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International Journal of Quantum Chemistry

On the time‐dependent solutions of the Schrödinger equation. I. The linear time‐dependent potential

A. Palma, M. Villa, L. Sandoval

Published Jul 8, 2010• 7 citations
Publisher

Abstract

Abstract The solution of the Schrödinger equation for the linear time‐dependent potential has recently been the subject of several publications. In this report, we show this is one of the few systems that leads to a solvable Lie algebra. In fact, we consider a more general problem where the linear time‐dependent potential is only a particular case. The solution is found by using the well‐known theorem of Wei‐Norman. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2010

DOI
10.1002/qua.22781

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By making use of the Lewis-Riesenfeld invariant theory, the solution of the Schrödinger equation for the time-dependent linear potential corresponding to the quadratic-form Lewis-Riesenfeld invariant $I_{\rm q}(t)$ is obtained in the present paper. It is emphasized that in order to obtain the general solutions of the time-dependent Schrödinger equation, one should first find the complete set of Lewis-Riesenfeld invariants. For the present quantum system with a time-dependent linear potential, the linear $I_{\rm l}(t)$ and quadratic $I_{\rm q}(t)$ (where the latter $I_{\rm q}(t)$ cannot be written as the squared of the former $I_{\rm l}(t)$, {\it i.e.}, the relation $I_{\rm q}(t)= cI_{\rm l}^{2}(t)$ does not hold true always) will form a complete set of Lewis-Riesenfeld invariants. It is also shown that the solution obtained by Bekkar {\it et al.} more recently is the one corresponding to the linear $I_{\rm l}(t)$, one of the invariants that form the complete set. In addition, we discuss some related topics regarding the comment [Phys. Rev. A {\bf 68}, 016101 (2003)] of Bekkar {\it et al.} on Guedes's work [Phys. Rev. A {\bf 63}, 034102 (2001)] and Guedes's corresponding reply [Phys. Rev. A {\bf 68}, 016102 (2003)].

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Comment on "Solutions of the Schrödinger equation for the time-dependent linear potential''

Jian Qi Shen

We show that the solution obtained by Bekkar {\it et al.} in their comment [Phys. Rev. A {\bf 68}, 016101 (2003)] on Guedes's work of solving the quantum system with a time-dependent linear potential is still {\it not} the {\it general} one of the Schrödinger equation. It is concluded that Bekkar {\it et al.}'s solution (corresponding to the linear Lewis-Riesenfeld invariant) and our solution (corresponding to the quadratic-form Lewis-Riesenfeld invariant) presented here will constitute together a complete set of solutions (general solutions) of the time-dependent Schrödinger equation of the system under consideration.

arXiv:quant-ph/0311002•Nov 1, 2003•0 citations
Abstract The solution of the Schrödinger equation for the linear time‐dependent potential has recently been the subject of several publications. In this report, we show this is one of the few systems that leads to a solvable Lie algebra. In fact, we consider a more general problem where the linear time‐dependent potential is only a particular case. The solution is found by using the well‐known theorem of Wei‐Norman. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2010
Abstract The solution of the time‐dependent Schrödinger's equation for a perturbed harmonic oscillator is obtained using a solvable Lie algebra. We choose a harmonic oscillator interacting with a one‐mode field, where the perturbation happens to be periodic in time. This leads to one of the simplest Floquet problems. Using the Wei–Norman theorem, the Floquet wave function is obtained as well as the semiclassical Floquet shift in the energy. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2011
Abstract In this article, we introduce a simple analytic method for obtaining approximate solutions of the Schrödinger equation for a wide range of potentials in one‐ and two‐dimensions. We define an operator, called the iteration operator, which will be used to solve for the lowest order state(s) of a system. The method is simple in that it does not require the computation of any integrals in order to obtain a solution. We use this method on several potentials which are well understood or even exactly solvable in order to demonstrate the strengths and weaknesses of this method. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2009
We solve the Schrodinger equation analytically for systems whose potentials have a certain time-dependence (which is monotonously decreasing) and general coordinate-dependences.Only a few time-dependent systems have been reported to be analytically solved whose potentials are constant, linear, and quadratic functions of coordinate with arbitrary time-dependences.From a different perspective, we focus on the time-dependent systems whose potentials are monotonously decreasing functions of time with arbitrary coordinate dependences.Time-dependent potential of any coordinate-dependence can be handled analytically by transforming it to a time-independent potential of known solutions if its time-dependence is monotonously decreasing.We do this by a unitary transformation of the wavefunction and variable transformations to change the Schrodinger equation to be time-independent in new variables.These variables are then determined by solving a set of simple differential equations.This way we are able to find and to obtain analytical solutions for time-dependent potentials which we mention above.
A representation of invariants in quantum mechanics for a general time-dependent Hamiltonian is provided. The main properties of these operators and their relevance for solving the Schrödinger equation are discussed in light of this representation. In particular, the well-known Lewis and Riesenfeld’s method is shown to be recovered quite directly by the present approach. A detailed analysis is concerned with Hamiltonians which at each instant are elements of a finite dimensional Lie algebra. Exploiting the Wei and Norman’s theory for such Hamiltonians, it is found that the evolution of a quantum system is always determined, in part or fully, by an invariant which belongs to the same algebra.
By making use of the Lewis-Riesenfeld invariant theory, the solution of the Schrödinger equation for the time-dependent linear potential corresponding to the quadratic-form Lewis-Riesenfeld invariant Iq(t)I_{\rm q}(t)Iq​(t) is obtained in the present paper. It is emphasized that in order to obtain the general solutions of the time-dependent Schrödinger equation, one should first find the complete set of Lewis-Riesenfeld invariants. For the present quantum system with a time-dependent linear potential, the linear Il(t)I_{\rm l}(t)Il​(t) and quadratic Iq(t)I_{\rm q}(t)Iq​(t) (where the latter Iq(t)I_{\rm q}(t)Iq​(t) cannot be written as the squared of the former Il(t)I_{\rm l}(t)Il​(t), {\it i.e.}, the relation Iq(t)=cIl2(t)I_{\rm q}(t)= cI_{\rm l}^{2}(t)Iq​(t)=cIl2​(t) does not hold true always) will form a complete set of Lewis-Riesenfeld invariants. It is also shown that the solution obtained by Bekkar {\it et al.} more recently is the one corresponding to the linear Il(t)I_{\rm l}(t)Il​(t), one of the invariants that form the complete set. In addition, we discuss some related topics regarding the comment [Phys. Rev. A {\bf 68}, 016101 (2003)] of Bekkar {\it et al.} on Guedes's work [Phys. Rev. A {\bf 63}, 034102 (2001)] and Guedes's corresponding reply [Phys. Rev. A {\bf 68}, 016102 (2003)].
We show that the solution obtained by Bekkar {\it et al.} in their comment [Phys. Rev. A {\bf 68}, 016101 (2003)] on Guedes's work of solving the quantum system with a time-dependent linear potential is still {\it not} the {\it general} one of the Schrödinger equation. It is concluded that Bekkar {\it et al.}'s solution (corresponding to the linear Lewis-Riesenfeld invariant) and our solution (corresponding to the quadratic-form Lewis-Riesenfeld invariant) presented here will constitute together a complete set of solutions (general solutions) of the time-dependent Schrödinger equation of the system under consideration.