At temperatures near the absolut zero, a gas, here atomic sodium vapour, with high enough density cannot be described as tiny balls moving around as in classical physics. Since the temperature is low, the atoms are so slow that the matterwave of each atom starts to extend over the size of the atom and even over the interatomic distance. Therefore, they start to interfere like waves. Quantum mechanics start to dominate the physics in this regime. Further, depending on the sort of atoms (bosons or fermions) the atoms prefer to be in the same state or avoid to be in the same state. In the case of bosons as in the thesis, if the temperature is lowered to sub micro Kelvin temperature, a new state of matter appears after a phase transition - a macroscopic, standing wave, the Bose-Einstein condensate. This leads to a new phenomena: superfluidity - frictionless flow, second sound, vorticity and coherent scattering effects to name a few. The atoms are trapped in a elongated trap as in most of the experiments in ultra cold gasses. Usually experiments are done in a regime where the atoms seldomly collide with each other while travelling from one end to the other end of the cloud. In this experiment, however, the atoms collide many times with each other when they oscillate in the trap. This means that the cloud is hydrodynamic and leads to a very different behaviour. Two different sound waves (first and second sound), heat conduction, and collisional dominated transport can be observed in this case. The fact that the gas is weakly interacting allows comparison with current theory. At very low temperatures as in the experiments described in the thesis, the Bose character strongly alters the collisions of the atoms. The outcome of the collision does not only depend on the colliding atoms, but also on the atoms near by in phase space. The experiments outlined in this thesis cover some aspects of physics involved. Vortices have been created and observed in the Bose-Einstein condensate that rested in a weak trap. Both sound modes first and second sound have been observed with slight local heating. In the regime considered, first sound, that has not been observed in a dilute Bose-Einstein condensate before, is mainly a modulation in local temperature and not density. In another experiment a particular effect is observed when the cloud is only axially hydrodynamic. When the trap is suddenly axially relaxed, the cloud creats a strip pattern that is in the radial direction and moving outward. The analysis of this experiment suggests that this is only the case when the cloud is indeed only axially hydrodynamic. The last chapter describs a spin drag experiment. In this experiment two spin species of atoms are prepared and on one of them a force is applied. Through collisions, the other species is dragged along. This effect is Bose enhanced at temperatures approaching the transition temperature to a Bose-Einstein condensate which is observed and matches recent theory.
At temperatures near the absolut zero, a gas, here atomic sodium vapour, with high enough density cannot be described as tiny balls moving around as in classical physics. Since the temperature is low, the atoms are so slow that the matterwave of each atom starts to extend over the size of the atom and even over the interatomic distance. Therefore, they start to interfere like waves. Quantum mechanics start to dominate the physics in this regime. Further, depending on the sort of atoms (bosons or fermions) the atoms prefer to be in the same state or avoid to be in the same state. In the case of bosons as in the thesis, if the temperature is lowered to sub micro Kelvin temperature, a new state of matter appears after a phase transition - a macroscopic, standing wave, the Bose-Einstein condensate. This leads to a new phenomena: superfluidity - frictionless flow, second sound, vorticity and coherent scattering effects to name a few. The atoms are trapped in a elongated trap as in most of the experiments in ultra cold gasses. Usually experiments are done in a regime where the atoms seldomly collide with each other while travelling from one end to the other end of the cloud. In this experiment, however, the atoms collide many times with each other when they oscillate in the trap. This means that the cloud is hydrodynamic and leads to a very different behaviour. Two different sound waves (first and second sound), heat conduction, and collisional dominated transport can be observed in this case. The fact that the gas is weakly interacting allows comparison with current theory. At very low temperatures as in the experiments described in the thesis, the Bose character strongly alters the collisions of the atoms. The outcome of the collision does not only depend on the colliding atoms, but also on the atoms near by in phase space. The experiments outlined in this thesis cover some aspects of physics involved. Vortices have been created and observed in the Bose-Einstein condensate that rested in a weak trap. Both sound modes first and second sound have been observed with slight local heating. In the regime considered, first sound, that has not been observed in a dilute Bose-Einstein condensate before, is mainly a modulation in local temperature and not density. In another experiment a particular effect is observed when the cloud is only axially hydrodynamic. When the trap is suddenly axially relaxed, the cloud creats a strip pattern that is in the radial direction and moving outward. The analysis of this experiment suggests that this is only the case when the cloud is indeed only axially hydrodynamic. The last chapter describs a spin drag experiment. In this experiment two spin species of atoms are prepared and on one of them a force is applied. Through collisions, the other species is dragged along. This effect is Bose enhanced at temperatures approaching the transition temperature to a Bose-Einstein condensate which is observed and matches recent theory.
