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Physica Scripta

Linear superpositions of states in radiative processes

Claude N. Cohen-Tannoudji

Published Jan 1, 1997• 3 citations
Publisher

Abstract

When an atom, in a linear superposition of states, absorbs or emits light, interference can occur between two different absorption or emission amplitudes, giving rise to observable physical effects, such as level crossing resonances, quantum beats, and dark states. Early experimental demonstrations of effects of this kind, using an optical detection of the atomic internal state, are briefly reviewed. In fact, such interference effects are still playing a fundamental role in modern developments, such as laser cooling and trapping. We present in this paper a few examples of such applications, including the mechanical Hanle effect, velocity selective resonances for an atom moving in a standing wave and subrecoil laser cooling by Velocity Selective Coherent Population Trapping (VSCPT).

DOI
10.1088/0031-8949/1997/t70/012

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ABSTRACT In this work we present an investigation of velocity-selective coherent population trapping (VSCPT) in asym- metric three-level schemes. The light force in such schemes is of an intrinsically transient character and shouldnot be described in a quasiclassical approach. Instead, results of the full quantum-mechanical calculations are presented with emphasis on their meaning to the efficiency of subrecoil laser cooling. 1 INTRODUCTION Laser cooling of neutral atoms has received significant advances by the introduction of velocity-selectivecoherent population trapping ((VSCPT) some years ago.1 Since it leads to atomic temperatures well below therecoil limit, studies of ultracold atoms and atomic interactions may be improved by magnitudes.The effect of VSCPT relies on optical pumping of atoms into a state WNC) which is a trap state for a certaincenter-of-mass velocity vO. This trap state is created by a destructive superposition of atomic states within amultilevel quantum system. Once being in such a state LWNC) the laser light does not interact anymore with theatom which leads to a decoupling with the rest of the system at vo. Atoms located outside this small velocityregion get a chance to be trapped by the momentum diffusion due to spontaneous emission of photons. Aftera sufficient long interaction time nearly all atoms are trapped inside a narrow momentum distribution whichcan be interpreted as cooling. The theoretical and experimental investigation of VSCPT is usually consideredby use of a three-level A-system as shown in Fig.1. Such a system can be found for example in a symmetrical

