Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

International Journal of Quantum Chemistry

Second quantization for composite particles, reactive collisions, and unstable particles

Marvin D. Girardeau

Published Jan 1, 1980• 32 citations
Publisher

Abstract

Abstract The salient features of generalized second‐quantization representations for nonrelativistic systems of composite particles are reviewed and their application to a reformulation of the quantum theory of reactive collisions is discussed. Such representations allow the properties of the bound composite states to be built explicitly into the algebra of states and observables. A single unperturbed Hamiltonian simultaneously describes the free propagation of the various species of bound composites as well as of their unbound constituents, while the interaction Hamiltonian describes only true scattering and reaction processes. The inclusion of the binding of all composites in the unperturbed Hamiltonian cures the divergences in the Born series arising from bound‐state poles. Unstable composites can be included in a natural way, leading to an explicit representation for the kinematics and dynamics of their decay and their contribution to collision phenomena.

DOI
10.1002/qua.560170103

Related papers

Second-quantization representation for a nonrelativistic system of composite particles. I. Generalized Tani transformation and its iterative evaluation

Marvin D. Girardeau

A method of constructing ’’atomic second quantization’’ representations is described, based on the introduction of redundant modes (’’ideal atom variables’’) which are then given physical content by carrying out a suitable unitary transformation, the ’’generalized Tani transformation.’’ In such a representation bound atoms or molecules are described by elementary Bose or Fermi operators, the field operators for nuclei and electrons referring only to unbound particles. The Hamiltonian thus obtained contains not only nucleus–nucleus, electron–electron, and nucleus–electron Coulomb interactions, but also atom–atom, atom–nucleus, and atom–electron Coulomb and exchange interactions, including breakup and recombination terms. All possible scattering and reaction channels are exhibited simultaneously in this transformed Hamiltonian. The method is applicable to any species or mixture of species of composite particles, but for simplicity the derivation is restricted here to the case of atomic hydrogen.

Journal of Mathematical Physics•Sep 1, 1975•71 citations

Second-quantization representation for a nonrelativistic system of composite particles. II. Kinematical properties of the multispecies Tani transformation

Marvin D. Girardeau

In previous publications a first-principles method was developed for constructing second-quantization representations for systems of composite bound states and their constituents. It is based on the introduction of redundant modes (’’ideal atom variables’’) which are given physical content by carrying out a suitable unitary transformation. A single transformed Hamiltonian explicitly and simultaneously exhibits all kinematically possible scattering and reaction channels. Most of the previous results were limited to the case of two fermion composites. This restriction is removed herein, in order to allow a first-principles approach to the many-particle quantum dynamics and statistics of chemical and nuclear reactions. The kinematical aspects of the relevant transformation are examined.

Journal of Mathematical Physics•Dec 1, 1978•16 citations

Idealization Second Quantization of Composite Particles

Zhou Duan-Lu, Yu Si-Xia, Sun Chang-Pu

A practical method is developed to deal with the second quantization of the many-body system containing the composite particles.In our treatment,the modes associated with composite particles are regarded approximately as independent ones compared with those of unbound particles.The field operators of the composite particles thus arise naturally in the second quantization Hamiltonian.To be emphasized,the second quantization Hamiltonian has the regular structures which correspond clearly to different physical processes.

arXiv:quant-ph/0012080•Communications in Theoretical Physics•Nov 15, 2001•2 citations

Second-quantized representation for a model system with composite particles

J. Gilbert

A second-quantized representation for nonrelativistic systems with composite particles is given in which composite particles of two-fermion constituents are described as elementary bosons. The Tani transformation of Girardeau is used to introduce elementary composite fields. An equivalent linear equation of motion method—introducing a ’’d matrix’’—is used in place of the usual nonlinear equation of motion method. This and a diagram formalism are developed to calculate a Hamiltonian and subsidiary condition for this model system and to derive some properties of the Tani transformation.