The field of Bose-Einstein condensation (BEC) in dilute atomic gases provides a fruitful playground to test well-developed theories of quantum fluids. Research using BECs can address open questions relating to the many-body aspects of two-component quantum liquids, namely the interaction between the hydrodynamic normal and the superfluid component at finite temperatures. After the first realization of BEC some pilot experiments have been carried out, but detailed experiments are missing. This has to be compared to the case of liquid helium II, where many experiments since the 1950s have added to our understanding of novel phenomena in quantum liquids, like collective excitations, first and second sound, and others. One of the drawbacks of liquid helium is that the interactions are so strong that a clear distinction between the two components is difficult and the interpretation of the phenomena remains ambiguous. Most experimental studies of dilute Bose-Einstein condensed gases use clouds, which are in the collisionless regime. The reason for the lack of detailed experiments in BECs to study quantum liquids and in particular the hydrodynamical aspects of it, is the limited number of atoms (typically 1--10 million) in the experiments leaving the thermal atoms virtually collisionless. Efforts to decrease the mean free path by increasing the confinement limits the lifetime of the sample, since the density is limited by three-body decay. Experiments on dilute clouds of cold atoms are generally conducted in highly asymmetric traps. In these elongated, cigar-shaped geometries the mean free path of the atoms can become much shorter than the size of the cloud in the long, axial direction, but at the same time exceeds the size in the other, radial directions. In this so-called hydrodynamic-collisionless regime the system can be considered radially collisionless and axially hydrodynamic. In our setup we have created BECs containing up to 300 million sodium atoms by evaporation of atoms in an axially strongly decompressed trap with an aspect ratio of 1:65. Hot atoms created in three-body collisions are able to leave the sample in this highly asymmetric trap, before they can heat other atoms in an avalanche. The sample is axially hydrodynamic, but due to the large aspect ratio collisionless in the radial direction. Such samples are ideal for the observation of the interaction between the superfluid and normal fluid component of the cloud. In this thesis we describe the setup which is used to reach the hydrodynamic regime and we describe a novel implementation of the well-known phase contrast imaging technique. Next, we study collective excitations in the crossover from the collisionless toward the hydrodynamic regime, we determine the heat conduction in a cold, hydrodynamic thermal cloud and observe the propagation of a thermal wave in the two-fluid regime. Furthermore, we study the friction between the superfluid and normal fluid component of the cloud. In the final chapters of this thesis we study the propagation of second sound, as well as the formation and propagation of shock waves.
The field of ultra-cold atomic physics allows probing of two-component quantum liquids with a hydrodynamic normal fluid accompanied by superfluid Bose-Einstein condensates (BEC’s), where the experimental results can be compared to theoretical predictions of the behavior of a weakly interacting two fluid system. Hydrodynamicity in quantum systems like BEC's can have influence on multiple aspects of the collective behavior of the system, such as on the oscillation frequency of quadrupole modes, multiple sound modes in the condensate, but also on high-order excitations which resemble standing sound waves. The hydrodynamicity and excitations of the ultra-cold atomic cloud are the main motivation for the experiments presented in this thesis. In the Utrecht experiment large BEC's up to a few hundred million atoms are produced, which are deeply in the hydrodynamic collisional regime. The macroscopic behavior of the cloud of atoms is dominated by inter-atomic collisions since the mean free path of the individual particles is much smaller than the size of the atomic sample and local equilibrium is established. The influence of the hydrodynamicity on the collective excitations can be investigated by measuring the quadrupole frequency of ultra-cold atomic clouds above the transition temperature Tc, where Bose-Einstein condensation occurs. This quadrupole frequency is determined by measuring the collective shape oscillations of the atomic cloud, where the oscillation frequency is influenced by inter-atomic collisions during the shape oscillations due to the hydrodynamicity of the atomic cloud. The hydrodynamic equations predict the existence of two sound modes in ultra-cold atomic gases below Tc. The speeds of sound are dependent on both the temperature and the chemical potential of the atomic cloud. For low enough temperatures or large enough chemical potential these two speeds of sound become comparable and reaching this regime experimentally allows measuring the speed of sound beyond this avoided crossing. An alternate method of measuring the speed of sound of ultra-cold atomic clouds is exploiting the analogy between a standing sound wave-pattern and high order excitations in BEC's, also referred to as Faraday waves. By exciting the wave-pattern with a frequency and measuring the wavenumber k of the wave-pattern, the speed of sound c can be extracted from the linear dispersion relation. In the process of exciting the standing wave-pattern, remarkable dynamics is discovered in the BECs. As a result of the excitation a large array of other modes are excited next to the wave-pattern. These modes are for example the dipole mode, the axial and radial quadrupole modes, and the scissor mode. This gives rise to complex dynamics in this hydrodynamic quantum mechanical system and although the ultra-cold sample is only excited with a very short pulsed excitation, these modes and the wave-pattern show a large degree of reproducibility during several seconds of time evolution.
