We investigate a two-level system in contact with a larger quantum environment, often consisting of many two-level systems itself (spin environment) which may or may not interact. The total system is considered to be closed. The environment typically is in a canonical state with a given temperature initially. Depending on the precise spectral structure of the environment and the type of coupling between both systems, the smaller part may relax to a canonical state with the same temperature as the environment (i.e., thermal relaxation) or to some other quasiequilibrium state (nonthermal relaxation). The type of (quasi)equilibrium state can be related to the distribution of certain properties of the energy eigenvectors of the total system. We examine these distributions for several abstract and concrete (spin environment) Hamiltonian systems; the significant aspect of these distributions can be related to the relative strength of the local and interaction parts of the Hamiltonian.
We investigate a two-level system in contact with a larger quantum environment, often consisting of many two-level systems itself (spin environment) which may or may not interact. The total system is considered to be closed. The environment typically is in a canonical state with a given temperature initially. Depending on the precise spectral structure of the environment and the type of coupling between both systems, the smaller part may relax to a canonical state with the same temperature as the environment (i.e., thermal relaxation) or to some other quasiequilibrium state (nonthermal relaxation). The type of (quasi)equilibrium state can be related to the distribution of certain properties of the energy eigenvectors of the total system. We examine these distributions for several abstract and concrete (spin environment) Hamiltonian systems; the significant aspect of these distributions can be related to the relative strength of the local and interaction parts of the Hamiltonian.
We investigate a two-level system in resonant contact with a larger environment. The environment typically is in a canonical state with a given temperature initially. Depending on the precise spectral structure of the environment and the type of coupling between both systems, the smaller part may relax to a canonical state with the same temperature as the environment (i.e., thermal relaxation) or to some other quasiequilibrium state (nonthermal relaxation). The type of (quasi)equilibrium state can be related to the distribution of certain properties of the energy eigenvectors of the total system. We examine these distributions for several abstract and concrete (spin environment) Hamiltonian systems; the significant aspect of these distributions can be related to the relative strength of the local and interaction parts of the Hamiltonian.
We investigate the decoherence of a spin- 1/2 subsystem weakly coupled to an environment of many spins- 1/2 with and without mutual coupling. The total system is closed, its state is pure, and evolves under Schrödinger dynamics. Nevertheless, the considered spin typically reaches a quasistationary equilibrium state. Here we show that this state depends strongly on the coupling to the environment on the one hand and on the coupling within the environmental spins on the other. In particular we focus on spin star and spin ring-star geometries to investigate the effect of intra-environmental coupling on the central spin. By changing the spectrum of the environment, its effect as a bath on the central spin is also changed and may even be adjustable to some degree. We find that the relaxation behavior is related to the distribution of the energy eigenstates of the total system. For each of these relaxation modes, there is a dual mode for which the resulting subsystem approaches an inverted state occupation probability (negative temperature).
The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.
