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Chaos Solitons & Fractals

Complex dynamics in diatomic molecules. Part II: Quantum trajectories

Ciann Dong Yang, Hung-Jen Weng

Published May 26, 2007• 6 citations
Publisher
DOI
10.1016/j.chaos.2007.03.011

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This work (O3 — Part II) completes the derivation of the quantum mechanical formalism within the Emergent Pre-Quantizable (EPPQ) framework by establishing the necessary emergence of the complex Hilbert space structure from purely relational dynamics. Building upon O3 — Part I, where the Schrödinger equation and the Born rule were derived conditionally from coarse-grained Markov dynamics on metastable basins, this paper addresses the remaining foundational gap: the origin of complex amplitudes and quantum phases. We demonstrate that a discrete U(1) gauge structure naturally arises from the contextual layer of the EPPQ vacuum, formalized as a principal bundle over the vacuum graph. The associated holonomies (Wilson lines) induce geometric phases along microscopic trajectories. By analyzing the interference of these trajectories, we prove that: • Transition amplitudes must take values in the complex field ℂ • The Born rule P = |ψ|² is the unique probability measure compatible with superposition and gauge invariance • The effective Hamiltonian emerges from the skew-symmetric component of the coarse-grained Markov generator and is directly determined by contextual holonomies Furthermore, we show that the same structure yields, in a specific spectral sector, the Yukawa matrices of the Standard Model, including nontrivial complex phases responsible for CP violation. The results establish that the complex structure of quantum mechanics is not an independent postulate, but a necessary consequence of relational holonomy and trajectory interference. This provides the missing link between the geometric constructions of O1/O4 and the emergent quantum dynamics of O3. This work is part of a broader program (EPPQ) aimed at deriving spacetime, quantum theory, and particle physics from a minimal relational ontology.

•Apr 17, 2026•0 citations

5 Quantum dynamics and spectroscopy

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We demonstrate the mixing of rotational states in the ground electronic state using microwave radiation to enhance optical cycling in the molecule yttrium (II) monoxide (YO). This mixing technique is used in conjunction with a frequency modulated and chirped continuous wave laser to slow longitudinally a cryogenic buffer-gas beam of YO. We generate a flux of YO below 10 m/s, directly loadable into a three-dimensional magneto-optical trap. This technique opens the door for laser cooling of diatomic molecules with more complex loss channels due to intermediate states.
This work (O3 — Part II) completes the derivation of the quantum mechanical formalism within the Emergent Pre-Quantizable (EPPQ) framework by establishing the necessary emergence of the complex Hilbert space structure from purely relational dynamics. Building upon O3 — Part I, where the Schrödinger equation and the Born rule were derived conditionally from coarse-grained Markov dynamics on metastable basins, this paper addresses the remaining foundational gap: the origin of complex amplitudes and quantum phases. We demonstrate that a discrete U(1) gauge structure naturally arises from the contextual layer of the EPPQ vacuum, formalized as a principal bundle over the vacuum graph. The associated holonomies (Wilson lines) induce geometric phases along microscopic trajectories. By analyzing the interference of these trajectories, we prove that: • Transition amplitudes must take values in the complex field ℂ • The Born rule P = |ψ|² is the unique probability measure compatible with superposition and gauge invariance • The effective Hamiltonian emerges from the skew-symmetric component of the coarse-grained Markov generator and is directly determined by contextual holonomies Furthermore, we show that the same structure yields, in a specific spectral sector, the Yukawa matrices of the Standard Model, including nontrivial complex phases responsible for CP violation. The results establish that the complex structure of quantum mechanics is not an independent postulate, but a necessary consequence of relational holonomy and trajectory interference. This provides the missing link between the geometric constructions of O1/O4 and the emergent quantum dynamics of O3. This work is part of a broader program (EPPQ) aimed at deriving spacetime, quantum theory, and particle physics from a minimal relational ontology.