The concept of ‘tunnelling time’ in the context of quantum particle tunnelling is reviewed. Various suggestions of linking the tunnelling dynamics with a characteristic time (real or complex) like the phase time, barrier interaction time (bounce time), presence time, etc. are analysed. A simple but fully quantal method of defining and estimating a real tunnelling time is examined in a variety of situations. The recently proposed idea of interpreting ‘tunnelling time’ as the cavity lifetime of a particle is also explored. We emphasize that proton or H-atom transfer reactions in double or triple wells offer systems in which the signature of the tunnelling time should be recognizable not just indirectly through the tunnelling splitting of spectral lines, but by following the relaxation dynamics of the subsystem that the proton or H atom leaves by tunnelling.
The concept of ‘tunnelling time’ in the context of quantum particle tunnelling is reviewed. Various suggestions of linking the tunnelling dynamics with a characteristic time (real or complex) like the phase time, barrier interaction time (bounce time), presence time, etc. are analysed. A simple but fully quantal method of defining and estimating a real tunnelling time is examined in a variety of situations. The recently proposed idea of interpreting ‘tunnelling time’ as the cavity lifetime of a particle is also explored. We emphasize that proton or H-atom transfer reactions in double or triple wells offer systems in which the signature of the tunnelling time should be recognizable not just indirectly through the tunnelling splitting of spectral lines, but by following the relaxation dynamics of the subsystem that the proton or H atom leaves by tunnelling.
The tunneling time of a particle through a given barrier is commonly defined in terms of “internal clocks” that effectively measure the interaction time with internal degrees of freedom of the barrier. It is known that this definition of the time scale for tunneling is not unique in the sense that it depends on the clock used to define it. For the case of resonance tunneling, a particular choice that in the limit of a high/broad square barrier yields the original result of Büttiker and Landauer ( Phys. Rev. Lett. 1982, 49, 1739) is correlated to the lifetime of the resonance state. This is illustrated for analytically solvable one-dimensional double barrier models and for a realistic model of electron tunneling through a static water barrier. The latter calculation constitutes a novel application of this concept to a 3-dimensional model, and the observed structure in the energy dependence of the computed traversal time reflects the existence of transient tunneling resonances associated with instantaneous water structures. These models, characterized by the existence of shape resonances in the barrier, make it possible to examine different internal clocks that were proposed for measuring tunneling times in situations where a “clock independent” intrinsic time scale (the resonance lifetime) for the tunneling time exists. It is argued that this time may be used in order to estimate the relative importance of dynamical barrier processes that affect the tunneling probability.
Quantum tunneling, a quintessential quantum phenomenon, challenges classical intuitions by allowing particles to pass through seemingly insurmountable barriers. This study delves into the intricate dynamics of electron tunneling, focusing on the critical role of sub-barrier interactions and complex time processes. Through a combination of experimental measurements and simulations based on Feynman’s path integral of complex time trajectories, we reveal that the sub-barrier potential interaction introduces an asymmetric electron wave packet probability distribution along the real time axis and a marked delay at the tunneling exit. The energy-dependent behavior of this delay in electronic tunneling agrees with that observed in the previous atomic tunneling studies, suggesting a universal mechanism underlying quantum tunneling across different scales. Our findings underscore the necessity of incorporating both the wave and particle aspects of quantum entities to fully comprehend tunneling dynamics, which holds promise for an intuitive interpretation of complex-number quantum processes.
Tunneling phenomenon is one of the wondrous events that take place particularly in quantum mechanics and it has no counterpart in classical physics. We focus on its two important implications : tunneling time and tunneling probability. There has been no consensus on tunneling times among the tunneling time community for last seven decades. So far, most of the attempts to calculate tunneling times have apparently been centered on a simple rectangular barrier example. We implement the tunneling times with the most widely accepted approach, which is using physical Larmor clock, into a nonsymmetrical barrier and a double barrier. It results in different and unique insights into the usual understanding of tunneling time. Three characteristics tunneling time expressions are thoroughly studied in these quantum structures. The difference between dwell time and phase-delay time is once again approved. The unique characteristics of the phase-delay time, which was thought to be exactly similar to dwell time when we assign higher energies to the particles, is also revealed in the nonsymmetrical barrier that it should actually be regarded as a distinct feature from the dwell time. The singularity of reflection time in rectangular barrier is no longer valid in nonsymmetrical barrier. The finiteness of reflection time fairly shows that different quantum structures might bear some taboo breaking results. Since a double barrier involves much more complicated features and calculations, the calculation of tunneling times under this barrier is praiseworthy. The dwell time is the most crucial, troublesome and distinctive tunneling time element to look into for a double barrier. Besides the dwell and phase-delay time, we also calculate the three characteristic times as well as the reflection time for a double barrier. Another area that we study within the context of tunneling phenomenon is the tunneling probability. Recently, there has been ground shaking attempts in modifying the conventional WKB formulae. We follow one of the modified versions of WKB formulae in order to be able to calculate the tunneling probability through different quantum structures where conventional WKB formulae fail. These generalized WKB connection formulae are applied to some complex quantum potentials by seeking aid from the Green's function and the path integral approach. One of the biggest problems in quantum mechanics (visualization) is partially overcome through implementing the method of diagrammatic representations that make the life easier in understanding the events happening in the quantum world when we attempt to calculate the transmission and reflection probabilities. This part therefore has a pedagogical sense too in terms of interpreting the results in a diagrammatic way with the help of the path integral approach.