Journal of Mathematical Physics•Apr 1, 1977•29 citations

EXTENDED QUANTUM MECHANICS

B Pavel

The work can be considered as an essay on mathematical and conceptual structure of nonrelativistic quantum mechanics (QM) which is related here to some other (more general, but also to more special and “approximative”) theories. QM is here primarily reformulated in an equivalent form of a Poisson system on the phase space consisting of density matrices, where the “observables”, as well as “symmetry generators” are represented by a specific type of real valued (densely defined) functions, namely the usual quantum expectations of corresponding selfadjoint operators. It is shown in this paper that inclusion of additional (“nonlinear”) symmetry generators (i.e. “Hamiltonians”) into this reformulation of (linear) QM leads to a considerable extension of the theory: two kinds of quantum “mixed states” should be distinguished, and operator ‐ valued functions of density matrices should be used in the r ˆ ole of “nonlinear observables”. A general framework for physical theories is obtained in this way: By different choices of the sets of “nonlinear observables” we obtain, as special cases, e.g. classical mechanics on homogeneous spaces of kinematical symmetry groups, standard (linear) QM, or nonlinear extensions of QM; also various “quasiclassical approximations” to QM are all subtheories of the presented extension of QM - a version of the extended quantum mechanics (EQM). A general interpretation scheme of EQM extending the usual statistical interpretation of QM is also proposed. Eventually, EQM is shown to be (included into) a C -algebraic (hence linear) quantum theory. Mathematical formulation of these theories is presented. The presentation includes an analysis of problems connected with differentiation on infinite ‐ dimensional manifolds, as well as a solution of some problems connected with the work with only densely defined unbounded real‐valued functions on the (infinite dimensional) “phase space” which correspond to unbounded operators (generators) and to their nonlinear generalizations. Also “nonlinear deformations” of unitary representations of kinematical symmetry Lie groups are introduced. Possible applications are briefly discussed, and some specific examples are presented. The text contains also brief reviews of Hamiltonian classical mechanics, as well as of QM. Mathematical appendices make the paper nearly selfcontained.

•Jan 1, 2000•18 citations

Formulation of the Many-Body Problem for Composite Particles

Marvin D. Girardeau

The many-body problem for a system of composite particles is formulated in a way which takes explicit account of the composite nature of these particles and allows a clear separation between interatomic and intraatomic interactions. A second-quantization representation, fully equivalent to the conventional representation in which nuclei and electrons appear explicitly, is developed in terms of atomic annihilation and creation operators satisfying elementary Bose or Fermi commutation relations. All effects of the composite nature of the atoms are exactly contained in the interatomic and intraatomic matrix elements and in certain exchange integrals. An application is made to the problem of Bose condensation of fermion pairs.

