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Physical Review Letters

Role of Binding Energy in Feshbach-Resonant Positron-Molecule Annihilation

Jason A. Young, Clifford M. Surko

Published Sep 28, 2007• 24 citations
Publisher

Abstract

Measurements of positron-on-molecule annihilation have established that positrons bind to a variety of molecules via vibrational Feshbach resonances. Data for deeply bound states in benzene and 1-chlorohexane and for positronically excited (i.e., second) bound states in alkanes are used to establish the dependence of annihilation rates on the binding energy and incident positron energy. With this dependence removed, annihilation rates for a broad class of molecules lie on a universal curve as a function of the number of molecular vibrational degrees of freedom. The implications of these results for theoretical models are discussed.

DOI
10.1103/physrevlett.99.133201

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Measurements of positron-on-molecule annihilation have established that positrons bind to a variety of molecules via vibrational Feshbach resonances. Data for deeply bound states in benzene and 1-chlorohexane and for positronically excited (i.e., second) bound states in alkanes are used to establish the dependence of annihilation rates on the binding energy and incident positron energy. With this dependence removed, annihilation rates for a broad class of molecules lie on a universal curve as a function of the number of molecular vibrational degrees of freedom. The implications of these results for theoretical models are discussed.
Measurements of energy-resolved positron-molecule annihilation show the existence of positron binding and vibrational Feshbach resonances. The existing theory describes this phenomenon successfully for the case of infrared-active vibrational modes that allow dipole coupling between the incident positron and the vibrational motion. Presented here are measurements of positron-molecule annihilation made using a recently developed cryogenic positron beam capable of significantly improved energy resolution. The results provide evidence of resonances associated with infrared-inactive vibrational modes, indicating that positron-molecule bound states may be populated by nondipole interactions. The anticipated ingredients for a theoretical description of such interactions are discussed.
The very large annihilation rates observed at room temperature in positron collisions with certain molecules have instigated the development of several models of positron annihilation based on the role of virtual processes, Feshbach resonances and bound states. One of the outcomes of these models has been the interest they have generated in investigations of the energy dependence of the annihilation cross-section in the vicinity of inelastic thresholds. The aim of this article is to provide a review of these recent studies and to highlight outstanding questions.
An overview is presented of recent studies of the interaction of low-energy positrons with atoms and molecules using a trap-based positron beam. The beam is tunable from ~100 meV to many electron volts, with a typical energy resolution of 25 meV (FWHM). A variety of scattering processes are investigated using the properties of positron orbits in a spatially varying magnetic field. Recent scattering measurements are reviewed, and new data for electronic excitation, ionization, and positronium formation in noble gases are presented. In a separate set of experiments, positron annihilation below the threshold for positronium formation is studied in molecules as a function of positron energy. The data show large Feshbach resonances in the range of energies of the molecular vibrations. Within the framework of this model, these results provide the first experimental evidence that positrons bind to hydrocarbon molecules.
The lifetime of positrons contained in an electrostatic trap is studied when small quantities of alkanes (i.e., hydrocarbon molecules of the form Cn{\mathrm{C}}_{\mathrm{n}}Cn​H2n+2{\mathrm{H}}_{2\mathrm{n}+2}H2n+2​) are added. As n is increased from 4 to 16, the annihilation rate per molecule is found to increase by a factor of 300 and then to level off. These data are interpreted as evidence for the existence of long-lived resonances and bound states of positrons and neutral molecules, and a model of the formation process is discussed.