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Physical Review A

Time delay in atomic collisions

Slobodan Danko Bosanac

Published Aug 1, 1981• 14 citations
Publisher

Abstract

The time delay, as defined via phase shifts, does not apply to atom-atom collisions because of the semiclassical nature of the system. In this limit the contribution of one partial wave to the cross section is negligible. Therefore, we analyze time delay for the scattering amplitude and show that some new phenomena may occur, which cannot be explained by the time delay for a single phase shift. The time delay, which is averaged over all scattering angles, shows structure corresponding to several delay mechanisms. We also show that the lifetime of a resonance state, formed in a collision, may be considerably shorter than expected from the theory of resonance scattering.

DOI
10.1103/physreva.24.777

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Journal of Mathematical Physics•Mar 1, 1967•6 citations
The time delay, as defined via phase shifts, does not apply to atom-atom collisions because of the semiclassical nature of the system. In this limit the contribution of one partial wave to the cross section is negligible. Therefore, we analyze time delay for the scattering amplitude and show that some new phenomena may occur, which cannot be explained by the time delay for a single phase shift. The time delay, which is averaged over all scattering angles, shows structure corresponding to several delay mechanisms. We also show that the lifetime of a resonance state, formed in a collision, may be considerably shorter than expected from the theory of resonance scattering.
A formalism to calculate the time delay experienced by a particle undergoing scattering is presented. The formalism is a natural extension of Wigner’s delay time to wave packets which do not exhibit a well defined angular momentum. The delay depends only on the partial wave phase shifts characterizing the scattering event. The formalism is tested by applying it to the 3D square well. The results are shown to agree with the known properties of resonant scattering as deduced from a study of the poles of the scattering matrix in the complex energy plane.
The theory of measurements in which photons are detected in delayed coincidence with a scattered particle is developed in a form specifically applicable to atomic collisions. Equations are obtained which relate the measured coincidence rate to excitation amplitudes. These equations incorporate the polarization of the radiation, the fine and hyperfine structure of the atomic levels, the coherence of the radiation, and the time dependence of the radiation intensity. A semiclassical model for certain transitions is introduced to illustrate new features of coincidence measurements. The $\mathrm{Ly}\ensuremath{-}\ensuremath{\alpha}$ transitions in hydrogen and $^{1}P\ensuremath{\rightarrow}^{1}S$ transitions in He are treated in detail to illustrate the general theory.
We have implemented the Gedanken experiment of an individual atom scattering a wave packet of near-resonant light, and measured the associated Wigner time delay as a function of the frequency of the light. In our apparatus, the atom behaves as a two-level system and we have found delays as large as 42 ns at resonance, limited by the lifetime of the excited state. This delay is an important parameter in the problem of collective near-resonant scattering by an ensemble of interacting particles, which is encountered in many areas of physics.
The Ramsauer effect does not correspond to the decrease in optical scattering by a particle when the wave-length of the light is increased. For one may compute the cross-section for elastic collision of an electron with an atom, without making the approximations used by Born. If one does this, and neglects the resonance of the colliding electron with the atomic electrons one finds that, for atoms with no dipole moment in the normal state, the cross-section approaches a finite limit when the electronic velocity is decreased. The only general result of this calculation is that the distribution of scattered electrons tends, in this limit, to become uniform over all angles.
A simple analytical formula, a=a\ifmmode\bar\else\textasciimacron\fi{}[1-tan(\ensuremath{\pi}/n-2)tan{\ensuremath{\Phi}-[\ensuremath{\pi}/2(n-2)]}, is obtained for the scattering length in atomic collisions. Here a\ifmmode\bar\else\textasciimacron\fi{}=cos[\ensuremath{\pi}/(n-2)]{ \ensuremath{\surd}2M\ensuremath{\alpha} /[\ensuremath{\Elzxh}(n-2)]${\mathrm{}}}^{2/(\mathit{n}\mathrm{\ensuremath{-}}2)}$[\ensuremath{\Gamma}(n-3)/(n-2)]/[T(n-1)/(n-2)] is the mean scattering length determined by the asymptotic behavior of the potential U(r)\ensuremath{\sim}-\ensuremath{\alpha}/Rn{\mathit{R}}^{\mathit{n}}Rn, (n=6 for atom-atom scattering or n=4 for ion-atom scattering), M is the reduced mass of the atoms, and \ensuremath{\Phi} is the semiclassical phase calculated at zero energy from the classical turning point to infinity. The value of a\ifmmode\bar\else\textasciimacron\fi{}, the average scattering length, also determines the slope of the s-wave phase shifts beyond the near-threshold region. The formula is applicable to the collisions of atoms cooled down in traps, where the scattering length determines the character of the atom-atom interaction. Our calculation shows that repulsion between atoms (a>0) is more likely than attraction with a ``probability'' of 75%. For the Cs-Cs scattering in the $^{3}\mathrm{\ensuremath{\Sigma}}_{\mathit{u}}$ state, a\ifmmode\bar\else\textasciimacron\fi{}=95.5aB{\mathit{a}}_{\mathit{B}}aB​ has been obtained, where aB{\mathit{a}}_{\mathit{B}}aB​ is the Bohr radius. The comparison of the calculated cross-section energy dependence with the experimental data gives evidence for a positive value for the Cs-Cs scattering length, which makes cesium Bose gas stable.
Two-body scattering is analyzed using a time-dependent formalism and wave packets of arbitrary shape as the initial wavefunctions. In particular, the case of single-channel resonant scattering is discussed in some detail. In addition to the usual amplitudes resulting from the potential term and the resonant term, a third amplitude is found which interferes with the other two. Another interesting result is that in this formalism the final state is not necessarily represented by spherical outgoing waves, but can be interpreted instead as two separate outgoing wave packets whose shape is different from the initial packets. The Wigner time delay is obtained as a natural consequence of the analysis, and the resonant cross sections are expressed as density matrices constructed from the wave packets.