Physica Scripta
Generalized Demkov model: geometrical adiabatic phase factors
S F C O'Rourke
Abstract
We consider a two-state model which extends the exponential time-dependent Demkov model of non-adiabatic coupling to complex energies and interactions. Using the method of steepest descent, exact and practicable asymptotic expansions of the Hankel functions H v j (1) (λ), H v j (2) (λ) are obtained when | v j | and | λ | are large and of the same order. The semiclassical scattering two channel matrix within the strong-coupling Demkov model and embracing non-adiabatic parameters is derived. Closed form expressions for the transition probabilities, which incorporate the effects of the classical turning point, are also derived. The matrix elements are shown to reduce correctly in known limiting cases. These include the case of exact symmetric resonance, the Landau-Zener and Callaway-Bartling model and the Stueckelberg noncrossing formula. In the case of a Hamiltonian matrix which is complex Hermitian on the real t axis, Berry has shown that the phenomenon of anholonomy arises as the physical manifestation of a non-integrable real geometric phase in adiabatic parallel transport round a closed circuit in real space. More recently Berry has reinterpreted this theory as arising from transport around a circuit in complex time. The geometric amplitude factor, which is simply the anholonomic phase corresponding to the connection on a complex fibre bundle, occurs naturally in the Demkov model which is an example of a closed system in parameter space driven by a complex Hermitian Hamiltonian. It is shown that the Berry phase phenomenon also involves contributions from both real and complex circuit adiabatic phases.