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Canadian Journal of Physics

Diverse, successful, and fascinating relativistic many-body perturbation theory

Igor Savukov

Published Jan 1, 2009• 0 citations
Publisher
DOI
10.1139/p08-121

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We present relativistic many-body calculations of the fine-structure splittings of the n2Fn\phantom{\rule{0.16em}{0ex}}{}^{2}Fn2F Rydberg states of Rb (n=4(n=4(n=4--16) using both order-by-order relativistic many-body perturbation theory (RMBPT), up to a subset of fourth-order corrections, and relativistic equation-of-motion coupled-cluster methods, including singles, doubles, and an approximate treatment of valence triples. Good overall agreement is found with the measurements of Brandenberger et al. [Phys. Rev. A 65, 042510 (2002); Phys. Rev. A 81, 032515 (2010)] to better than the 1% level, which is our expected level of theoretical uncertainty due to omitted higher-order correlation effects. It is shown that the RMBPT of the fine-structure splittings is complex and slowly convergent, and that relativistic effects are enhanced compared with the RMBPT of the ionization energy of the 2F^{2}\mathrm{F}2F states. We also analyze smaller field-theoretic contributions to the fine-structure splittings from retardation and the radiative self-energy and vacuum polarization, finding them to enter at the 0.1% level.