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Basic quantum Hamiltonian's relativistic corrections

Gintautas Kamuntavičius

Published Feb 3, 2013• 0 citations
OpenAlex

Abstract

After analyzing Dirac’s equation, one can suggest that a well-known quantum-mechanical momentum operator is associated with relativistic momentum, rather than with non-relativistic one. Consideration of relativistic energy and momentum expressions allows us to define the non

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According to non-relativistic quantummechanics, the evolution of the wave function of a free particle of mass m and momentum p is described by the Schro¨dinger equation: i ∂ψ ∂t = Hψ , (6.1) with the Hamiltonian operator H = −∇2/2m obtained from the expression for energy E = p2 2m , (6.2) using the substitution E → i ∂ ∂t , p → −i∇ . (6.3) Schro¨dinger himself [6] first suggested a generalisation of equation (6.1) based on the use of the relativistic energy equation: E2 = p2 +m2 . (6.4) (+m2)ψ = 0 , (6.5) Multiplying by ψ∗ and subtracting the product of ψ and the complex conjugate of (6.5) from the result, the continuity equation is obtained ∂ρ ∂t = ∇j , (6.6) with ρ = ψ∗ ∂ψ ∂t − ψ∂ψ ∂t (6.7) and j = −∇ (ψ∗∇ψ − ψ∇ψ∗) . (6.8) However, the ρ which appears in equation (6.6) cannot be identified with the probability density, in analogy with the similar quantity obtained from the Schro¨dinger equation, because it does not have the required property of being always positive-definite. To be convinced of this it is sufficient to substitute i∂/∂t→ E in (6.7). The result, ρ = E|ψ|2 , shows that ρ can be either positive or negative, following from the fact that the Klein-Gordon equation has solutions for the energy with both signs E = ± √ p2 +m2 , Note that in the non-relativistic limit E ≈ m > 0, and the familiar result ρ ∝ |ψ|2 is recovered.
After analyzing Dirac's equation, one can suggest that a well-known quantum-mechanical momentum operator is associated with relativistic momentum, rather than with non-relativistic one. Consideration of relativistic energy and momentum expressions allows us to define the non-relativistic, relativistic and pseudo-relativistic (present in Schrödinger equation) kinetic energy operators. Consequences of kinetic energy operator's correction for spectra of basic quantum Hamiltonians are investigated. In some cases this correction can produce remarkable spectra modifications.
A realistic interpretation of Schroedinger and Dirac equations for density matrices is proposed, in which the difference between the position arguments of the density matrix is considered as an objective extra space dimension. "Particle" solutions are found, which are perfectly localized both in position space and in momentum space (the position and momentum operators commute in the density matrix representation); definitions for all observable quantities are given and the values associated to the "particle" solutions are the correct ones, both for the non-relativistic and the relativistic case. Finally, a non-linear interaction (the electromagnetic one) is introduced in an attempt to single out the "particle" solutions of the Dirac equation from all other solutions; the dynamical evolution of the electromagnetic field is described by the classical (unquantized) Maxwell equations.