The essentials of quantum mechanics are derived from Liouville's theorem in statistical mechanics. An elementary solution, g, of Liouville's equation helps to construct a differentiable N-particle distribution function (DF), F(g), satisfying the same equation. Reality and additivity of F(g): (i) quantize the time variable; (ii) quantize the energy variable; (iii) quantize the Maxwell–Boltzmann distribution; (iv) make F(g) observable through time-elimination; (v) produce the Planck constant; (vi) yield the black-body radiation spectrum; (vii) support chronotopology introduced axiomatically; (viii) the Schrödinger and the Klein–Gordon equations follow. Hence, quantum theory appears as a corollary of Liouville's theorem. An unknown connection is found allowing the better understanding of space-times and of these theories.
The essentials of quantum mechanics are derived from Liouville's theorem in statistical mechanics. An elementary solution, g, of Liouville's equation helps to construct a differentiable N-particle distribution function (DF), F(g), satisfying the same equation. Reality and additivity of F(g): (i) quantize the time variable; (ii) quantize the energy variable; (iii) quantize the Maxwell–Boltzmann distribution; (iv) make F(g) observable through time-elimination; (v) produce the Planck constant; (vi) yield the black-body radiation spectrum; (vii) support chronotopology introduced axiomatically; (viii) the Schrödinger and the Klein–Gordon equations follow. Hence, quantum theory appears as a corollary of Liouville's theorem. An unknown connection is found allowing the better understanding of space-times and of these theories.
The chrono-topology, as introduced axiomatically in a different context, is also supported by Liouville's theorem of statistical mechanics. It is shown that, if time is quantized, the distribution function (d.f.) becomes real. An elementary solution, g, of the classical Liouville equation has been found in phase-space and time, which can be used to construct any differentiable d.f, F(g), satisfying the same Liouville equation. The conditions imposed on F(g) are reality and additivity. The reality requirement, {Im F(g)=0) quantizes: (i) F(g) and makes it time-independent, (ii). The time variable, (iii) The energy. As a verification of chronotopology, the Planck constant h has been calculated on the basis of the time quantization. The d.f. F(g) becomes, after the time quantization, a real generalized Maxwell-Boltzmann d.f, F(g) = exp[g(p, g; l1,l2,..,lN)], depending on Ν quantum numbers. These facts are significant for quantum theory, because they uncover an intrinsic relationship between Liouville's theorem and quantum mechanics.
In non-relativistic quantum mechanics, the absolute square of Schrödinger's wave function for a particle in a potential determines the probability of finding it either at a position or momentum at a given time. In classical mechanics the corresponding problem is determined by the solution of Liouville's equation for the probability density of finding the joint position and momentum of the particle at a given time. Integrating this classical solution over either one of these two variables can then be compared with the probability in quantum mechanics. For the special case that the force is a constant, it is shown analytically that for an initial Gaussian probability distribution, the solution of Liouville's integrated over momentum is equal to Schrödinger's probability function in coordinate space, provided the coordinate and momentum initial widths of this classical solution satisfy the minimal Heisenberg uncertainty relation. Likewise, integrating Lioville's solution over position is equal to Schrödinger's probability function in momentum space. Quanta 2017; 6: 53–56.
A wave dynamics of fields φ(p, q; t) ∈ L2(Γ) over the phase space Γ(p, q) of a classical system 𝒮 is derived from the Liouville theorem. We define the energy contained in a given field φ(p, q; t). We show that for a special class of fields, selected on physical grounds, the energy spectrum is given by a time-independent Schrödinger equation. This allows us to associate with 𝒮 an ordinary quantum system Q such that the values of the quantized energy coincide for the fields in the phase space of 𝒮 and for Q. Then we make use of Wiener's stochastic integral based on the theory of Brownian motion to derive probabilities which are the same as those one would obtain through Born's statistical postulate of quantum theory. From this it follows that we can regard normalized fields φ(p, q; t) as ``probability amplitudes'' leading to a probability density function ρ(p, q; t) = φφ* in the sense of Gibbs' statistical mechanics. Our work therefore appears as a bridge between a statistical theory (in the sense of Gibbs) of a mechanical system 𝒮 and the usual quantum theory of the related quantum system Q.
We derive a classical Schrodinger type equation from the classical Liouville equation in phase space. The derivation is based on a Wigner type Fourier transform of the classical phase space probability distribution, which depends on an arbitrary constant α with dimension of action. In order to achieve this goal two requirements are necessary: 1) It is assumed that the classical probability amplitude Ψ(x,t) can be expanded in a complete set of functions Φn(x) defined in the configuration space; 2) the classical phase space distribution W(x,p,t) obeys the Liouville equation and is a real function of the position, the momentum and the time. We show that the constant α appearing in the Fourier transform of the classical phase space distribution, and also in the classical Schrodinger type equation, has its origin in the spectral distribution of the vacuum zero-point radiation, and is identified with the Planck's constant ℏ.
Density distribution function of classical statistical mechanics is generally generalized as a product of a general complex function and its complex Hermitian conjugate function, and the average of classical statistical mechanics is generalized as the average of the quantum mechanics. Furthermore, this paper derives three ones of the five axiom presumptions of quantum mechanics, makes the three axiom presumptions into three theorems of quantum mechanics, not only solves the crisis to hard understand, but also gets new theories and new discoveries, e.g., this paper solves the crisis of the origin of the wave-particle duality (i.e., complementary principle), derives operators, eigenvalues and eigenstates, deduces commutation relations for coordinate and momentum as well as the time and energy, and discovers quantum mechanics is just a generalization ( mechanics ) theory of the square root of ( density function of ) classical statistical mechanics, which will make people renew thinking modern physics development. In addition, this paper discovers the reason why the time derivative of Schrȍdinger doesn’t takes the derivative of space coordinates. Therefore, this paper gives solution to the Crisis of the first quantization origin.