Just a couple decades ago bosonic low-temperature physics was synonymous with one particular liquid at a temperature of several degrees Kelvin. This liquid, helium-4, and its famous Helium-II phase, has revealed remarkable quantum properties such as quantized vortices and second sound. Yet, despite many things learned by investigating helium, its study has certain limitations. On the one hand, helium is a strongly interacting liquid, which makes first-principles theoretical research challenging. To name one example, establishing a connection between the non-interacting condensate state described by Bose and Einstein, and the helium properties observed in the lab took decades. Furthermore, helium is a specific chemical element, and hence there is no surprise that its physical properties are fixed by nature. However, every particular chemical element has particular physical properties, so for a long time it seemed that it was as good as it gets. The picture has changed drastically when the first Bose-Einstein condensate (BEC) was observed in an ultracold atomic gas. “Low temperature” has become synonymous with “ultracold”, and the latter implies temperatures on the order of nanokelvins. Most strikingly, the relationship between what is fixed by nature and what is experimentally changeable has evolved. In particular, systems of different particle statistics, spin, and interactions have been engineered using ultracold vapours of various alkali atoms. This versatile manipulation not only makes emulating various condensed-matter physics models in a controlled system without impurities possible, but also opens a path towards novel phenomena that are at present not achievable in any other manner. In this thesis, we have explored some of the novel phenomena that arise in systems of bosonic particles with internal degrees of freedom, such as (pseudo)spin and electric dipole moment. In the introduction, we describe a ferromagnetically coupled spin-1/2 Bose gas with contact interactions in the mean- field approximation. In particular, we compute and discuss the phase diagram of this gas, since it is a simple system which nevertheless has two order parameters. In the chapters that follow, the ideas touched upon in the introduction are developed in more detail. In Chapter 2 we develop a hydrodynamic description of the ferromagnetic spin-1/2 Bose gas at arbitrary temperatures. We study magnetization relaxation and geometric forces. In particular, we consider the topological Hall effect due to the presence of a skyrmion. In Chapter 3 we investigate the miscible (non-ferromagnetic) spin-1/2 Bose gas at arbitrary temperatures, construct its hydrodynamic description, calculate the thermodynamic properties, and study the collective modes of this system. In Chapter 4 we discuss the influence of the off-diagonal Berry curvature on the Bose-Einstein condensation temperature. Finally, in Chapter 5 we study a Bose-Einstein condensate of dipolar molecules in a weak electric field and find it to be described by a quantum rotor model. Moreover, we show that the molecular Bose-Einstein condensate is a ferroelectric material that is fully disordered by quantum fluctuations.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Bose-Einstein condensate (BEC) is a new state of matter, experimentally realized in a dilute alkali gas of weakly interacting bosons. The gas is cooled to very low temperatures, of the order of nano-Kelvin, at which point a large fraction of the atoms occupy the lowest quantum state. Under such conditions, the quantum effects become apparent on a macroscopic scale. Many fundamental ideas
of quantum mechanics have been realized and proven to be true in experiments,
by studying the Bose-Einstein condensates. Amongst them, the observation of
macroscopic matter wave interference, the creation of vortices, dark and bright
solitons etc, find special mention. The dynamics of this system in presence of an
optical lattice reveals a superfluid to Mott insulator quantum phase transition.
This has opened a new avenue for research on BEC and its applications. From
a theoretical standpoint, the dynamics of BEC can be described by means of an
effective mean-field theory. This formalism is much simpler than the many-body
Schr¨odinger equation and based on a classical nonlinear evolution equation, known
as Gross-Pitaevskii equation. The nonlinear nature of the GPE leads to several interesting phenomena like soliton propagation, vortices, four wave mixing etc.,
which are closely related to nonlinear fiber optics.
The present thesis deals with nonlinear excitations and different phases of BEC
and is organized as follows: after a brief introduction, in chapter two, we start
with BEC in a one-dimensional shallow optical lattice, experiencing both cubic
and quintic nonlinearity. A superfluid density wave, of twice the periodicity of
lattice potential, is identified. This indicates matter redistribution, where atoms
from neighbouring sites have been depleted leading to a density wave behaviour.
Interestingly, it ceases to exist when only one of these interactions is operative.
We predict the loss of superfluidity through a classical dynamical phase transition,
where modulational instability leads to the loss of phase coherence. In presence
of pure two-body interaction, the superfluid density shows a periodicity commensurate
with the lattice potential. Apart from the superfluid state, a density wave
insulating phase is also found to exist, possessing two frequency modulations commensurate
with the lattice potential. A dynamical phase transition connects the
superfluid phase with an insulating phase, which in turn, is connected with the
density wave insulating phase. The solutions are found to be marginally stable, as
per the Vakhitov-Kolokolov (VK) criterion.