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE•Jan 1, 1996•0 citations
When an atom, in a linear superposition of states, absorbs or emits light, interference can occur between two different absorption or emission amplitudes, giving rise to observable physical effects, such as level crossing resonances, quantum beats, and dark states. Early experimental demonstrations of effects of this kind, using an optical detection of the atomic internal state, are briefly reviewed. In fact, such interference effects are still playing a fundamental role in modern developments, such as laser cooling and trapping. We present in this paper a few examples of such applications, including the mechanical Hanle effect, velocity selective resonances for an atom moving in a standing wave and subrecoil laser cooling by Velocity Selective Coherent Population Trapping (VSCPT).
Dark states were first observed in optical pumping experiments and interpreted as a quenching of fluorescence due to a destructive interference between two absorption amplitudes connecting two ground state sublevels g1 and g2 to an excited sublevel e. The atom can absorb light from g1 and jump to e. Similarly, it can absorb light from g2 and jump to e. But, if it is in a certain linear superposition of g1 and g2, , the two absorption amplitudes from g1 to e and from g2 to e interfere destructively and cancel out. The fluorescence stops. The state from which light cannot be absorbed is called a dark state. This paper will start with a description of the first experiments demonstrating the existence of dark states and of the first theoretical interpretations that have been proposed. Dark states appeared to play an essential role in several new physical effects, such as electromagnetically induced transparency, slow light, stimulated Raman adiabatic passage (STIRAP), which will be briefly described. A special emphasis will be given to the applications of dark states in the field of ultracold atoms and molecules. It will be first shown how the use of velocity dependent dark states allows atoms to be cooled below the so-called recoil limit, corresponding to a velocity dispersion of the cooled atoms smaller than the recoil momentum communicated to the atom by the absorption of a single photon. It turned out that a quantitative interpretation of this subrecoil cooling may be given in terms of anomalous random walks and Lévy statistics. Finally, recent applications of dark states to the production of ultracold molecules will be described: production of ultracold polar molecules by the combination of Feshbach resonances and STIRAP; dark states in the photo-association of ultracold atoms allowing a precise determination of the scattering length describing their collisions.
Quantum coherence and correlations in atomic and radiation physics have led to many interesting and unexpected consequences. For example, an atomic ensemble prepared in a coherent superposition of states yields the Hanle effect, quantum beats, photon echo, self-induced transparency, and coherent Raman beats. In fact, in Section 1.4, we saw that the quantum beat effect provides one of the most compelling reasons for quantizing the radiation field. A further interesting consequence of preparing an atomic system in a coherent superposition of states is that, under certain conditions, it is possible for atomic coherence to cancel absorption. Such atomic states are called trapping states †. The observation of nonabsorbing resonances via atomic coherence and interference impacts on the concepts of lasing without inversion (LWI),‡ enhancement of the index of refraction accompanied by vanishing absorption, and electromagnetically induced transparency. In lasing without inversion, the essential idea is the absorption cancellation by atomic coherence and interference. This phenomenon is also the essence of electromagnetically induced transparency. Usually this is accomplished in three-level atomic systems in which there are two coherent routes for absorption that can destructively interfere, thus leading to the cancellation of absorption. A small population in the excited state can thus lead to net gain. A related phenomenon is that of resonantly enhanced refractive index without absorption in an ensemble of phase-coherent atoms ( phaseonium ). In a phaseonium gas with no population in the excited level, the absorption cancellation always coincides with vanishing refractivity.
We discuss the connection between quantum interference effects in optical beams and radiation fields emitted from atomic systems. We illustrate this connection by a study of the first- and second-order correlation functions of optical fields and atomic dipole moments. We explore the role of correlations between the emitting systems and present examples of practical methods to implement two systems with non-orthogonal dipole moments. We also derive general conditions for quantum interference in a two-atom system and for a control of spontaneous emission. The relation between population trapping and dark states is also discussed. Moreover, we present quantum dressed-atom models of cancellation of spontaneous emission, amplification on dark transitions, fluorescence quenching and coherent population trapping.
The appearance of quantum interference in the microscopic world is one of the deepest mysteries at the very root of quantum mechanics. When light interacts with atoms, it can induce transitions by way of distinct but indistinguishable pathways and yield unexpected and often counter-intuitive results. Electromagnetically Induced Transparency (EIT), Coherent Population Trapping (CPT), and Lasing Without Inversion (LWI) are modern examples of phenomena where the traditional rules that govern absorption and dispersion undergo major revisions. Spectacular consequences of this new state of affairs include the ability of a light beam to propagate through a normally absorbing medium with little or no absorption, or to undergo amplification even if the active medium is not prepared in a state of population inversion. Light signals have been shown to travel with strongly subluminal group velocities of only a handful of meters per second and, even, to propagate at speed greater than the ordinary speed of light, but without violation of causality or of the established rules that control the transfer of optical information through space. Three-level atoms can interact with two coherent electromagnetic fields according to three different systems, known as Cascade, Lambda and Vee systems. The propagation of a weak probe field can be deeply affected by the presence of a second stronger beam, the so-called coupling field. Transparency windows, splitting of emission and absorption lines and enormously enhanced dispersion have been documented in numerous experiments. In this thesis we explore the physical origin of the transparency induced in these systems by the simultaneous interplay of the coupling and probe fields. We focus our attention on the Cascade system and study its two configurations, Cascade-EIT and Cascade-AT. We develop a variety of complementary approaches for the description of these two configurations, some semiclassical and others fully quantum mechanical. We prove the existence of quantum interference in Electromagnetically Induced Transparency and also the surprising absence of interference in a closely related phenomenon, known as the Autler-Townes effect. Finally we complement the traditional machinery of theoretical quantum optics with techniques borrowed from quantum scattering theory, and offer what we believe is the most convincing physical evidence for the appearance, or for the absence, of quantum interference effects.
A theory of matter-wave interference is developed in which resonant, standing-wave optical fields interact with an ensemble of two-level atoms. If effects related to the recoil the atoms undergo on absorbing or emitting radiation are neglected, the total atomic density is spatially uniform. However, when recoil effects are included, spatial modulation of the atomic density can occur for times that are greater than or comparable to the inverse recoil frequency. In this regime, the atoms exhibit matter-wave interference that can be used as the basis of a matter-wave atom interferometer. Two specific atom-field geometries are considered, involving either one or two field-interaction zones. For each geometry, the recoil-induced spatial modulation of the total atomic density is calculated. In contrast to the normal Talbot and Talbot-Lau effects, the spatially modulated density is nota periodic function of time, owing to spontaneous emission; however, after a sufficiently long time, the contribution from spontaneous processes no longer plays a role and the periodicity is restored. With a suitable choice of observation time and field strengths, the spatially modulated atomic density serves as an indirect probe of the distribution of spontaneously emitted radiation.
ABSTRACT In this work we present an investigation of velocity-selective coherent population trapping (VSCPT) in asym- metric three-level schemes. The light force in such schemes is of an intrinsically transient character and shouldnot be described in a quasiclassical approach. Instead, results of the full quantum-mechanical calculations are presented with emphasis on their meaning to the efficiency of subrecoil laser cooling. 1 INTRODUCTION Laser cooling of neutral atoms has received significant advances by the introduction of velocity-selectivecoherent population trapping ((VSCPT) some years ago.1 Since it leads to atomic temperatures well below therecoil limit, studies of ultracold atoms and atomic interactions may be improved by magnitudes.The effect of VSCPT relies on optical pumping of atoms into a state WNC) which is a trap state for a certaincenter-of-mass velocity vO. This trap state is created by a destructive superposition of atomic states within amultilevel quantum system. Once being in such a state LWNC) the laser light does not interact anymore with theatom which leads to a decoupling with the rest of the system at vo. Atoms located outside this small velocityregion get a chance to be trapped by the momentum diffusion due to spontaneous emission of photons. Aftera sufficient long interaction time nearly all atoms are trapped inside a narrow momentum distribution whichcan be interpreted as cooling. The theoretical and experimental investigation of VSCPT is usually consideredby use of a three-level A-system as shown in Fig.1. Such a system can be found for example in a symmetrical