Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

The Journal of Chemical Physics

Intrinsic resonance representation of quantum mechanics

M. Carioli, Eric J. Heller, Klaus B. Mo ller

Published May 22, 1997• 9 citations
Publisher

Abstract

The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a “merely complete” basis, whose coefficients in the eigenstates carry little physical insight. We suggest here an optimal representation, based purely on classical mechanics. “Hidden” constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations. This simplifies the hierarchical structure of couplings between “zero-order” states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton–Jacobi equation.

DOI
10.1063/1.473911

Related papers

The complete solution of the Hamilton-Jacobi equation in Quantum Mechanics

Rafael Ferraro

An ordinary unambiguous integral representation for the finite propagator of a quantum system is found by starting of a privileged skeletonization of the functional action in phase space, provided by the complete solution of the Hamilton-Jacobi equation. This representation allows to regard the propagator as the sum of the contributions coming from paths where the momenta generated by the complete solution of the Hamilton-Jacobi equation are conserved -as it does happen on the classical trajectory-, but are not restricted to having the classical values associated with the boundary conditions for the original coordinates.

arXiv:quant-ph/9607013•Jul 17, 1996•1 citation

Quantum Hamilton–Jacobi formalism and the bound state spectra

R. S. Bhalla, Ashok Kumar Kapoor, Prasanta Kumar Panigrahi

It is well known in classical mechanics that the frequencies of a periodic system can be obtained rather easily through the action variable, without completely solving the equation of motion. Analogously, the equivalent quantum action variable appearing in the quantum Hamilton–Jacobi formalism can provide the energy eigenvalues of a bound state problem, without the necessity of solving the corresponding Schrödinger equation explicitly. This elegant and useful method is elucidated here in the context of some known and not so well-known solvable potentials. It is also shown how this method provides an understanding as to why approximate quantization schemes such as ordinary and supersymmetric WKB can give exact answers for certain potentials.

arXiv:quant-ph/9512018•American Journal of Physics•Dec 1, 1997•71 citations

On the reality of quantum states: A pedagogic survey from classical to quantum mechanics

Moncy Vilavinal John

Some recent experiments claim to show that any model in which a quantum state represents mere information about an underlying physical reality of the system must make predictions which contradict those of quantum theory. The present work undertakes to investigate the issue of reality, treading a more fundamental route from the Hamilton-Jacobi equation of classical mechanics to the Schrodinger equation of quantum mechanics. Motivation for this is a similar approach from the eikonal equation in geometrical optics to the wave equation in electromagnetic theory. We rewrite the classical Hamilton-Jacobi equation as a wave equation and seek to generalise de Broglie's wave particle duality by demanding that both particle and light waves have the freedom of being described by any square-integrable function. This generalisation, which allows superposition also for matter wave functions, helps us to obtain the Schrodinger equation, whose solution can be seen to be as much objective as the classical mechanics wave function. Several other equations which one writes in quantum mechanics, including the eigenvalue equations for observables, series expansion of energy states in terms of eigenstates of observables other than energy, etc., can be written in the classical case too. Absence of any collapse of the wave function, entanglement, etc. in the classical realm have their origin in the nonlinearity of the classical wave equation. These considerations indicate that many of the puzzles in quantum mechanics are present also in classical mechanics in a dormant form, which fact shall help to demystify quantum mechanics to a great extent.

quant-pharXiv:2602.02617•Feb 3, 2026•0 citations

Hamilton-Jacobi/action-angle quantum mechanics

Robert A. Leacock, Michael J. Padgett

A quantum mechanics is constructed which is patterned on classical Hamilton-Jacobi theory. The dynamical basis of the theory is a quantum Hamilton-Jacobi equation with accompanying physical boundary conditions. Basic objects of the formulation are quantum Hamilton's principal and characteristic functions. As an application of the formalism a theory of quantum action-angle variables is set up. The central feature of this theory is the definition of the quantum action variable which permits the determination of the bound-state energy levels without solving the dynamical equation.

Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields•Nov 15, 1983•150 citations

Schroedinger and Hamilton-Jacobi equations

M. V. Lokajíček

Time-dependent Schroedinger equation represents the basis of any quantum-theoretical approach. The question concerning its proper content in comparison to the classical physics has not been, however, fully answered until now. It will be shown that there is one-to-one physical correspondence between basic solutions (represented always by one Hamiltonian eigenfunction only) and classical ones, as the non-zero quantum potential has not any physical sense, representing only the "numerical" difference between Hamilton principal function and the phase of corresponding wave function in the case of non-inertial motion. Possible interpretation of superposition solutions will be then discussed in the light of this fact. And also different interpretation alternatives of the quantum-mechanical model will be newly analyzed and new attitude to them will be reasoned.

arXiv:quant-ph/0611176•Nov 16, 2006•0 citations

“A call to action”: Schrödinger's representation of quantum mechanics via Hamilton's principle

Michele Marrocco

A few years ago, one of the former Editors of this journal launched “a call to action” (E. F. Taylor, Am. J. Phys. 71, 423–425 (2003)) for a revision of teaching methods in physics in order to emphasize the importance of the principle of least action. In response, we suggest the use of Hamilton's principle of stationary action to introduce the Schrödinger equation. When considering the geometric interpretation of the Hamilton–Jacobi theory, the real part of the action S defines the phase of the wave function exp iS/ℏ, and requiring the Hamilton–Jacobi wave function to obey wave-front propagation (i.e., Re(S) is a constant of the motion) yields the Schrödinger equation.

