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Physical Review A

Coherent states of the Kratzer-Fues oscillator

Marcin Molski

Published Aug 27, 2007• 27 citations
Publisher

Abstract

The coherent states for the Kratzer-Fues potential, which are eigenstates of the annihilation operator and minimize the generalized position-momentum uncertainty relation, are constructed using the algebraic approach. The method is extended to include the rotating Kratzer-Fues oscillator. Construction of such states is important in the theory of molecular interactions with coherent electromagnetic fields, for example, in calculation of the dynamic alternation of the refractive index due to the interactions of the laser pulse with the coherent vibration-rotational states of the diatomic molecule.

DOI
10.1103/physreva.76.022107

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The coherent states for the Kratzer-Fues potential, which are eigenstates of the annihilation operator and minimize the generalized position-momentum uncertainty relation, are constructed using the algebraic approach. The method is extended to include the rotating Kratzer-Fues oscillator. Construction of such states is important in the theory of molecular interactions with coherent electromagnetic fields, for example, in calculation of the dynamic alternation of the refractive index due to the interactions of the laser pulse with the coherent vibration-rotational states of the diatomic molecule.
The coherent states for a particle in Kratzer type potentials are constructed by solving Feynman’s path integral. The action of the generalized Kratzer potential is transformed into two harmonic oscillators by Levi-Civita transformation to derive the parametric time coherent states. Green’s function, energy eigenvalues, and the corresponding wave functions for this potential are calculated. The evaluated results are reduced to the modified Kratzer potentials and Kratzer-Fues oscillators which are special cases of the generalized Kratzer potential.
A mixed supersymmetric-algebraic approach to construction of the minimum uncertainty coherent states of anharmonic oscillators is presented. It permits generating not only the well-known coherent states of the harmonic and Morse oscillators but also the so far unknown coherent states of the Wei Hua, Kratzer-Fues and generalized Morse and Kratzer-Fues oscillators. The method can be applied also to generate superpotentials indispensable for deriving the Schrödinger equation in the supersymmetric form amenable to direct solution in the SUSYQM scheme.
For the one-dimensional Morse oscillator we have built a set of creation and annihilation operators and established the corresponding coherent states. The average values of some observables in these coherent states have been calculated and their time evolution established. In order to study the strong vibrations of di-atomic molecules we use a three-dimensional Morse oscillator model and its dynamic group. For this system we have built the coherent states and calculated the dynamic modifications of the refractive index of the molecules, as the result of interaction with a laser beam.
The ladder operators for the Goldman and Krivchenkov anharmonic potential have been derived within the algebraic approach. The method is extended to include the rotating oscillator. The coherent states for the Goldman and Krivchenkov oscillator, which are the eigenstates of the annihilation operator and minimize the generalized position-momentum uncertainty relation, are constructed within the framework of supersymmetric quantum mechanics. The constructed ladder operators can be a useful tool in quantum chemistry computations of non-trivial matrix elements. In particular, they can be employed in molecular vibrational–rotational spectroscopy of diatomic molecules to compute transition energies and dipole matrix elements.
A mixed supersymmetric–algebraic approach to the construction of the minimum uncertainty coherent states of anharmonic oscillators is presented. It permits generating not only the well-known coherent states of the harmonic and Morse oscillators but also the so far unknown coherent states of the Wei Hua and generalized Morse and Kratzer–Fues oscillators. The method can be applied to generate superpotentials indispensable for deriving the Schrödinger equation in the supersymmetric form amenable to direct solution in the SUSYQM scheme.