Quasiequilibrium relaxational thermodynamics is developed to understand LA-phonon-assisted thermalization of Bose-Einstein distributed excitons in quantum wells. We study quantum-statistical effects in the relaxational dynamics of the effective temperature of excitons
T=T(t). When T is less than the degeneracy temperature
T0, well-developed Bose-Einstein statistics of quantum-well excitons leads to nonexponential and density-dependent thermalization. At low bath temperatures ${T}_{b}\ensuremath{\rightarrow}0,$ the thermalization of quantum statistically degenerate excitons effectively slows down and $T(t)\ensuremath{\propto}1/\mathrm{ln}t.$ We also analyze the optical decay of Bose-Einstein distributed excitons in perfect quantum wells, and show how nonclassical statistics influences the effective lifetime ${\ensuremath{\tau}}_{\mathrm{opt}}.$ In particular, ${\ensuremath{\tau}}_{\mathrm{opt}}$ of a strongly degenerate gas of excitons is given by $2{\ensuremath{\tau}}_{R},$ where ${\ensuremath{\tau}}_{R}$ is the intrinsic radiative lifetime of quasi-two-dimensional excitons. Kinetics of resonant photoluminescence of quantum-well excitons during their thermalization is studied within the thermodynamic approach and taking into account Bose-Einstein statistics. We find density-dependent photoluminescence dynamics of statistically degenerate excitons. Numerical modeling of the thermalization and photoluminescence kinetics of quasi-two-dimensional excitons are given for ${\mathrm{G}\mathrm{a}\mathrm{A}\mathrm{s}/\mathrm{A}\mathrm{l}}_{x}{\mathrm{Ga}}_{1\ensuremath{-}x}\mathrm{As}$ quantum wells.
Excitation by two-photon resonant absorption may be able to maintain the temperature of the orthoexcitonic system in
Cu2O sufficiently low, resulting in an excitonic density high enough to allow us to study the quantum Bose-Einstein statistical properties of a nearly ideal Bose gas. The luminescence spectra show that the orthoexcitonic system consists of two parts. One follows the usual Bose-Einstein statistics with chemical potential \ensuremath{\mu}=0. The other is at an energy position corresponding to zero kinetic energy.