American Journal of Physics•Jan 23, 2023•2 citations
The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a “merely complete” basis, whose coefficients in the eigenstates carry little physical insight. We suggest here an optimal representation, based purely on classical mechanics. “Hidden” constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations. This simplifies the hierarchical structure of couplings between “zero-order” states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton–Jacobi equation.
An ordinary unambiguous integral representation for the finite propagator of a quantum system is found by starting of a privileged skeletonization of the functional action in phase space, provided by the complete solution of the Hamilton-Jacobi equation. This representation allows to regard the propagator as the sum of the contributions coming from paths where the momenta generated by the complete solution of the Hamilton-Jacobi equation are conserved -as it does happen on the classical trajectory-, but are not restricted to having the classical values associated with the boundary conditions for the original coordinates.
It is well known in classical mechanics that the frequencies of a periodic system can be obtained rather easily through the action variable, without completely solving the equation of motion. Analogously, the equivalent quantum action variable appearing in the quantum Hamilton–Jacobi formalism can provide the energy eigenvalues of a bound state problem, without the necessity of solving the corresponding Schrödinger equation explicitly. This elegant and useful method is elucidated here in the context of some known and not so well-known solvable potentials. It is also shown how this method provides an understanding as to why approximate quantization schemes such as ordinary and supersymmetric WKB can give exact answers for certain potentials.
Some recent experiments claim to show that any model in which a quantum state represents mere information about an underlying physical reality of the system must make predictions which contradict those of quantum theory. The present work undertakes to investigate the issue of reality, treading a more fundamental route from the Hamilton-Jacobi equation of classical mechanics to the Schrodinger equation of quantum mechanics. Motivation for this is a similar approach from the eikonal equation in geometrical optics to the wave equation in electromagnetic theory. We rewrite the classical Hamilton-Jacobi equation as a wave equation and seek to generalise de Broglie's wave particle duality by demanding that both particle and light waves have the freedom of being described by any square-integrable function. This generalisation, which allows superposition also for matter wave functions, helps us to obtain the Schrodinger equation, whose solution can be seen to be as much objective as the classical mechanics wave function. Several other equations which one writes in quantum mechanics, including the eigenvalue equations for observables, series expansion of energy states in terms of eigenstates of observables other than energy, etc., can be written in the classical case too. Absence of any collapse of the wave function, entanglement, etc. in the classical realm have their origin in the nonlinearity of the classical wave equation. These considerations indicate that many of the puzzles in quantum mechanics are present also in classical mechanics in a dormant form, which fact shall help to demystify quantum mechanics to a great extent.
A quantum mechanics is constructed which is patterned on classical Hamilton-Jacobi theory. The dynamical basis of the theory is a quantum Hamilton-Jacobi equation with accompanying physical boundary conditions. Basic objects of the formulation are quantum Hamilton's principal and characteristic functions. As an application of the formalism a theory of quantum action-angle variables is set up. The central feature of this theory is the definition of the quantum action variable which permits the determination of the bound-state energy levels without solving the dynamical equation.
Time-dependent Schroedinger equation represents the basis of any quantum-theoretical approach. The question concerning its proper content in comparison to the classical physics has not been, however, fully answered until now. It will be shown that there is one-to-one physical correspondence between basic solutions (represented always by one Hamiltonian eigenfunction only) and classical ones, as the non-zero quantum potential has not any physical sense, representing only the "numerical" difference between Hamilton principal function and the phase of corresponding wave function in the case of non-inertial motion. Possible interpretation of superposition solutions will be then discussed in the light of this fact. And also different interpretation alternatives of the quantum-mechanical model will be newly analyzed and new attitude to them will be reasoned.
A few years ago, one of the former Editors of this journal launched “a call to action” (E. F. Taylor, Am. J. Phys. 71, 423–425 (2003)) for a revision of teaching methods in physics in order to emphasize the importance of the principle of least action. In response, we suggest the use of Hamilton's principle of stationary action to introduce the Schrödinger equation. When considering the geometric interpretation of the Hamilton–Jacobi theory, the real part of the action S defines the phase of the wave function exp iS/ℏ, and requiring the Hamilton–Jacobi wave function to obey wave-front propagation (i.e., Re(S) is a constant of the motion) yields the Schrödinger equation.