We report a general bound for the efficiency of polarization or coherence transfer between quantized states under unitary transformations. This bound is more general than the so-called universal bound on spin dynamics [O. W. S\o{}rensen, J. Magn. Reson. 86, 435 (1990)] that applies only to transformations between Hermitian states. The new bound on transfer efficiency under unitary transformations between general non-Hermitian operators depends exclusively on the singular values of the matrix representations of these operators.
We investigate the geometric structure of the set of spectra of bipartite absolute separable states (
ASEPm,n) and absolute positive partial transpose states (
APPTm,n), \emph{i.e.}, bipartite quantum states that remain separable or PPT, respectively, under all global unitary transformations. First, we establish general geometric properties of absolute convex sets of matrices, their spectra and extreme points. Regarding absolute separability, we present a permutation-symmetric reformulation of the absolute PPT criterion and use it to demonstrate that
APPTm,n is a spectrahedron for all
m≤n: in particular, all its faces are exposed. While
ASEP2,n is a spectrahedron, too, for
ASEPm,n we can in general only show that it is a semialgebraic set for all
m,n≥3. Furthermore, we provide a complete characterization of the faces and extreme points of
APPTm,n and demonstrate that the dimension of a face is determined by the rank of a certain matrix, with maximal proper faces having dimension
mn−m−1.
In the quantitative setting, we provide a rigorous lower bound on the maximal attainable purity of
APPTm,n via an inscribed polytope
Pm,n and conjecture that the maximal purity of
APPTm,n (along with its spectra) coincides with the polytope for arbitrary dimensions except when
m=n=2. Additionally, we also provide a rigorous upper bound on the minimal von Neumann entropy of
APPTm,n and demonstrate numerically that the minimum entropy eventually coincides with the polytope
Pm,n as the local system dimension
n increases. Finally, we show that the relative spectral volume of
APPTm,n decays exponentially in
n by a constant multiplicative factor of the relative volume of the inscribed polytope
Pm,n.
We report analytical solutions to the unitary bound problem for coherence/polarization transfer in IS two-spin-12 systems by means of unitary operations. Theoretical upper bounds for the transfer efficiency along with the associated optimum transformation operators are obtained analytically by decomposing the unitary operator as a product of exponentials in the special unitary Lie group SU(4). Addressing NMR spectroscopy as a specific example, the method is demonstrated for the non-Hermitian transfers I−→S− and 2I−Sz→S− being relevant for heteronuclear single-quantum coherence (HSQC) experiments as well as the double- to single-quantum transfer I−S−→I−Sβ+IβS− being representative for coherence-order and spin-state-selective transfer in INADEQUATE CR experiments. Furthermore, using a Lagrangian function approach it is demonstrated how the method enables analytical description of two-dimensional bounds for Iz→Sz cross polarization.
We propose candidate lower bounds on the real Grothendieck constants
KG(d) and their infinite-dimensional limit
KG using rotationally invariant cubic kernels. For the continuous construction, we identify an explicit threshold above which hemispherical binary strategies are unstable under cubic boundary deformations. Supported by numerical evidence, we conjecture that hemispherical strategies are globally optimal at this threshold. This conjecture would imply
KG≥9π/16≃1.767146, improving the rigorous lower bound
6π/11≃1.713596. We also construct finite symmetric coefficient matrices from unit vectors in dimensions up to
24. Large-scale see-saw optimization supports the continuous predictions and suggests improved lower bounds on
KG(d) in the studied dimensions from
4 to
24, conditional on the conjectured binary optima being exact. Selected matrices also yield finite-setting candidate dimension witnesses when interpreted as bipartite correlation Bell functionals. If the corresponding binary upper bounds hold, these witnesses would certify a local Hilbert-space dimension of at least five for each party.