Abstract Atomistic rate equations are represented for the transfer of optical excitation energy between donor and acceptor ions in ionic crystals. The physical assumptions which are necessary to deduce the phenomenological collective rate equations from the atomistic ones are specified. Time resolved measurements of the energy transfer from isolated Cr3+ ions to Cr3+ pairs in ruby are discussed. It is shown that, contrary to the present ideas, the collective rate equations cannot be applied in this case.
This study summarizes the theory of laser-amplifier noise based on the master equation, the quantum-mechanical Langevin equation, and the rate equation. The three approaches are used differently depending on the application. Laser-amplifier noise in the direct-detection receiver is described by the master equation. Meanwhile, the quantum-mechanical Langevin equation is most effective for analyzing noise appearing in coherent optical communication systems. The rate equation approach provides a clear understanding of the intensity-noise characteristics of laser oscillators, including the amplitude squeezing.
This study summarizes the theory of laser-amplifier noise based on the master equation, the quantum-mechanical Langevin equation, and the rate equation. The three approaches are used differently depending on the application. Laser-amplifier noise in the direct-detection receiver is described by the master equation. Meanwhile, the quantum-mechanical Langevin equation is most effective for analyzing noise appearing in coherent optical communication systems. The rate equation approach provides a clear understanding of the intensity-noise characteristics of laser oscillators, including the amplitude squeezing.