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Physical Review A

Geometric phases for laser-induced aligned pendular states of linear molecules

Dmitriy V. Aleynikov

Published Feb 8, 2006• 0 citations
Publisher

Abstract

Geometric phases may arise in a linear molecule interacting via its anisotropic polarizability with a strong nonresonant laser field. When the polarization vector of laser radiation undergoes cyclic evolution, the molecule returns to its original state but may acquire a Berry or Aharonov-Anandan phase factor.
DOI
10.1103/physreva.73.022106

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Quantum eigenstates undergoing cyclic changes acquire a phase factor of geometric origin. This phase, known as the Berry phase, or the geometric phase, has found applications in a wide range of disciplines throughout physics, including atomic and molecular physics, condensed matter physics, optics, and classical dynamics. In this article, the basic theory of the geometric phase is presented along with a number of representative applications. The article begins with an account of the geometric phase for cyclic adiabatic evolutions. An elementary derivation is given along with a worked example for two-state systems. The implications of time-reversal are explained, as is the fundamental connection between the geometric phase and energy level degeneracies. We also discuss methods of experimental observation. A brief account is given of geometric magnetism; this is a Lorenz-like force of geometric origin which appears in the dynamics of slow systems coupled to fast ones. A number of theoretical developments of the geometric phase are presented. These include an informal discussion of fibre bundles, and generalizations of the geometric phase to degenerate eigenstates (the nonabelian case) and to nonadiabatic evolution. There follows an account of applications. Manifestations in classical physics include the Hannay angle and kinematic geometric phases. Applications in optics concern polarization dynamics, including the theory and observation of Pancharatnam's phase. Applications in molecular physics include the molecular Aharonov-Bohm effect and nuclear magnetic resonance studies. In condensed matter physics, we discuss the role of the geometric phase in the theory of the quantum Hall effect.
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In a quantum system initially in the n-th eigenstate, an adiabatic evolution of the Hamiltonian ensures that the system remains in the corresponding instantaneous eigenstate while acquiring a phase factor. This phase has two components: one resulting from standard time evolution and another associated with the dependence of the eigenstate on the varying Hamiltonian, known as the Berry phase. In this work, we explore the concept of geometric amplitudes in the context of a Hermitian Hamiltonian with imaginary eigenvalues. We introduce the notion of geometric amplitude and provide a novel derivation of this concept. Our study reveals that a system undergoing cyclic evolution under adiabatic conditions acquires an additional amplitude factor of purely geometric origin. To illustrate this idea, we apply it to a concrete case: a generalized harmonic oscillator.