Chapter three describes the dynamics of the atomic-molecular Bose-Einstein
condensate (AMBEC) by mean-field Gross-Pitaevskii equation (GPE), taking into
account the atom-molecular interaction, as well as atom-molecule inter-conversion.
The two-body atom-atom, atom-molecule and molecule-molecule interactions are
analogous to the cubic nonlinearity of the standard GPE, whereas, the quadratic
nonlinear term arising from the inter-conversion between atoms and molecules is
identical to the scenario in strongly coupled BEC in one dimension. The presence
of both weak and strong interactions adds further richness to this system. We
find the molecular BEC possesses a complex dark (grey) soliton, while the atomic condensate is a bright one. The energy and momentum of this system is computed
in order to see the effect of the both weak and strong interactions on Lieb mode
profile and compare it with the pure atomic condensate profile. Another class
of solutions exist in this system, where both atomic and molecular condensates
possess bright solitons.
In chapter four, we investigate the effect of a harmonic trap on the dynamics
of grey solitons in Bose-Einstein condensates. It is observed that, these nonlinear
excitations of the cigar-shaped Bose-Einstein condensate have strong coupling
with the trap at low momenta and hence can be effectively isolated from the
Bogoliubov sound modes, which respond weakly to harmonic confinement. This
strong coupling with the trap also makes the grey soliton amenable for control and
manipulation through trap modulation and temporal variation of the two-body interaction.
We have shown that in presence of an expulsive oscillator trap, the grey
soliton gets amplified, while having a compression in its width. Exact solutions are
also obtained in case of the two component Bose-Einstein condensates (TBECs),
where one component is a grey soliton and the other a bright one. The presence
of the trap and inter-species interaction significantly affects the grey soliton dynamics.
Similar to the single component, in the present case, we have shown that
both grey and bright soliton can be compressed simultaneously. A detailed study
of the energy and momentum of the soliton is reported, in order to find the effect
of the trap on the Lieb mode.
In chapter five, we study a BEC-defect complex in a quasi-one dimensional
scenario, where the defect atom moves in the condensate with constant velocity.
Explicit solutions of the coupled mean-field equations, describing defect-grey soliton
dynamics are obtained, demonstrating the coexistence of grey soliton and a
localized defect. Unlike the case of dark soliton, where the defect trapping center
has vanishing superfluid density, the moving grey soliton necessarily possesses a finite superfluid component at the defect location. The presence of the defect can
lower the grey soliton’s maximum velocity, as compared to the defect free case,
where the maximum velocity is the sound velocity. We have also carried out the
stability analysis of the obtained solutions using renormalized momentum formalism
and Vakhitov-Kolokolov criteria and find that the obtained solutions are stable
through both the methods. The grey soliton’s energy gets substantially modified
through its interaction with the defect, opening up the possibility of its control
through defect dynamics.
Chapter six describes a parametrically forced Bose-Einstein condensate in the
presence of a general moving optical lattice. The interaction between the atoms in
the condensate and the time dependent lattice potential leads to a novel propagating
superfluid matter wave, which can be controlled through chirp management.
This system, when placed in a trap, accelerates and undergoes rapid nonlinear
compression, controlled by the chirp. The density achieves its maximum, when
the matter wave changes direction. It is also shown that this system exhibits dynamical
superfluid insulator transition, where superfluidity breaks down and the
condensate transits to an insulating phase. The stability has been investigated
using Vakhitov-Kolokolov criterion and found that it depends on the chirp, as well
as on the nature of the atom-atom interaction. The exact expression for energy
is obtained and analyzed in detail to gain physical understanding of the chirp
management of the sinusoidal excitations and also the dynamical phase transition.
This chapter presents an overview of the specific experimental tools developed in the field of ultra-cold gases to achieve and probe superfluidity in vapours of bosonic atoms. First, it describes the main cooling techniques: the magneto-optical trap, which brings an atomic vapour from room temperature down to the sub-mK range, and the evaporative cooling scheme, which bridges the gap to the superfluid regime. It then proceeds to the study of interaction effects. It shows that these play a central role in the understanding of both static and dynamic properties of trapped Bose–Einstein condensates (BECs), despite the dilute character of these gases. As a consequence, gaseous BECs and superfluid helium obey the same laws of hydrodynamics and exhibit similar dynamical properties, although their densities differ by several orders of magnitude. The third section is devoted to the coherence properties of gaseous BECs. It shows that, by contrast with liquid helium, specific features of ultra-cold gases make them suitable for a direct probing of the quantum coherence associated with Bose–Einstein condensation. Finally, the possibility of tailoring trapping potentials and realizing low-dimensional systems is discussed, where one or two directions of motion are frozen.