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IEEE Journal of Quantum Electronics

On spontaneous emission

F.W. Cummings

Published Jul 1, 1988• 3 citations
Publisher

Abstract

The problem of the spontaneous emission from a single excited two-level atom in the presence of N unexcited similar atoms is discussed. A formalism is presented for evaluation of the time-development operator (and thus the density matrix) which has certain desirable features for time-dependent problems in the area, e.g. of atom-field interactions, when the off-diagonal elements are large compared to the diagonal elements of the Hamiltonian. By use of this formalism, it is shown that the spontaneous emission from a single atom is often drastically altered in the presence of unexcited atoms with similar resonances. When the number of atoms present becomes very large relative to the number of modes of the electromagnetic field, the excited atom becomes trapped in its excited state.>

DOI
10.1109/3.973

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Radiation from an N -Atom System. II. Spontaneous Emission from a Pair of Atoms

Robert H. Lehmberg

Using the formalism developed earlier, we treat spontaneous emission from a pair of identical two-level atoms ${A}_{1}$, ${A}_{2}$, whose separation ${r}_{21}$ can be comparable to the wavelength $\ensuremath{\lambda}$. We obtain expressions for time-dependent intensities and damping rates with the initial conditions (a) both atoms inverted, (b) prior excitation by a short $\frac{1}{2}\ensuremath{\pi}$ pulse, and (c) only ${A}_{1}$ inverted. The results in (a) are compared with those obtained for a model consisting of two initially excited harmonic oscillators ${O}_{1}$, ${O}_{2}$. The atoms exhibit superradiant behavior, whereas ${O}_{1}$, ${O}_{2}$ tend to trap radiation. In (a), the intensity pattern $\mathcal{R}(\ensuremath{\theta},t)$ develops lobes in different directions at different times, so that the spatial distribution of photons at time $t\ensuremath{\rightarrow}\ensuremath{\infty}$ is the same as in the independent-atom case ${r}_{21}\ensuremath{\gg}\ensuremath{\lambda}$. For the oscillators, the lobes of $\mathcal{R}(\ensuremath{\theta},t)$ do not change direction, but only become more pronounced as time increases. In (b) and (c), the lobes oscillate back and forth at frequency $2{\ensuremath{\Omega}}_{12}$ corresponding to the shifts $\ifmmode\pm\else\textpm\fi{}{\ensuremath{\Omega}}_{12}$ of the triplet and singlet states due to the ${A}_{1}\ensuremath{-}{A}_{2}$ interaction. The intensity can therefore have a sinusoidal component. Field correlation functions calculated for (a) and (c) show that ${A}_{2}$ and ${A}_{2}$ radiate simultaneously around the frequencies $\ensuremath{\epsilon}\ifmmode\pm\else\textpm\fi{}{\ensuremath{\Omega}}_{12}$, where $\ensuremath{\epsilon}$ is the single-atom resonant frequency. The spectrum is calculated for case (c), and shows the effects of coherent linewidth enhancement in addition to the frequency shifts.

