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Journal of the Society of Chemical Industry

Hydrogen isotopes and the wave nature of matter

C. E. H. Bawn

Published Jul 13, 1934• 0 citations
Publisher
DOI
10.1002/jctb.5000532802

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An analytical solution to the problem of wave transport of matter through composite hyper-fine barriers is constructed. It is shown that, for a composite membrane consisting of two identical ultra-thin layers, there are always distances between the layers at which the resonant passage of one of the components is realized. Resonance makes it possible to separate de Broiler waves of particles with the same properties, which differ only in masses. Broad bands of hyper-selective separation of a hydrogen isotope mixture are found at the temperature of 40 K.
Abstract Motivated by the needs of atomic tritium sources for neutrino mass experiments and Doppler-free two-photon 1 S–2 S spectroscopy in atomic deuterium and tritium, we present calculations of energy-dependent elastic scattering cross sections of hydrogen isotopes (H, D, and T) on helium isotopes ( 3 He and 4 He) in the temperature range 1 mK to 300 K. The tritium-on-helium cross sections are found to be enhanced over their hydrogen-on-helium counterparts by a near-threshold resonant s -wave bound state at low energy, similar to one that has been predicted in the triplet T–T system. While the energy-dependent cross sections span a wide range at low energy due to this s -wave enhancement, they tend toward a common value at high energy where the scattering becomes effectively geometric in nature.