A derivation of a special case of the Wigner–Eckart theorem suitable for use in an undergraduate course in quantum mechanics is presented. This presentation is restricted to the wave mechanical formalism of quantum mechanics.
Chapter 6 applies the material of the previous chapters to some particular topics, specifically the Wigner–Eckart theorem, selection rules, and gamma matrices and Dirac bilinears. We begin by discussing the perennially confusing concepts of vector operators and spherical tensors, and then unify them using the notion of a representation operator. We then use this framework to derive a generalized selection rule, from which the various quantum-mechanical selection rules can be derived, and we also discuss the Wigner–Eckart theorem. We conclude by showing that Dirac’s famous gamma matrices can be understood in terms of representation operators, which then immediately gives the transformation properties of the ‘Dirac bilinears’ of QED.