Physical Review A•Sep 1, 1970•280 citations
The problem of the spontaneous emission from a single excited two-level atom in the presence of N unexcited similar atoms is discussed. A formalism is presented for evaluation of the time-development operator (and thus the density matrix) which has certain desirable features for time-dependent problems in the area, e.g. of atom-field interactions, when the off-diagonal elements are large compared to the diagonal elements of the Hamiltonian. By use of this formalism, it is shown that the spontaneous emission from a single atom is often drastically altered in the presence of unexcited atoms with similar resonances. When the number of atoms present becomes very large relative to the number of modes of the electromagnetic field, the excited atom becomes trapped in its excited state.>
The quantum-electrodynamical problem of N identical two-level atoms interacting with M field modes is considered, and an exact solution for the case of spontaneous emission from a single atom is obtained. The behavior of this system is shown to be quite different from the exponential decay of a single excited atom radiating into free space. A ``ringing'' behavior at the enigmatic frequency \ensuremath{\sim} \ensuremath{\surd}N which occurs when only one mode is accessible to the field persists when many modes are present. When a continuum of modes is accessible, the long-time limit shows that the energy of the originally excited atom is equally likely to be shared by the N-1 originally unexcited atoms and the electromagnetic field when M/N\ensuremath{\rightarrow}1. ``Radiation suppression'' occurs whenever N\ensuremath{\gg}1 and M\ensuremath{\ll}N, when the originally excited atom does not emit its energy. When M=N\ensuremath{\gg}1, the single atom decays monotonically to zero (and approximately exponentially) but with a decay rate that is \ensuremath{\surd}N times the Rabi frequency. Such unexpected effects are presently within experimental range.
The long-time behavior of the number of photons in a mode of the electromagnetic field is given in closed form in terms of elementary functions when there is initially one (two-level) atom excited in the presence of NNN unexcited identical atoms and MMM field modes. The radiation trapping which occurs with only one mode disappears when the number of modes MMM approaches the total number of atoms in the continuum mode approximation.
NNN two-level "atoms" are considered in interaction with a single-mode resonant electromagnetic field. The exact solution is given nonrelativistically for all times for the case of spontaneous emission, when only one atom is initially excited. The solution is given for the general case of the NNN atoms in inequivalent mode positions.
The problem of a single two level atom in its excited state, placed in a cavity in which no photons are present initially, and interacting with N modes of the electromagnetic field is solved exactly in the electric dipole, rotating wave approximation. Expressions for the energy eigenvalues and eigenvectors are derived, and an exact representation for the time dependent wavefunction of the system is given. These quantities are evaluated analytically for N=1,2 and 3, and the time dependent properties of the system for these values of N are investigated and discussed.
The interaction between the electromagnetic field and a number of identical atomic systems, individually characterized by an electric dipole moment and two energy levels, is analyzed for the case where the atomic systems are inside a lossy cavity and exposed to a coherent driving field, resonance being assumed between atomic system, cavity, and driving field.The problem of introducing loss into a quantum-mechanical formalism is treated first. Formal operator expressions are obtained for the field variables which include the absorption and the fluctuation (both thermal and quantum-mechanical) effects of the loss mechanism. Expectation values are then obtained for the field strength and the field energy which are valid for times short compared to the lifetime of the excited state. It is shown that the spontaneous-emission energy in the field increases initially as the square of the time and approaches a steady-state value after a transient period which is of the order of the cavity relaxation time. The induced emission contains two parts: incoherent emission induced by the thermal field, and coherent emission induced by the driving field. The incoherent induced-emission energy has the same time dependence as the spontaneous-emission energy, and the ratio of the former to the latter is the number of photons in the thermal (inducing) field. The coherent induced-emission energy does not approach a steady-state value, but, after a transient period, increases linearly with the time. The ratio of the coherent induced-emission energy to the spontaneous-emission energy is equal, initially, to the number of photons in the driving-field energy, but becomes $\ensuremath{\beta}t$ times as large after the transient period, where $\ensuremath{\beta}$ is the reciprocal of the cavity relaxation time.The expectation value of the rate of energy emission by the atomic systems is also obtained. It is shown that the ratio of the downward to the upward transition probabilities has the well-known value of (n+1)n\frac{(n+1)}{n}n(n+1)​, where nnn is the field energy in units of the photon energy, only in the absence of a coherent field.
Using the formalism developed earlier, we treat spontaneous emission from a pair of identical two-level atoms A1{A}_{1}A1​, A2{A}_{2}A2​, whose separation r21{r}_{21}r21​ can be comparable to the wavelength $\ensuremath{\lambda}$. We obtain expressions for time-dependent intensities and damping rates with the initial conditions (a) both atoms inverted, (b) prior excitation by a short $\frac{1}{2}\ensuremath{\pi}$ pulse, and (c) only A1{A}_{1}A1​ inverted. The results in (a) are compared with those obtained for a model consisting of two initially excited harmonic oscillators O1{O}_{1}O1​, O2{O}_{2}O2​. The atoms exhibit superradiant behavior, whereas O1{O}_{1}O1​, O2{O}_{2}O2​ tend to trap radiation. In (a), the intensity pattern $\mathcal{R}(\ensuremath{\theta},t)$ develops lobes in different directions at different times, so that the spatial distribution of photons at time $t\ensuremath{\rightarrow}\ensuremath{\infty}$ is the same as in the independent-atom case ${r}_{21}\ensuremath{\gg}\ensuremath{\lambda}$. For the oscillators, the lobes of $\mathcal{R}(\ensuremath{\theta},t)$ do not change direction, but only become more pronounced as time increases. In (b) and (c), the lobes oscillate back and forth at frequency $2{\ensuremath{\Omega}}_{12}$ corresponding to the shifts $\ifmmode\pm\else\textpm\fi{}{\ensuremath{\Omega}}_{12}$ of the triplet and singlet states due to the ${A}_{1}\ensuremath{-}{A}_{2}$ interaction. The intensity can therefore have a sinusoidal component. Field correlation functions calculated for (a) and (c) show that A2{A}_{2}A2​ and A2{A}_{2}A2​ radiate simultaneously around the frequencies $\ensuremath{\epsilon}\ifmmode\pm\else\textpm\fi{}{\ensuremath{\Omega}}_{12}$, where $\ensuremath{\epsilon}$ is the single-atom resonant frequency. The spectrum is calculated for case (c), and shows the effects of coherent linewidth enhancement in addition to the frequency shifts.