Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physical Review Letters

Spontaneous Emission of Organic Molecules Embedded in a Photonic Crystal

Eugene P. Petrov, V. N. Bogomolov, I. I. Kalosha, Sergey V. Gaponenko

Published Jul 6, 1998• 297 citations
Publisher

Abstract

We report on modification of the spontaneous emission of dye molecules embedded in a three-dimensional solid-state photonic crystal exhibiting a stop band in the visible range. Molecules embedded in artificial opal filled with a polymer show a dip in the fluorescence spectrum and nonexponential spontaneous decay kinetics containing both accelerated and inhibited components compared to the dye fluorescence in a reference polymer matrix. Results are interpreted in terms of redistribution of the photon density of states in the photonic crystal.

DOI
10.1103/physrevlett.81.77

Related papers

Modification of the Spontaneous Emission of Dye Molecules in Photonic Crystals

Eugene P. Petrov, V. N. Bogomolov, I. I. Kalosha +1 more

Modification of the spontaneous emission of dye molecules embedded in artificial opals exhibiting stop bands in the visible range is observed.Molecules embedded in artificial opals show dips in spontaneous emission spectra and modified fluorescence decay kinetics.Results are interpreted in terms of redistribution of the photon density of states.Effects of the multiple reabsorption and reemission of fluorescence photons and interaction of dye molecules with the silica surface are discussed.

Acta Physica Polonica A•Nov 1, 1998•9 citations

Spontaneous emission of dye molecules, semiconductor nanocrystals, and rare-earth ions in opal-based photonic crystals

Sergey V. Gaponenko, V. N. Bogomolov, Eugene P. Petrov +8 more

Photonic crystals based on silica colloidal crystals (artificial opals) exhibit pronounced stopbands for electromagnetic wave propagation and the corresponding modification of the photon density of states in the visible range. These spectrally selective features can be enhanced by impregnating opals with higher refractive materials like, e.g., polymers. Doping of these structures with dye molecules, semiconductor nanoparticles (quantum dots), and rare-earth ions provides a possibility to examine the challenging theoretical predictions of the inhibited spontaneous emission in photonic bandgap (PBG) materials. First experiments are discussed in which pronounced modification of spontaneous emission spectra and noticeable changes in decay kinetics were observed.

Journal of Lightwave Technology•Jan 1, 1999•86 citations

Spontaneous emission spectra of organic molecules in synthetic opal photonic crystals

O. O. Guziy, B. Abusal, V. N. Moiseyenko +2 more

The emission of rhodamine 6G and 2,5-bis(2-benzoxazolyl)hydroquinone molecules embedded in synthetic opal photonic crystals are studied in the spectral range of 520-620 nm.It is found that the intensity of spontaneous emission is suppressed in the spectral region corresponding to the photonic stop band and is amplified on its "blue" side.

Ukrainian Journal of Physical Optics•Jan 1, 2008•1 citation

Spontaneous emission of laser dye molecules in synthetic opals under conditions of low dielectric contrast

V. N. Moiseyenko, Mykhailo P. Derhachov, V. G. Shvachich +2 more

Spontaneous emission of laser dye molecules (rhodamine 6G and pironin G) embedded into pores of synthetic opal photonic crystals is studied in the spectral region of 520-650 nm.It is ascertained that the emission spectra are greatly dependent on the photonic stop-band position and the spectral distribution of photon density of states.A dependence of spectral position of the emission band from the dielectric contrast is found.

Ukrainian Journal of Physical Optics•Jan 1, 2010•6 citations

Emission in a SnS2 inverted opaline photonic crystal

Sergei G Romanov, Torsten Maka, Clivia Marfa Sotomayor Torres +2 more

The photoluminescence of a dye embedded in the three-dimensional SnS2 inverted opal has been studied. Changes of the emission spectrum compared with the free-space dye emission was observed in the stop-band frequency range in accord with reflectance/transmission spectra of this photonic crystal. The angular-dependent component, due to the Bragg stop band, and the angular-independent component, which is, possibly, related to the minimum in the density of photon states, have been distinguished in the dye emission spectrum.

Applied Physics Letters•Aug 6, 2001•52 citations

Nonexponential decay of spontaneous emission from an ensemble of molecules in photonic crystals

Renaud A. L. Vallée, Kris Baert, Branko Kolarić +2 more

Photonic crystals (PCs) with relatively low dielectric contrast (i.e., with pseudogaps) have significant influence on the fluorescence decay of internal emitters. Fluorescence decays of ensembles of dye molecules measured at different positions in the PCs exhibit a nonexponential behavior, which is best fitted by a continuous distribution of decay rates. The most frequent decay rates of these distributions are smaller and their widths are narrower in a PC with a pseudogap acting in the emission range of the emitters than in a PC having the pseudogap out of this range. These experimental results have been well accounted for by calculations of the local density of states and rate constant for spontaneous emission.

Physical Review B•Jul 19, 2007•43 citations
We report on modification of the spontaneous emission of dye molecules embedded in a three-dimensional solid-state photonic crystal exhibiting a stop band in the visible range. Molecules embedded in artificial opal filled with a polymer show a dip in the fluorescence spectrum and nonexponential spontaneous decay kinetics containing both accelerated and inhibited components compared to the dye fluorescence in a reference polymer matrix. Results are interpreted in terms of redistribution of the photon density of states in the photonic crystal.
Photonic crystals based on silica colloidal crystals (artificial opals) exhibit pronounced stopbands for electromagnetic wave propagation and the corresponding modification of the photon density of states in the visible range. These spectrally selective features can be enhanced by impregnating opals with higher refractive materials like, e.g., polymers. Doping of these structures with dye molecules, semiconductor nanoparticles (quantum dots), and rare-earth ions provides a possibility to examine the challenging theoretical predictions of the inhibited spontaneous emission in photonic bandgap (PBG) materials. First experiments are discussed in which pronounced modification of spontaneous emission spectra and noticeable changes in decay kinetics were observed.
The photoluminescence of a dye embedded in the three-dimensional SnS2 inverted opal has been studied. Changes of the emission spectrum compared with the free-space dye emission was observed in the stop-band frequency range in accord with reflectance/transmission spectra of this photonic crystal. The angular-dependent component, due to the Bragg stop band, and the angular-independent component, which is, possibly, related to the minimum in the density of photon states, have been distinguished in the dye emission spectrum.
Photonic crystals (PCs) with relatively low dielectric contrast (i.e., with pseudogaps) have significant influence on the fluorescence decay of internal emitters. Fluorescence decays of ensembles of dye molecules measured at different positions in the PCs exhibit a nonexponential behavior, which is best fitted by a continuous distribution of decay rates. The most frequent decay rates of these distributions are smaller and their widths are narrower in a PC with a pseudogap acting in the emission range of the emitters than in a PC having the pseudogap out of this range. These experimental results have been well accounted for by calculations of the local density of states and rate constant for spontaneous emission.