p=4p=4p=4 spin-glass model for a one-dimensional long-range proxy for the finite dimensional short-range ppp-spin glass model to examine the nature of the glass transition beyond mean-field theory. We perform large-scale Monte Carlo equilibrated simulations for both fully connected and power-law diluted versions of the model. The critical temperatures extracted from the finite-size scaling (FSS) analysis of spin-glass susceptibility are in good agreement with theoretical predictions for σ=0,0.25σ= 0, 0.25σ=0,0.25, and 0.55. For these values of the long-range exponent σσσ (which is the power of the decrease of the interactions between the spins with their separation), one might have expected that mean-field theory would provide a good description of the system. However, the spin-overlap distribution and the value of the λλλ-parameter do not provide numerical evidence for a one-step replica symmetry breaking (1RSB) phase transition. Instead, our results indicate a direct transition from the paramagnetic state to a full replica symmetry broken phase, with a renormalized value of λ≡ω2/ω1<1λ\equiv ω_2/ω_1 < 1λ≡ω2​/ω1​<1 suggesting a continuous FRSB transition, despite this ratio being equal to 2 at mean-field level. A value of λ>1λ> 1λ>1 is required for the discontinuous 1RSB transition. We argue that strong finite-size effects and closely spaced transition temperatures remove the expected 1RSB transition for the system sizes which we can study. For values of the exponent σ=0.85σ= 0.85σ=0.85, which roughly corresponds to a three dimensional system, we find that the renormalized value of λλλ is again less than 1, with no signs of either the 1RSB transition or the continuous FRSB transition, suggesting that the Kauzmann temperature TKT_KTK​ in three dimensions might be zero and the complete absence of phase transitions in structural glasses.
Spin glasses are the paradigm of complex systems. These materials present really slow dynamics. However, the nature of the spin glass phase in finite dimensional systems is still controversial. Different theories describing the low temperature phase have been proposed: droplet, replica symmetry breaking and chaotic pairs. We present analytical studies of critical properties of spin glasses, in particular, critical exponents at and below the phase transition, existence of a phase transition in a magnetic field, computation of the lower critical dimension (in presence/absence of a magnetic field). We also introduce some rigorous results based on the concept of metastate. Finally, we report some numerical results regarding the construction of the Aizenman-Wehr metastate, scaling of the correlation functions in the spin glass phase and existence of a phase transition in a field, confronting these results with the predictions of different theories.