Abstract We present a systematic formalism for the computation of the density matrix of an N-state quantum system in the presence of classical noise or a coupling to the environment. In this formalism, the density matrix of the system is given as an expansion in the generators of the SU(N) group with real coefficients. This leads to a system of master equations. The parameters in these equations may be approximately expressed in terms of the components of the Redfield tensor, when the Born and Markov approximations are valid. The general form of the solution of the system of master equations is established. All relaxation and dephasing rates are then very simply expressed as eigenvalues of a certain matrix. This gives the formulation its simplicity and makes it uniquely suitable for numerical computation. The spectral representation of the components of the Redfield tensor is derived in the case when the environment is a harmonic oscillator bath in thermal equilibrium. Beyond the Born approximation, the decoherence of the system is determined by the Lindblad formula for the Liouvillian superoperator. The Lindblad formulae of some models of multi-state quantum systems are also presented.
Abstract We present a systematic formalism for the computation of the density matrix of an N-state quantum system in the presence of classical noise or a coupling to the environment. In this formalism, the density matrix of the system is given as an expansion in the generators of the SU(N) group with real coefficients. This leads to a system of master equations. The parameters in these equations may be approximately expressed in terms of the components of the Redfield tensor, when the Born and Markov approximations are valid. The general form of the solution of the system of master equations is established. All relaxation and dephasing rates are then very simply expressed as eigenvalues of a certain matrix. This gives the formulation its simplicity and makes it uniquely suitable for numerical computation. The spectral representation of the components of the Redfield tensor is derived in the case when the environment is a harmonic oscillator bath in thermal equilibrium. Beyond the Born approximation, the decoherence of the system is determined by the Lindblad formula for the Liouvillian superoperator. The Lindblad formulae of some models of multi-state quantum systems are also presented.
Abstract This chapter is dedicated to open quantum systems. We explain the origin of non-unitary time evolution by studying different interactions between a qubit and the environment. The first part of the chapter introduces the time evolution equation of an open quantum system, also called the Born-Markov master equation and the Redfield equation. We then study the interaction between a qubit and a thermal bath of harmonic oscillators and introduce the qubit relaxation and the dephasing times. After discussing the relationship between relaxation and dephasing times of a qubit and the power spectral density of the noise source, we present the Hahn echo and the Carr-Purcell-Meiboom-Gill experiments, two protocols that provide information about the noise spectrum. The chapter ends with a discussion of the driven evolution of a qubit subject to spontaneous emission and dephasing
Markovian quantum master equations are generally thought to satisfy the following three conditions: (i) they describe the dynamics of time scales that are larger than the reservoir correlation time scale, (ii) these stationary solutions give the thermal equilibrium states with a reservoir, and (iii) they can be written in the Lindblad form. In fact, for single systems such as a single harmonic oscillator and a single two-level system, Markovian quantum master equations satisfying all these conditions can be obtained. However, for composite systems, which consist of more than one subsystem coupled with each other, such equations have not been obtained thus far. In this study, we found that we cannot use the Born–Markov approximation for obtaining quantum master equations for composite systems in the strong-coupling regime, no matter how short the reservoir correlation time is.
We develop a Markovian master equation in the Lindblad form that enables the efficient study of a wide range of open quantum many-body systems that would be inaccessible with existing methods. The validity of the master equation is based entirely on properties of the bath and the system-bath coupling, without any requirements on the level structure within the system itself. The master equation is derived using a Markov approximation that is distinct from that used in earlier approaches. We provide a rigorous bound for the error induced by this Markov approximation; the error is controlled by a dimensionless combination of intrinsic correlation and relaxation timescales of the bath. Our master equation is accurate on the same level of approximation as the Bloch-Redfield equation. In contrast to the Bloch-Redfield approach, our approach ensures preservation of the positivity of the density matrix. As a result, our method is robust, and can be solved efficiently using stochastic evolution of pure states (rather than density matrices). We discuss how our method can be applied to static or driven quantum many-body systems, and illustrate its power through numerical simulation of a spin chain that would be challenging to treat by existing methods.
The Lindblad theory of open quantum systems has been successfully applied in various fields ranging from quantum optics, condensed matter physics, and quantum thermodynamics to quantum chemistry. Nevertheless, there are situations where we can compare its predictions to those of exact methods or numerically exact results and find discrepancies between them. One example is the case where a single harmonic oscillator is coupled to a thermal bath of independent harmonic oscillators. In this case, for certain parameters, the exact master equation describes equilibration of the system to a thermal state with a temperature different from the one predicted by the Lindblad master equation. The Lindblad theory, based on a weak coupling between the system and environment as well as the Born-Markov approximation, predicts that the system will evolve to a thermal state whose temperature is equal to the initial temperature of the bath. This result is a consequence of the Born approximation, which supposes that throughout the evolution, the bath only fluctuates around its initial equilibrium state. In this master thesis we study the validity of the Born approximation as well as its consistency with other approximations. By starting from a Hamiltonian for the total system we show that, if the the Born approximation is not invoked, the dynamics of the system is determined by a hierarchy of equations for matrices which can be used to reconstruct the reduced density matrix of the system. This hierarchy approach is fundamentally different from the standard approach, which describes the system dynamics with a weak-coupling master equation, because the hierarchy does not restrict the amount of entanglement possible between the system and the environment. Furthermore, we show how invoking the Born approximation reduces to the usual result and how a generalised ansatz, which we refer to as a generalised Born approximation, reduces the hierarchy to a master equation where the bath temperature is an additional degree of freedom. Finally, we analyse the conservation of the energy of the total system and its relationship to the Markov and secular approximations, and discuss whether imposing it as a condition can fix the time-dependent temperature.
Abstract Chapter 22 investigates the dynamics of open quantum systems that interact with their environment. We discuss the time-evolution of the joint system in terms of a time-ordered exponential of an integral over the Hamiltonian and determine a similar formulation for a Liouvillian super-operator. Based on these ideas we develop the notion of dynamical maps and apply the Born-Markov approximation to arrive at a dynamical semi-group and general Markovian master equations. We then turn to a specific example of such an equation of motion for the density operator: the Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) equation which captures both dissipative dynamics and decoherence using Lindblad operators. We employ the GKLS equation to model the absorption, and spontaneous as well as stimulated emission of radiation by a two-level atom. We then discuss the Jaynes-Cummings model that describes the interaction of such an atom with a single mode of the electromagnetic field in a cavity
We develop a systematic field-theoretical approach to open quantum systems based on condensed-matter many-body methods. The time evolution of the reduced density matrix for the open quantum system is determined by a transmission matrix. Developing diagrammatic perturbation theory, invoking Wick's theorem in connection with a Caldeira-Leggett quantum oscillator environment in thermal equilibrium, the transmission matrix satisfies a Dyson equation characterized by an irreducible kernel. Unlike the Nakajima-Zwanzig and standard approaches, the Dyson equation is equivalent to a general non-Markovian master equation for the reduced density matrix, incorporating secular effects and independent of the initial preparation. The kernel is determined by a systematic diagrammatic expansion in powers of the interaction. We consider the Born approximation for the kernel. Applying a condensed-matter pole or, equivalently, a quasiparticle-type approximation, equivalent to the usual assumption of a timescale separation, we derive a master equation of the Markov type. Furthermore, imposing the rotating-wave approximation, we obtain a Markov master equation of the Lindblad form. To illustrate the method, we consider the standard example of a single qubit coupled to a thermal heat bath.