A nonlinear correction to the probability of a transition in atoms interacting resonantly with the field of a standing wave, averaged over the atomic velocities, is shown to have logarithmic divergences responsible for the slow atom effect. This effect and the resultant narrowing of Doppler-free lines of the lamb dip type are found to occur both in a gas and in an atomic beam.
A nonlinear correction to the probability of a transition in atoms interacting resonantly with the field of a standing wave, averaged over the atomic velocities, is shown to have logarithmic divergences responsible for the slow atom effect. This effect and the resultant narrowing of Doppler-free lines of the lamb dip type are found to occur both in a gas and in an atomic beam.
The field dependence of the susceptibility of a gas interacting with a standing wave is calculated near the center of a line for a field of arbitrary profile. An allowance is made for the effects of spatial modulation of the gas. Numerical calculations are reported for a field with a Gaussian profile allowing for degeneracy. These calculations can be checked directly against experimental results for a transition corresponding to a line at λ = 3.39 μ in CH4 , which should make it possible to determine accurately the dipole moment of the transition. The amplitude and half-width of a Lamb dip are calculated for a field of arbitrary profile on the basis of perturbation theory. The problem of approximation of a real Gaussian field with a model field characterized by an amplitude constant over a circular cross section is considered. The precision of model calculations is determined for weak and strong fields. Resonances in atomic beams are discussed under transit conditions. It is shown that in this case there is a slow atom effect, which is responsible for lines with a characteristic width that is a linear function of the homogeneous width of a transition when excited particles are detected on the basis of their fluorescence.
We develop a field-nonlinear theory of sub-Doppler spectroscopy in a gas of two-level atoms, based on a self-consistent solution of the Maxwell-Bloch equations in the mean-field and single-atom density-matrix approximations. This makes it possible to correctly take into account the effects caused by the free motion of atoms in a gas, which lead to a nonlinear dependence of the spectroscopic signal on the atomic density even in the absence of a direct interatomic interaction (e.g., dipole-dipole interaction). Within the framework of this approach, analytical expressions for the light field were obtained for an arbitrary number of resonant waves and arbitrary optical thickness of a gas medium. Sub-Doppler spectroscopy in the transmission signal for two counterpropagating and copropagating waves has been studied in detail. A previously unknown redshift of a narrow sub-Doppler resonance is predicted in a counterpropagating waves scheme, when the frequency of one wave is fixed and the frequency of the other wave is varied. The magnitude of this shift depends on the atomic density and can be more than an order of magnitude greater than the known shift from the interatomic dipole-dipole interaction (Lorentz-Lorenz shift). The found effects, caused by the free motion of atoms, require a significant revision of the existing picture of spectroscopic effects depending on the density of atoms in a gas. Apart from the fundamental aspect, obtained results are important for precision laser spectroscopy and optical atomic clocks.
Previous theoretical results on the influence of a laser on the line shape of a coupled transition-laser-induced line narrowing-have been restricted to the case where the laser is detuned from the center of its atomic gain profile or is in the form of a traveling wave. This paper extends those results to include the case where the laser is an intense standing-wave field tunable to the center of its atomic gain profile (conditions for Lamb dip). The effect may be observed either in transmission, by probing the coupled transition with a weak traveling-wave field coaxial with the laser field, or else in spontaneous emission from the coupled transition viewed along the axis of the laser field. It is now well known that for a laser detuned from the center of its atomic gain profile, two narrow Lorentzian resonances of different widths appear superimposed upon the broad background signal at frequencies symmetrically located about the corresponding line center. When the laser is tuned to the center of its gain profile, however, additional fine structure develops. This structure, which is particularly significant when the laser field is intense, may have important applications in highresolution spectroscopy and laser-frequency stabilization. In this paper the laser frequency may be smaller or larger than the frequency of the coupled transition. In the latter case an intense laser introduces additional splitting effects, even when the laser is detuned. Splitting effects due to weakly saturating laser fields are also discussed. The problem is formulated by expanding elements of the ensemble-averaged density matrix in an infinite series of spatial Fourier components. A perturbation technique is employed, valid for a weak probe field and a standing-wave field of arbitrary intensity. One obtains an expression for emission induced by the probe field due to atoms moving with one velocity, written in terms of continued fractions in the general case and with Bessel functions in an important special case. This expression is integrated over the atomic velocity distribution by means of a computer to obtain the total emission due to atoms moving with all velocities. In some cases the integrated expressions may be written in closed algebraic form. A detailed discussions of line shapes and of the physical processes involved is included.
We develop a field-nonlinear theory of sub-Doppler spectroscopy in a gas of two-level atoms, based on a self-consistent solution of the Maxwell-Bloch equations in the mean field and single-atom density matrix approximations. This makes it possible to correctly take into account the effects caused by the free motion of atoms in a gas, which lead to a nonlinear dependence of the spectroscopic signal on the atomic density even in the absent of a direct interatomic interaction (e.g., dipole-dipole interaction). Within the framework of this approach, analytical expressions for the light field were obtained for an arbitrary number of resonant waves and arbitrary optical thickness of a gas medium. Sub-Doppler spectroscopy in the transmission signal for two counterpropagating and co-propagating waves has been studied in detail. A previously unknown red shift of a narrow sub-Doppler resonance is predicted in a counterpropagating waves scheme, when the frequency of one wave is fixed and the frequency of the other wave is varied. The magnitude of this shift depends on the atomic density and can be more than an order of magnitude greater than the known shift from the interatomic dipole-dipole interaction (Lorentz-Lorenz shift). The found effects, caused by the free motion of atoms, require a significant revision of the existing picture of spectroscopic effects depending on the density of atoms in a gas. Apart of fundamental aspect, obtained results are important for precision laser spectroscopy and optical atomic clocks.
A theoretical analysis is made of the interaction of a spatially bounded plane standing optical wave with a molecular gas at a very low pressure. This theory applies to weak and strong (saturating) fields. Calculations are made of the profile, amplitude, and width of a Lamp dip as a function of the intensity of the saturating field and of the dimensions of the light beam. The role of slow molecules in the formation of the dip is identified. It is shown that in weak saturating fields the width of the resonance is governed by the average thermal velocity of molecules in a gas and by the transverse size of the light beam.
In Chaps. 8 and 9, we considered a laser medium consisting of homo geneously broadened, stationary atoms. When the lasing atoms move as in a gas, they see an electric field with shifted frequency due to the Doppler effect, as shown in Fig. 10-1. One might argue that it is merely necessary to average the complex polarization or the susceptibility Xn over the frequency range corresponding to the velocity distribution, that is, calculate a new ^ n , for which Here the frequency co = coo + Kv, where coo is the frequency at atomic line (1) center, v is the component of velocity along the laser (z) axis, and the frequen cy distribution is determined by a Maxwell-Boltzmann velocity distribution W(y) = ( w)-1 exp [ - (v/w)2]. (2) Here u is the most probable speed of the atom, and K is the wave number. The simple recipe (1) is, in fact, valid for an inhomogeneously broadened mediumt consisting of stationary atoms such as ruby at low temperatures. However, in the standing-wave laser, the atoms not only see Doppler-shifted frequencies, but also move through the standing-wave electric field, effectively seeing an amplitude-modulated field. Equivalently, each atom sees two frequencies, for the standing-wave field is the sum of oppositely directed running waves, one of which appears to be Doppler upshifted, one down shifted. Hence it is necessary to consider both the frequency shift and the time dependence of the atomic z coordinate when calculating the polarization of a gaseous medium.