Journal of Mathematical Physics•Aug 1, 1963•91 citations
Abstract The salient features of generalized second‐quantization representations for nonrelativistic systems of composite particles are reviewed and their application to a reformulation of the quantum theory of reactive collisions is discussed. Such representations allow the properties of the bound composite states to be built explicitly into the algebra of states and observables. A single unperturbed Hamiltonian simultaneously describes the free propagation of the various species of bound composites as well as of their unbound constituents, while the interaction Hamiltonian describes only true scattering and reaction processes. The inclusion of the binding of all composites in the unperturbed Hamiltonian cures the divergences in the Born series arising from bound‐state poles. Unstable composites can be included in a natural way, leading to an explicit representation for the kinematics and dynamics of their decay and their contribution to collision phenomena.
A method of constructing ’’atomic second quantization’’ representations is described, based on the introduction of redundant modes (’’ideal atom variables’’) which are then given physical content by carrying out a suitable unitary transformation, the ’’generalized Tani transformation.’’ In such a representation bound atoms or molecules are described by elementary Bose or Fermi operators, the field operators for nuclei and electrons referring only to unbound particles. The Hamiltonian thus obtained contains not only nucleus–nucleus, electron–electron, and nucleus–electron Coulomb interactions, but also atom–atom, atom–nucleus, and atom–electron Coulomb and exchange interactions, including breakup and recombination terms. All possible scattering and reaction channels are exhibited simultaneously in this transformed Hamiltonian. The method is applicable to any species or mixture of species of composite particles, but for simplicity the derivation is restricted here to the case of atomic hydrogen.
In previous publications a first-principles method was developed for constructing second-quantization representations for systems of composite bound states and their constituents. It is based on the introduction of redundant modes (’’ideal atom variables’’) which are given physical content by carrying out a suitable unitary transformation. A single transformed Hamiltonian explicitly and simultaneously exhibits all kinematically possible scattering and reaction channels. Most of the previous results were limited to the case of two fermion composites. This restriction is removed herein, in order to allow a first-principles approach to the many-particle quantum dynamics and statistics of chemical and nuclear reactions. The kinematical aspects of the relevant transformation are examined.
A practical method is developed to deal with the second quantization of the many-body system containing the composite particles.In our treatment,the modes associated with composite particles are regarded approximately as independent ones compared with those of unbound particles.The field operators of the composite particles thus arise naturally in the second quantization Hamiltonian.To be emphasized,the second quantization Hamiltonian has the regular structures which correspond clearly to different physical processes.
A second-quantized representation for nonrelativistic systems with composite particles is given in which composite particles of two-fermion constituents are described as elementary bosons. The Tani transformation of Girardeau is used to introduce elementary composite fields. An equivalent linear equation of motion method—introducing a ’’d matrix’’—is used in place of the usual nonlinear equation of motion method. This and a diagram formalism are developed to calculate a Hamiltonian and subsidiary condition for this model system and to derive some properties of the Tani transformation.
The work can be considered as an essay on mathematical and conceptual structure of nonrelativistic quantum mechanics (QM) which is related here to some other (more general, but also to more special and “approximative”) theories. QM is here primarily reformulated in an equivalent form of a Poisson system on the phase space consisting of density matrices, where the “observables”, as well as “symmetry generators” are represented by a specific type of real valued (densely defined) functions, namely the usual quantum expectations of corresponding selfadjoint operators. It is shown in this paper that inclusion of additional (“nonlinear”) symmetry generators (i.e. “Hamiltonians”) into this reformulation of (linear) QM leads to a considerable extension of the theory: two kinds of quantum “mixed states” should be distinguished, and operator ‐ valued functions of density matrices should be used in the r ˆ ole of “nonlinear observables”. A general framework for physical theories is obtained in this way: By different choices of the sets of “nonlinear observables” we obtain, as special cases, e.g. classical mechanics on homogeneous spaces of kinematical symmetry groups, standard (linear) QM, or nonlinear extensions of QM; also various “quasiclassical approximations” to QM are all subtheories of the presented extension of QM - a version of the extended quantum mechanics (EQM). A general interpretation scheme of EQM extending the usual statistical interpretation of QM is also proposed. Eventually, EQM is shown to be (included into) a C -algebraic (hence linear) quantum theory. Mathematical formulation of these theories is presented. The presentation includes an analysis of problems connected with differentiation on infinite ‐ dimensional manifolds, as well as a solution of some problems connected with the work with only densely defined unbounded real‐valued functions on the (infinite dimensional) “phase space” which correspond to unbounded operators (generators) and to their nonlinear generalizations. Also “nonlinear deformations” of unitary representations of kinematical symmetry Lie groups are introduced. Possible applications are briefly discussed, and some specific examples are presented. The text contains also brief reviews of Hamiltonian classical mechanics, as well as of QM. Mathematical appendices make the paper nearly selfcontained.
The many-body problem for a system of composite particles is formulated in a way which takes explicit account of the composite nature of these particles and allows a clear separation between interatomic and intraatomic interactions. A second-quantization representation, fully equivalent to the conventional representation in which nuclei and electrons appear explicitly, is developed in terms of atomic annihilation and creation operators satisfying elementary Bose or Fermi commutation relations. All effects of the composite nature of the atoms are exactly contained in the interatomic and intraatomic matrix elements and in certain exchange integrals. An application is made to the problem of Bose condensation of fermion pairs.