We examine the effect of multilevels on decoherence and dephasing properties of a quantum system consisting of a non-ideal two level subspace, identified as the qubit and a finite set of higher energy levels above this qubit subspace. The whole system is under interaction with an environmental bath through a Caldeira-Leggett type coupling. The model interaction we use can generate nonnegligible couplings between the qubit states and the higher levels upto N∼10. In contrast to the pure two-level system, in a multilevel system the quantum information may leak out of the qubit subspace through nonresonant as well as resonant excitations induced by the environment. The decoherence properties of the qubit subspace is examined numerically using the master equation formalism of the system's reduced density matrix. We numerically examine the relaxation and dephasing times as the environmental frequency spectrum, the environmental temperature, and the multilevel system parameters are varied. We observe the influence of all energy scales in the noise spectrum on the short time dynamics implying the dominance of nonresonant transitions at short times. The relaxation and dephasing times calculated, strongly depend on N for 4<N<10 and saturate for $10
It is known that the origin of the deviations from standard thermodynamics proceed from the strong coupling to the bath. Here, it is shown that these deviations are related to the power spectrum of the bath. Specifically, it is shown that the system thermal-equilibrium-state cannot be characterized by the canonical Boltzmann's distribution in quantum mechanics. This is because the uncertainty principle imposed a lower bound of the dispersion of the total energy of the system that is dominated by the spectral density of the bath. However, in the classical case, for a wide class of systems that interact via central forces with pairwise-self-interacting environment, the system thermal equilibrium state is exactly characterized by the canonical Boltzmann distribution. As a consequence of this analysis and taking into account all energy scales in the system and reservoir interaction, an effective coupling to the environment is introduced. Sample computations in different regimes predicted by this effective coupling are shown. Specifically, in the strong coupling effective regime, the system exhibits deviations from standard thermodynamics and in the weak coupling effective regime, quantum features such as stationary entanglement are possible at high temperatures. Moreover, it is known that the spectrum of thermal baths depends on the non-Markovian character. Hence, non-Markovian interactions have a important role in the thermal equilibrium state of physical systems. For example, in quantum optomechanics is looked up to cool the mechanical system through an auxiliary system which generally is a cavity. This cooling process takes into account the non-Markovian interaction and as it is shown here, it is more effective than if we use only the Markovian approximation in the equation of motion for the different modes.
The rather new field of quantum thermodynamics intends to derive thermodynamics from quantum mechanics, as well as to study thermodynamical behavior of quantum systems. It turns out that, indeed, thermalization can be obtained even for very small quantum systems due to the interaction with an appropriate environment. The consideration of an ensemble, as in statistical mechanics, is not necessary. However, the total system - consisting of system and environment - in quantum thermodynamics is usually considered to be closed. In particular, there exists no interaction with an external observer. Since quantum measurements typically influence the measured system, one may wonder which influence such an observation will have in the quantum thermodynamical setting. In this thesis, we study this influence of measurements in quantum thermodynamical systems. It turns out that various concepts known from statistical mechanics arise from such a "quantum thermodynamics under observation", although they do not have any meaning in the isolated quantum thermodynamical setting. The model discussed in the first part consists of a two-level system coupled to a large spin environment, the magnetization of which is measured periodically. This leads to quasi-classical trajectories for the system and - as in statistical mechanics - thermalization and temperature only have a meaning in terms of an ensemble average or a long-time average. Calculating these averages, we prove the ergodicity of the system. Interestingly, the entropy of the obtained attractor state depends on the time between the measurements and can be shown to be connected with the subjective lack of knowledge of the observer. In case of optimal measurements, the ensemble averaged state of the system under periodic measurements equals the state of the system in the quantum thermodynamical model without measurements. Introducing a detuning between system and environment, we find that the system can be prepared in almost arbitrary thermal states due to the periodic measurements. Even the creation of inversion becomes possible. As shown in numerical simulations, our results, which were analytically obtained for large environments, are even applicable to describe the behavior of the system coupled to small environments consisting of only a few spins. Besides measurements of the environment, we also study direct projective measurements of the system, as well as measurements with finite duration, obtaining that the dynamics of the system is almost independent of the concrete realization of the measurements. In the second part of the thesis, we discuss the meaning of temperature fluctuations in quantum thermodynamical systems. In statistical mechanics, there exist different approaches to the problem of temperature fluctuations, which lead to the well-known temperature fluctuation formula. The nature and operational accessibility of these fluctuations, however, remains rather unclear. We argue that according to quantum thermodynamics a system relaxes into a quasi-stationary thermal state and therefore the temperature does not fluctuate. However, since temperature is not an observable, it can only be determined indirectly. For modular systems, we show that the fluctuations of the temperature estimate obtained from a single energy measurement, indeed, are given by the temperature fluctuation formula derived in statistical mechanics, but only within a certain temperature range. The validity range of this formula increases with increasing size of the system. Thus, one can conclude that these "temperature fluctuations" can be interpreted as representing a fundamental limit for the instantaneous determination of temperature.