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Journal of Physics A Mathematical and General

Bose-Einstein condensation in an Einstein universe

M. B. Altaie

Published Aug 1, 1978• 25 citations
Publisher

Abstract

The condensation of a non-relativistic ideal Bose gas in an Einstein universe is investigated. Explicit expressions for the condensate fraction N 0 /N and the specific heat are obtained by using the Poisson summation formula to express the summations as integrations plus corrections. It is shown that the finiteness of the system smoothes out the cusp-like singularity of the infinite system. A rigorous asymptotic analysis of the critical temperature and the specific heat maximum are given, and the relation with the scaling theory of finite size effects is briefly discussed.

DOI
10.1088/0305-4470/11/8/020

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The condensation of a non-relativistic ideal Bose gas in an Einstein universe is investigated. Explicit expressions for the condensate fraction N 0 /N and the specific heat are obtained by using the Poisson summation formula to express the summations as integrations plus corrections. It is shown that the finiteness of the system smoothes out the cusp-like singularity of the infinite system. A rigorous asymptotic analysis of the critical temperature and the specific heat maximum are given, and the relation with the scaling theory of finite size effects is briefly discussed.
Taking into account the possibility of particle-antiparticle pair production, we have investigated the onset of Bose-Einstein condensation in an ideal relativistic Bose gas confined to restricted geometries. Through an extensive use of the Poisson summation formula, we have carried out an explicit evaluation of the summations over states appearing in the problem, which enables us to make a rigorous analysis of the temperature dependence of the thermogeometric parameter yyy of the system in the case of a cubical enclosure under periodic boundary conditions. This, in turn, leads us to determine the growth of the condensate fraction $\frac{{\ensuremath{\rho}}_{0}}{\ensuremath{\rho}}$ as a smooth function of temperature from $T\ensuremath{\gtrsim}{T}_{c}$ down to T=0T=0T=0 K. Finite-size corrections to the standard bulk results are obtained in explicit terms and are shown to be in complete agreement with the Fisher-Barber scaling theory for such effects. In the end, special geometries, such as narrow channels and thin films, are also examined.
Mathematical singularities, which are known to be at the heart of phase transitions and are responsible for making the thermodynamic functions of the given system nonanalytic, are a consequence of the thermodynamic limit, viz. N and V → ∞ with N/V staying constant. When a system containing a finite number of particles and confined to a restricted geometry undergoes a phase transition, these singularities get rounded off, with the result that all thermodynamic functions become analytic and vary smoothly with the relevant parameters of the problem. Theoretical analysis of such situations requires the use of special mathematical techniques which may vary drastically from case to case.In the present communication we report the results of a rigorous analysis of the problem of "Bose–Einstein condensation in restricted geometries", which has been carried out by making an extensive use of the Poisson summation formula. Particular emphasis is laid on the growth of the condensate fraction [Formula: see text] as the temperature of the system is lowered, and on the influence of the boundary conditions imposed on the wave functions of the particles. The relevance of these results, in relation to the scaling theory of finite size effects, is also discussed.
The scaling hypothesis on the 'singular' part of the free-energy density of a finite system is examined in the context of a relativistic Bose gas confined to an Einstein universe of radius R. Finite-size effects in the various thermodynamic properties of the system, such as the free energy, the specific heat, the isothermal compressibility and the condensate density, are predicted in the regions of both first-order (T<T c ) and second-order (T approximately=T c ) phase transitions. To test these predictions, a detailed analytical study is carried out which includes the possibility of particle-antiparticle pair production in the system. The various predictions of the scaling hypothesis are fully borne out and the scaling functions governing the critical behaviour of the system are found to be universal, irrespective of the severity of the relativistic effects.
Bose-Einstein condensation of a relativistic ideal Bose gas in a rectangular cavity is studied. Finite size corrections to the critical temperature are obtained by the heat kernel method. Using zeta-function regularization of the one-loop effective potential, lower-dimensional critical temperatures are calculated. In the presence of strong anisotropy, the condensation is shown to occur in multisteps. The criteria of this behavior is that critical temperatures corresponding to lower-dimensional systems are smaller than the three-dimensional critical temperature.
We have carried out a rigorous asymptotic analysis of the thermodynamic behavior of an ideal Bose gas confined to an arbitrary, finite cuboidal geometry under periodic boundary conditions. Our investigation, which is based on the grand canonical ensemble, leads to the construction of an abstract, thermogeometric space in which the process of Bose-Einstein condensation appears as a "collapse" of the lattice points of the space towards its origin. In an infinite geometry, the collapse is accomplished in an infinitesimally small interval of temperature; this results in the appearance of mathematical singularities in the thermodynamic functions of the system. In a finite geometry, the "collapse" proceeds gradually and is spread over a temperature range $\ensuremath{\Delta}T$ such that $\frac{\ensuremath{\Delta}T}{{T}_{0}}=O(\frac{\overline{l}}{{L}_{<}})$, where l‾\overline{l}l is the mean interatomic distance while L<{L}_{<}L<​ is the length of the shortest side of the assembly; accordingly, the thermodynamic functions of the system remain smooth throughout. Special events, such as the specific-heat maximum, occur when the "lattice parameters" of our thermogeometric space acquire certain characteristic values which depend only on the shape of the system and not on its actual size. This leads to a new law of corresponding states for Bose-Einstein systems of finite size.