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International Journal of Quantum Chemistry

Foundations of quantum mechanics: Building on von Neumann's heritage

Gérard G. Emch

Published Jan 1, 1997• 5 citations
Publisher

Abstract

From 1927 to 1943, the mathematical and conceptual foundations of quantum mechanics, and their prolongations into the formulation of statistical mechanics, were either the direct subject of or one of the primary motivations for several publications by von Neumann. We contrast the reception received by the work done during the first 5 years (1927–1932) and that received by the monumental mathematical constructs wrought in the second period (1934–1943); we describe how the latter were to lead to the elaboration of a formalism generalizing the fundamental structures of quantum mechanics so that they can encompass and deal consistently with situations typical of the quantum many-body problems of statistical mechanics. © 1997 John Wiley & Sons, Inc. Int J Quant Chem 65: 379–387, 1997

DOI
10.1002/(sici)1097-461x(1997)65:5<379::aid-qua2>3.0.co;2-t

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After a quarter century of discoveries that rattled the foundations of classical mechanics and electrodynamics, the year 1926 saw the publication of two works intended to provide a theoretical structure to support new quantum explanations of the subatomic world. Heisenberg's matrix mechanics and Schrodinger's wave mechanics provided compatible but mathematically disparate ways of unifying the discoveries of Planck, Einstein, Bohr and many others. Efforts began immediately to prove the equivalence of these two structures, culminated successfully by John von Neumann's 1932 volume Mathematical Foundations of Quantum Mechanics. This forms the springboard for the current effort. We begin with a presentation of a minimal set of von Neumann postulates while introducing language and notation to facilitate subsequent discussion of quantum calculations based in finite dimensional Hilbert spaces. Chapters that follow address two-state quantum systems (with spin one-half as the primary example), entanglement of multiple two-state systems, quantum angular momentum theory and quantum approaches to statistical mechanics. A concluding chapter gives an overview of issues associated with quantum mechanics in continuous infinite-dimensional Hilbert spaces.
After a quarter century of discoveries that rattled the foundations of classical mechanics and electrodynamics, the year 1926 saw the publication of two works intended to provide a theoretical structure to support new quantum explanations of the subatomic world. Heisenberg's matrix mechanics and Schrodinger's wave mechanics provided compatible but mathematically disparate ways of unifying the discoveries of Planck, Einstein, Bohr and many others. Efforts began immediately to prove the equivalence of these two structures, culminated successfully by John von Neumann's 1932 volume Mathematical Foundations of Quantum Mechanics. This forms the springboard for the current effort. We begin with a presentation of a minimal set of von Neumann postulates while introducing language and notation to facilitate subsequent discussion of quantum calculations based in finite dimensional Hilbert spaces. Chapters that follow address two-state quantum systems (with spin one-half as the primary example), entanglement of multiple two-state systems, quantum angular momentum theory and quantum approaches to statistical mechanics. A concluding chapter gives an overview of issues associated with quantum mechanics in continuous infinite-dimensional Hilbert spaces.
After a quarter century of discoveries that rattled the foundations of classical mechanics and electrodynamics, the year 1926 saw the publication of two works intended to provide a theoretical structure to support new quantum explanations of the subatomic world. Heisenberg's matrix mechanics and Schrodinger's wave mechanics provided compatible but mathematically disparate ways of unifying the discoveries of Planck, Einstein, Bohr and many others. Efforts began immediately to prove the equivalence of these two structures, culminated successfully by John von Neumann's 1932 volume Mathematical Foundations of Quantum Mechanics. This forms the springboard for the current effort. We begin with a presentation of a minimal set of von Neumann postulates while introducing language and notation to facilitate subsequent discussion of quantum calculations based in finite dimensional Hilbert spaces. Chapters that follow address two-state quantum systems (with spin one-half as the primary example), entanglement of multiple two-state systems, quantum angular momentum theory and quantum approaches to statistical mechanics. A concluding chapter gives an overview of issues associated with quantum mechanics in continuous infinite-dimensional Hilbert spaces.
After a quarter century of discoveries that rattled the foundations of classical mechanics and electrodynamics, the year 1926 saw the publication of two works intended to provide a theoretical structure to support new quantum explanations of the subatomic world. Heisenberg's matrix mechanics and Schrodinger's wave mechanics provided compatible but mathematically disparate ways of unifying the discoveries of Planck, Einstein, Bohr and many others. Efforts began immediately to prove the equivalence of these two structures, culminated successfully by John von Neumann's 1932 volume Mathematical Foundations of Quantum Mechanics. This forms the springboard for the current effort. We begin with a presentation of a minimal set of von Neumann postulates while introducing language and notation to facilitate subsequent discussion of quantum calculations based in finite dimensional Hilbert spaces. Chapters that follow address two-state quantum systems (with spin one-half as the primary example), entanglement of multiple two-state systems, quantum angular momentum theory and quantum approaches to statistical mechanics. A concluding chapter gives an overview of issues associated with quantum mechanics in continuous infinite-dimensional Hilbert spaces.
Abstract We have already mentioned that Schriöidinger’s formulation of quantum mechanics was slightly preceded by a totally different algebraic formulation proposed by Heisenberg. Although Schriöidinger’s methods were so much simpler that they were generally preferred, both approaches seemed to give the same answers, so it was natural to ask how they were related. This was particularly important because some features of quantum theory were easier to understand in Heisenberg’s formalism. In fact, as we have already noted, Schriöidinger was able to show that the two methods were essentially equivalent. Soon mathematicians like Hermann Weyland John von Neumann were able to find a general mathematical scheme that encompassed both approaches, and it is this that we shall now describe.
Abstract This chapter covers the completion of the formalism of quantum mechanics and its statistical interpretation in the first two installments of a remarkable trilogy of work by von Neumann in 1927. In the first, von Neumann introduces the modern Hilbert space formalism and demonstrates the equivalence of matrix and wave mechanics by showing that they are just two different instantiations of Hilbert space, one being the space of square-summable sequences, the other being the space of square integrable functions. In the second, drawing on work by von Mises on the foundations of probability theory, he provides a careful formulation of the statistical interpretation of this formalism. In doing so, he introduces such staples of modern quantum mechanics as density operators characterizing quantum statistical ensembles and the distinction between pure and mixed states.