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Lecture notes in mathematics

Complete Positivity and the Markov structure of Open Quantum Systems

Rolando Rebolledo

Published Jan 1, 2006• 11 citations
Publisher
DOI
10.1007/3-540-33966-3_4

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Semi-Markov processes represent a well-known and widely used class of random processes in classical probability theory. Here, we develop an extension of this type of non-Markovian dynamics to the quantum regime. This extension is demonstrated to yield quantum master equations with memory kernels which allow the formulation of explicit conditions for the complete positivity of the corresponding quantum dynamical maps, thus leading to important insights into the structural characterization of the non-Markovian quantum dynamics of open systems. Explicit examples are analyzed in detail.
We investigate the mathematical structure of entropy-weighted quantum evolution within the framework of open quantum systems. Starting from a system–reservoir interaction model with weak entropy-coupled dynamics, we derive the reduced evolution of the system density matrix under the Born–Markov approximation. The resulting generatoris shown to be of Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) form, ensuring complete positivity and trace preservation. We further demonstrate that the associated dynamical semigroup admits both Stinespring dilation and Kraus operator representations, establishing that entropy-weighted reduced dynamics can be embedded into a fully unitary system environment framework. The entropy operator appearing in the effective description is identified with the positive-semidefinite dissipative structure induced by reservoir corre lation functions.The construction does not modify standard quantum mechanics but provides a parameterization of dissipative generators in terms of entropy-weighted couplings. This establishes a mathematically consis tent bridge between entropy-based dynamical formulations and conventional open quantum system theory.
We construct a large class of non-Markovian master equations that describe the dynamics of open quantum systems featuring strong memory effects, which relies on a quantum generalization of the concept of classical semi-Markov processes. General conditions for the complete positivity of the corresponding quantum dynamical maps are formulated. The resulting non-Markovian quantum processes allow the treatment of a variety of physical systems, as is illustrated by means of various examples and applications, including quantum optical systems and models of quantum transport.