Introduction In classical physics it is meaningful to ask the question, ‘How much time does a particle take to pass through a given region?’ The interesting question in quantum mechanics is: does a particle take a definite time to tunnel through a classically forbidden region? The question has been debated ever since the idea that there was such a time in quantum theory was first put forward by MacColl way back in 1932 [253]. A plethora of times has since then been proposed, and the answer seems to depend on the interpretation of quantum mechanics one uses. A reliable answer is clearly of great importance for the design of high-frequency quantum devices, tunnelling phenomena (as, for example, in scanning tunneling microscopy), nuclear and chemical reactions and, of course, for purely conceptual reasons. Most of the controversies centre around simple and intuitive notions in idealized one-dimensional models in a scattering configuration in which a particle (usually represented by a wave packet) is incident on a potential barrier localized in the interval [ a, b ]. Three kinds of time have been defined in this context. One, called the transmission time τ T ( a, b ), is the average time spent within the barrier region by the particles that are eventually transmitted. Similarly, the reflection time τ R ( a, b ) is the average time spent within the barrier region by the particles that are eventually reflected.
The precise definition and physical interpretation of a tunneling time is a fundamental problem in quantum mechanics. The lack of a well-defined time operator in quantum theory precludes the calculation of time in terms of an expectation value. Consequently, model calculations and simulation studies have been proposed and used to determine the time for a particle to traverse a quantum-mechanical barrier. The results offer both qualitatively and quantitatively, disparate predictions. One of the more commonly used approaches is the phase method, which we have applied to several one-dimensional model potentials to show that the tunneling time is characterized by the ratio of the typical decay length in the barrier to the incident velocity, τ∼(1/κ)/v0. We also show that the phase and the spin precession methods are equivalent when the magnetic field is applied throughout the space containing the particle wave function and the tunneling barrier. In principle, the spin precession method can be regarded as an operational definition of the tunneling time. It also has been shown that a tunneling time can be defined operationally for a time-dependent barrier, for which the model calculations predict a tunneling time given by the mean barrier width divided by the magnitude of the imaginary velocity of the particle in the barrier, τ∼d/‖v‖. This pseudokinematic result has been inferred by magnetic field dependent tunneling through heterostructures and computer simulation of wave packet tunneling through one-dimensional square barriers. Other tunneling time theories predict one or the other of the above mentioned characteristic times; several theories predict both. We interpret these different results for τ to mean that a tunneling time is not uniquely defined as a function of particle energy and the barrier shape unless the process in which the tunneling is involved is also specified. That is, the tunneling time is a meaningful and unique concept only for particular tunneling processes or definite operational procedures.
The tunneling time of particle through given barrier is commonly defined in terms of "internal clocks" which effectively measure the interaction time with internal degrees of freedom of the barrier. It is known that this definition of the time scale for tunneling is not unique in the sense that it depends on the clock used to define it. For the case of resonance tunneling, a particular choice that in the limit of a high/broad square barrier yields the original result of Buttiker and Landauer (Phys. Rev. Lett. 1982, 49, 1739) is correlated to the lifetime of the resonance state. This is illustrated for analytically solvable one-dimensional double barrier models and for a realistic model of electron tunneling through a static water barrier. The latter calculation constitutes a novel application of this concept to a 3-dimensional model, and the observed structure in the energy dependence of the computed traversal time reflects the existence of transient tunneling resonances associated with instantaneous water structures. These models, characterized by the existence of shape resonances in the barrier, make it possible to examine different internal clocks that were proposed for measuring tunneling times in situations where a "clock independent" intrinsic time scale (the resonance life time) for the tunneling time exists. It is argued that this time may be used in order to estimate the relative importance of dynamical barrier processes that affect the tunneling probability.