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Modern Physics Letters B

GENERALIZED PARTITION FUNCTION FOR BOSE STATISTICS AND THERMODYNAMIC FUNCTIONS

Hong-Yi Fan, HUI ZOU

Published Dec 30, 1999• 3 citations
Publisher

Abstract

Based on the density operator's coherent state representation [Phys. Lett.A252, 281 (1999)], we extend the well-known Bose distribution's partition function Ξ [Formula: see text] for ideal photon gas [Formula: see text] to that of an assembly of photon gas interacting with nonlinear medium described by the Hamiltonian [Formula: see text], where A=(a1,a2,…,an), Ω is a symmetric matrix, and we report that the corresponding partition function is [Formula: see text] As a result, the generalized Bose distribution and thermodynamic functions are derived.

DOI
10.1142/s0217984999001305

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Based on the density operator's coherent state representation [Phys. Lett.A252, 281 (1999)], we extend the well-known Bose distribution's partition function Ξ [Formula: see text] for ideal photon gas [Formula: see text] to that of an assembly of photon gas interacting with nonlinear medium described by the Hamiltonian [Formula: see text], where A=(a1,a2,…,an), Ω is a symmetric matrix, and we report that the corresponding partition function is [Formula: see text] As a result, the generalized Bose distribution and thermodynamic functions are derived.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
We analyze the so-called classical limit of the quantum-mechanical canonical partition function. In order to do that, we define accurately the density matrix for symmetrized and antisymmetrized wave functions only (Bose-Einstein and Fermi-Dirac), and find an exact relation between them and the density matrix for non symmetrized functions (Maxwell-Boltzmann). Our results differ from the generally assumed in a numerical factor N!, for which we suggest a physical interpretation. We derive as well the reverse (and also exact) relation, to find the canonical partition function for non-symmetrized wave functions in terms of the corresponding function for fermions and bosons.
The relation between the Wigner cistribution function and the P-representation of the density matrix for describing a boson system is investigated. The coherent-state representation of the density matrix is introduced for a Bose particle system. Especially the P-representation of the density matrix describing an ideal boson system in thermal equilibrium is obtained. It can be seen that the distribution function of the complex eigenvalues of the destruction operator is non-negative in this particular case. The coherent-state representation of the Wigner function is then obtained. The coherent-state representation of the components in the decomposition of the Wigner function is also found. The London-Placzek formula can be derived by using one of these components.
Recursive approaches determining the canonical ideal Bose gas partition function are reviewed that enable the Bose–Einstein condensate occupation probability to be calculated for a finite number of particles ensemble, where the thermodynamic limit approximation fails. In addition to the earlier known method recursive with respect to the number of particles, an iteration procedure with respect to the number of quantum states is proposed. The efficiency of both methods is demonstrated for an ideal Bose gas in a three-dimensional isotropic harmonic trap.
We present a microscopic derivation of the master equation for the condensate density matrix for an interacting Bogoliubov-Bose gas of N atoms. We choose the interaction Hamiltonian in a special way that substantially simplifies the master equation, yielding no coupling between diagonal and off-diagonal terms. The present formulation allows us to solve the problem analytically in a steady state and obtain the expression for the distribution function and equilibrium condensate fluctuations. For the first two central moments, our results are equivalent to those obtained in the canonical-ensemble quasiparticle formalism [V. V. Kocharovsky, Vl. V. Kocharovsky, and M. O. Scully, Phys. Rev. Lett. 84, 2306 (2000); Phys. Rev. A 61, 053606 (2000)], in the low-temperature range where these papers are valid, but also give an accurate description at high temperatures. The present analysis for an interacting Bose gas is as accurate as the master equation approach of Kocharovsky et al. [Phys. Rev. A 61, 023609 (2000)] is for an ideal gas.