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American Journal of Physics

Visualizing the solutions for the circular infinite well in quantum and classical mechanics

Richard W. Robinett

Published Apr 1, 1996• 56 citations
Publisher

Abstract

The classical and quantum mechanical problem of a particle in the infinite circular well has recently surfaced in two quite different manifestations: (i) the observation of ‘‘electron standing waves’’ in circular ‘‘corrals’’ of atoms adsorbed on surfaces and (ii) as a benchmark example of an integrable system for comparison to the classical and quantum chaotic behavior of the ‘‘stadium billiards’’ problem. Motivated by this, we review the quantum and classical probability distributions for both position and momentum for this familiar problem, focusing on the visualization of the quantum wave functions and classical trajectories as well as the semiclassical connections between the two.

DOI
10.1119/1.18188

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The classical and quantum mechanical problem of a particle in the infinite circular well has recently surfaced in two quite different manifestations: (i) the observation of ‘‘electron standing waves’’ in circular ‘‘corrals’’ of atoms adsorbed on surfaces and (ii) as a benchmark example of an integrable system for comparison to the classical and quantum chaotic behavior of the ‘‘stadium billiards’’ problem. Motivated by this, we review the quantum and classical probability distributions for both position and momentum for this familiar problem, focusing on the visualization of the quantum wave functions and classical trajectories as well as the semiclassical connections between the two.
We examine the quantum mechanical eigensolutions of the two-dimensional infinite-well or quantum billiard system consisting of a circular boundary with an infinite barrier or baffle along a radius. Because of the change in boundary conditions, this system includes quantized angular momentum values corresponding to half-integral multiples of ℏ/2. We discuss the resulting energy eigenvalue spectrum and visualize some of the novel energy eigenstates found in this system. We also discuss the density of energy eigenvalues, N ( E ), comparing this system to the standard circular well. These two billiard geometries have the same area ( A = π R 2 ), but different perimeters ( P = 2π R versus (2π + 2) R ), and we compare both cases to fits of N ( E ) which make use of purely geometric arguments involving only A and P . We also point out connections between the angular solutions of this system and the familiar pedagogical example of the one-dimensional infinite-well plus δ-function potential.
After briefly reviewing the definitions of classical probability densities for position, P CL ( x ), and for momentum, P CL ( p ), we present several examples of classical mechanical potential systems, mostly variations on such familiar cases as the infinite well and the uniformly accelerated particle for which the classical distributions can be easily derived and visualized. We focus especially on a simple potential which interpolates between the symmetric linear potential, V ( x ) = F | x |, and the infinite well, which can illustrate, in a mathematically straightforward way, how the divergent δ-function classical probability density for momentum for the infinite well can be seen to arise. Such examples can help students understand the quantum mechanical momentum-space wavefunction (and its corresponding probability density) in much the same way that other semiclassical techniques, such as the WKB approximation, can be used to visualize position-space wavefunctions.
The semi-classical method has become a necessary instrument to study the classical movement of the particle.Periodic orbit theory is rapidly becoming one of most useful semi-classical tools which can be used to make direct connections between the quantized energy eigenvalues of a bound state and the classical motions for the corresponding point particle.We use a quantum spectral function which contain rich information of classical orbits in well.We study the correspondence between quantum spectra and classical orbits in the circular.Two-dimensional billiard systems have provided easily visualization examples relevant for both types of analyses.As a simple example of the application to a billiard or infinite well system of Periodic orbit theory,we compute the Fourier transform(ρL) of the quantum mechanical energy level density of two-dimensional circular billiard systems.The resulting peaks in plots of ρL2 versus L are compared to the lengths of the classical trajectories in these geometries.The locations of peaks in ρL agree with the lengths of classical orbits perfectly,which testifies the correspondence of quantum mechanics and classical mechanics.This examples show evidently that semi-classical methods provides a bridge between quantum and classical mechanics.
The Fourier transform of the density of quantized energy levels for a quantum mechanical particle in a two-dimensional (2-D) infinite well (or billiard geometry) is known to exhibit δ-function-like spikes at distance values (L) corresponding to the lengths of periodic orbits or closed trajectories. We show how these Fourier transforms can be rather easily calculated numerically for simple infinite well geometries including the square and rectangular well in 2 D, the cubical well in three dimensions, as well as the circular infinite well (and variations) in two dimensions. Such calculations provide a novel, well-motivated, and relatively straightforward example of numerical Fourier transform techniques and make interesting connections between quantum energy levels and classical trajectories in a way which is seldom stressed in the undergraduate curriculum.
This paper examines the particle-in-a-box model as a simple but powerful example that highlights the fundamental differences between classical and quantum physics. In classical mechanics, a particle confined between two rigid walls moves with constant velocity and has a uniform probability of being found anywhere in the box; its energy can take any continuous value. In contrast, solving the Schrödinger equation for an infinite potential well yields standing-wave solutions whose wavelengths must satisfy fixed boundary conditions. These constraints produce discrete, quantized energy levels and non-uniform probability distributions, features with no classical analog. Through analytical derivations and numerical simulations using Python, we visualize wave functions, probability densities, and the statistical convergence of random samples toward the theoretical quantum distributions. Comparisons with the classical uniform distribution emphasize how quantum mechanics replaces certainty with probability and continuity with quantization. Finally, we connect the model to real physical systems—such as electrons confined in atoms—to show how this idealized system provides essential insight into the structure and stability of matter.
The dynamics of a particle in square and circular billiards is studied within the framework of Bohm's quantum mechanics. While conventional quantum mechanics predicts that the system shows no indication of chaotic behavior for these geometries from either the eigenvalue spectra distribution or the structure of the eigenfunctions, we find that in Bohm's quantum mechanics these systems exhibit both regular and chaotic behavior, depending on the form of the initial wave packet and on the particle's initial position.