This thesis addresses aspects of quantum phase and sets out to draw attention to a collection of new and extend some not so new techniques utilizing Weyl's correspondence rule and its inverse. The phase formulation of quantum mechanics is as old as quantum mechanics itself and evolved over a period of two decades due to the contributions of H. Weyl \cite{Weyl1950}, E. P. Wigner \cite{Wigner1932}, H. Groenewold \cite{Groenewold1946} and J. E. Moyal \cite{Moyal1949}. Over the ensuing years the phase picture has matured into a practical analytical tool, and has generated a multitude of technical papers, reports, reviews, and expositions from many authors and commentators. One reason for its success is that it offers an intuitive picture of quantum mechanics owing to its \it{classical look and feel}, and it has made an impression, in one way or another, in many fields such as mathematical physics, quantum optics, and physical chemistry.The thesis opens with a brief history of classical phase space, tracing the possible origin of the term ``phase space itself, and chronicles the events leading to the conceptualization (and generalization) of quantum phase space. In Chapter 2 the Weyl correspondence is recast in terms of von Neumann's integral kernel transform and a heuristic analysis is given from this perspective. A characteristic of Weyl's correspondence rule and its inverse is that there are two inherent representations of the same operator. These have been referred to as the Weyl representation and Wigner representation and are related by a symplectic Fourier transform. For an arbitrary outer dyadic operator it is shown that the Weyl representation leads to the \it{modified} Gabor transform (known to Signal Processing), while the Wigner representation specializes to the Bargmann transform and a representation in terms of analytic functions. Calculating Weyl-Wigner (WW) transforms of products of
n operators, from first principles, has proved to be a technically difficult problem. However, with the machinery developed in Chapter 2 the problem is reduced to a straightforward algebraic exercise. Finally, forming an
s-parametrized generalization of Weyl's correspondence rule and focusing on the Weyl representation it is shown to lead to an intimate relationship with the relative state formalism \cite{Ban1998}. Weyl's correspondence rule is only applicable to operators and consequently state vectors
∣ψ⟩ are not represented in the usual formulation of quantum phase space. This problem is circumvented in Chapter 3 by introducing the notion of a normalized fixed state (or window) vector
∣φ0⟩ to form an outer dyadic product $\wh{\Psi} = |\psi\rangle\langle\varphi_0|$. The WW transform of this product under the action of the Weyl's rule is a complex valued function of real variables called a phase amplitude and denoted by the symbol
Ψ. The phase amplitudes have many (and sometimes surprising) properties. For example they: \begin{itemize} \item form the building blocks of Wigner functions
W by admitting a generalized Born rule
W=Ψ⋆Ψˉ, and as such can be considered to be a more fundamental objects than Wigner functions; \item superpose and interfere like the state vectors they represent; \item specialize to the Bargmann and Gabor transforms when a Gaussian window is chosen; \end{itemize} \ni In Chapter 4 further aspects of phase amplitudes are explored and discussed. For example it is shown that they: \begin{itemize} \item define phase state vectors which form an over complete set and are elements of a reproducing kernel Hilbert space; \item allow unitary ray representations of the group symmetries of translation, rotation and time reversal; \item evolve in phase under the influence of a propagator
R which is intimately related to the Wigner propagator
P. \end{itemize} Chapter 5 considers an extension of phase amplitudes to include systems with finitely many degrees of freedom. These are called spin amplitudes and are obtained by first forming the outer dyadic product of a spin state vector with an arbitrary fixed spin state vector, and then applying a finite-dimensional analogue of the WW transform. The spin amplitude operator is represented as an
n×n matrix, whose elements are products of the spin components of the spin and fixed state vectors. Two kinds of spin amplitudes are considered, arising on the sphere
S2 or on a
(2j+1) dimensional lattice. In the special case of spin-$\half$ systems it is shown that the spin amplitudes transform as spinors under rotations on both the sphere and lattice. As a physical application the spin amplitudes for a spin-$\half$ magnetic dipole are found for a Nuclear Magnetic Resonance (NMR) environment. Chapter 6 considers Schwinger's abstract approach to quantum mechanics which takes into account the inability to indefinitely compensate for fluctuations in the measurement process. The resulting measurement algebra provides a symbolic representation of the physical laws as opposed to the mathematical abstraction (of von Neumann and Dirac) that was justified \it{\'a posteriori} by being in agreement with experiment. Despite Schwinger's prolific work on the subject of measurement algebra, its interpretation in quantum phase remained an open issue. It is shown that the key to formulating a quantum phase in terms of the measurement operators and transformation functions is the determination of a suitable set of basis operators for an arbitrary measurement operator. Many new results follow as a consequence of expanding an arbitrary measurement operator in this basis. In Chapter 7 the quantum-classical interface is explored by considering Hamilton's principal function or action
S(q,v,t). Starting from a purely heuristic classical argument, a phase function
U(p,q,t) is derived in terms of the classical action and is shown to be proportional to the WW transform of the quantum evolution operator. This association leads to the transform \be U(p,q,t) = A(t) \int e^{ipv/\hbar} e^{iS(q,v,t)/\hbar} \; \rm{d}v, \ee which enables one, in principle, to deduce the Wigner functions of a given system when only the classical action is known. Simple physical systems are used to provide examples illustrating this approach.
The Weyl-Wigner description of quantum mechanical operators and states in classical phase-space language is well known for Cartesian systems. We describe a new approach based on ideas of Dirac which leads to the same results but with interesting additional insights. A way to set up Wigner distributions in an interesting non-Cartesian case, when the configuration space is a compact connected Lie group, is outlined. Both these methods are adapted to quantum systems with finite-dimensional Hilbert spaces, and the results are contrasted.
The physical content of a theory is not intrinsically tied to any single mathematical formalism. Both classical and quantum mechanics admit equivalent representations, notably in phase space and in Hilbert space, related by the Wigner-Weyl correspondence. While this correspondence has long been studied in mathematical physics, its foundational and operational implications are often left implicit. Here we give a systematic account of what changes, and what does not, when classical and quantum theories are expressed in each other's native language. This representational viewpoint separates artifacts (such as the appearance of non-positivity or negativity under certain maps) from robust structural distinctions that persist across representations, in particular noncommutativity and its
ℏ-dependent
⋆-deformation of the classical algebra. We develop the comparison at the level of states, kinematics, and dynamics, and extend it to measurement by formulating both outcome statistics and state-update rules within the same framework.
The Wigner-Weyl isomorphism for quantum mechanics on a compact simple Lie group
G is developed in detail. Several New features are shown to arise which have no counterparts in the familiar Cartesian case. Notable among these is the notion of a `semiquantised phase space', a structure on which the Weyl symbols of operators turn out to be naturally defined and, figuratively speaking, located midway between the classical phase space
T∗G and the Hilbert space of square integrable functions on
G. General expressions for the star product for Weyl symbols are presented and explicitly worked out for the angle-angular momentum case.
The Wigner–Weyl isomorphism for quantum mechanics on a compact simple Lie group G is developed in detail. Several features are shown to arise which have no counterparts in the familiar Cartesian case. Notable among these is the notion of a semiquantized phase space, a structure on which the Weyl symbols of operators turn out to be naturally defined and, figuratively speaking, located midway between the classical phase space T*G and the Hilbert space of square integrable functions on G. General expressions for the star product for Weyl symbols are presented and explicitly worked out for the angle-angular momentum case.