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Europhysics Letters (EPL)

Optical emission in periodic dielectrics

Rudolf Sprik, Bart A. van Tiggelen, Ad Lagendijk

Published Aug 1, 1996• 215 citations
Publisher

Abstract

We show rigorously that the coefficient for spontaneous emission of an atom placed in a dielectric is proportional to the local radiative density of states—that is only a part of the local density of the eigenmodes of the Maxwell equations. Spontaneous emission is inhibited if the atom is located at a position where this local radiative density is small, even if the total density of states is not vanishing. This radiative density of states can be obtained without having to perform a full quantum calculation of the radiation-matter system. We demonstrate this principle by solving numerically a scalar model for a dielectric that consists of a lattice of resonating dipoles.

DOI
10.1209/epl/i1996-00564-y

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We show rigorously that the coefficient for spontaneous emission of an atom placed in a dielectric is proportional to the local radiative density of states—that is only a part of the local density of the eigenmodes of the Maxwell equations. Spontaneous emission is inhibited if the atom is located at a position where this local radiative density is small, even if the total density of states is not vanishing. This radiative density of states can be obtained without having to perform a full quantum calculation of the radiation-matter system. We demonstrate this principle by solving numerically a scalar model for a dielectric that consists of a lattice of resonating dipoles.
We study the spontaneous emission of an atom embedded in a one-dimensional photonic crystal or superlattice using a classical electrodynamic theory of radiation. The rate of emission is a function of the frequency of the emitted photon, the dipole's position and orientation, as well as the geometric and material parameters of the superlattice. The emission spectrum shows an oscillatory behavior which follows the photonic band structure. For TE modes, there are frequency regions where radiative emission is completely prohibited due to the absence of modes with k//>omega/c; the radiation is then TM polarized. In addition to the radiative modes, there are always evanescent modes with k//>omega/c which are waveguided by the dielectric layers. The evanescent contribution to the spontaneous emission is dominant if a dielectric layer is in the near field region of the dipole. For TM modes, emission rates greatly vary for parallel and perpendicular dipole moments. In a photonic crystal with a high filling fraction of the dielectric and perpendicular dipoles located in the low-index layer, the decay rate can be as much as 76 times the free space value for a single atom and 50 times for a gas of atoms. We also find that the rate of emission presents a strong dependence on the atom's position.
We consider the spontaneous emission in an absorbing medium by calculating the quantum flow of energy from an emitting atom. For this purpose, we extend the analysis by Power and Thirunamachandran of quantized Maxwell fields in the vicinity of an atom in the free space to a situation where the emitter is in a dielectric medium. We represent the quantum flow in terms of the non-equal time commutators involving electric and magnetic fields, as well as the local displacement field. The commutators are calculated applying a previously developed microscopic theory of quantization of radiation in dielectrics. Consequently, we derive from first principles the rate of spontaneous emission in an absorbing medium containing local field factors and other refractive contributions. The results support the previous introduction of the (virtual cavity) local field correction by Barnett et al on a phenomenological basis, as well as our previous approach in which the spontaneous emission is considered as a resonance energy transfer to the far-zone atoms. A distinctive feature of the present formalism is that it deals with the spontaneous emission directly by calculating the quantum flow from the emitting atom. Therefore, the method is free from divergences appearing in other approaches analysing the spontaneous decay in absorbing media.
Starting from a quantum Maxwell equation for the vector potential operator, we study the spontaneous emission properties of a two-level atom interacting with the electromagnetic field in a lossless and inhomogeneous dielectric structure and express the spontaneous emission rate, the external quantum efficiency, and the spontaneous emission factor in terms of the classical Green function of the dielectric structure. Comparing these results with the corresponding classical results, we show that the above quantities can be calculated from the radiation field of a classical dipole. Based on this correspondence, a numerical algorithm is developed to calculate the modification of spontaneous emission in microcavities. The line shape of the emission spectrum of the light source and the decay of the cavity resonant modes are automatically taken into account in this algorithm. The approximate expressions for the spontaneous emission rate and the spontaneous emission factor are discussed.
We have calculated the effect of material absorption on the rate of spontaneous emission by an embedded atom using a macroscopic Green-function approach and a microscopic Hamiltonian method that includes reservoir damping. When local field effects are neglected, the free-space emission rate is modified by the real part of the refractive index at the transition frequency of the embedded atom. Local field effects are introduced via a local field correction factor. This modification of the spontaneous emission rate generalizes a well-known result for transparent media and is of crucial importance in assessing the degree of inhibition of spontaneous emission for frequencies close to the resonances of the dielectric.
We present calculations of the rates of decay of an excited atom embedded in an absorbing dielectric. Decay can occur by spontaneous emission into transverse radiative modes of the electromagnetic field and by Joule heating via longitudinal coupling of the atom to the dielectric. The spontaneous emission (transverse) decay rate is modified in a dielectric, being the free-space rate multiplied by the real part of the refractive index at the transition frequency of the atom. There is a further modification due to the difference between the macroscopic dielectric field and the local field at the position of the atom. In addition there is a longitudinal decay rate which is proportional to the imaginary part of the dielectric constant and therefore vanishes in non-absorbing media. We derive expressions for each of these rates of decay and discuss the physical mechanisms leading to them.
We consider the process of spontaneous emission of a two-level atom embedded into a periodic layered dielectric structure. When the resonant atomic frequency lies within the photon-density-of-states gap, of width \ensuremath{\Gamma}, the atom emits light during a time interval t\ensuremath{\Gamma}\ensuremath{\ll}1 until the spontaneous emission becomes fully inhibited. We discuss the enhancing of spontaneous emission by tuning the atomic resonance with a one-mode microcavity. In the \ensuremath{\lambda}/4-shifted distributed feedback microcavities which possess the \ensuremath{\delta}-function-like density of states, in the middle of the gap, the process of spontaneous emission has damped Rabi oscillation behavior; the damping depends on the width of the gap and the height of its walls. A profile of the density-of-states gap can be determined from the experimental data on the temporal behavior of the atomic spontaneous decay.