FURTHER STUDY ON THE SOLUTION OF SCHRÖDINGER EQUATION OF HYDROGEN-LIKE ATOM
Zhong-Liang Zhang, Wu-Shou Zhang, Zhao-qun Zhang
Abstract
In this work the Schrödinger equation of the hydrogen-like atom is analytically solved. Three sets of analytical solution are obtained if the factor r−l is not neglected. The first solution is the same as the traditional radial wave function; another one diverges; the last one is far different from the traditional solution. On the consideration of the finite size of the nucleus, the third wave function does not diverge while r approaches to zero. Its radial wave function has below characteristics: (1) the angular-momentum quantum number l must be greater than the principal quantum number n; (2) l must not be 0 or 1; (3) the electron-cloud distribution differs from the traditional one; (4) the electron is closer to the nucleus by comparison with that in traditional results. On the other hand, the validity of solutions needs to be verified experimentally. 1.