Tunneling in Open Systems: Thermodynamical Approaches

Joachim Ankerhold

G.G. Adamian, N.V. Antonenko, W. Scheid

Fundamentals Survey of the Various Approaches Path Integral Description of Open Quantum Systems Imaginary-Time and Real-Time Approaches Influence Functional Method Phenomenological and Microscopic System-Plus-Reservoir Models Linear and Nonlinear Quantum Environments Ohmic, Super-Ohmic, and Sub-Ohmic Dissipation Quantum Decoherence and Relaxation Correlation Functions, Response Functions, and Fluctuation-Dissipation Theorem Damped Quantum Mechanical Harmonic Oscillator Quantum Brownian Motion Thermodynamic Variational Approach and Effective Potential Method Unified Approach to Quantum-Statistical Metastability: From Thermal Activation to Quantum Tunneling Electron Transfer and Incoherent Tunneling Macroscopic Quantum Effects in Josephson Systems Spin-Boson Model and Qubit Dissipative Two-State System: Thermodynamics and Dynamics Single-Charge and Cooper-Pair Tunneling Magnetic and Spin Tunneling Driven Quantum Tunneling Nonequilibrium Quantum Transport Full Counting Statistics Charge Transport in Quantum Impurity Systems Duality and Self-Duality.

Wei-Ming Huang, Wei-Min Zhang

By solving the exact master equation of open quantum systems, we formulate the quantum thermodynamics from weak to strong couplings. The open quantum systems exchange matters, energies, and information with their reservoirs through quantum particle tunnelings that are described by the generalized Fano-Anderson Hamiltonians. We find that the exact solution of the reduced density matrix of these systems approaches a Gibbs-type state in the steady-state limit for the systems in arbitrary initial states as well as for both the weak and strong system-reservoir coupling strengths. When the couplings become strong, thermodynamic quantities of the system must be renormalized. The renormalization effects are obtained nonperturbatively after exactly tracing over all reservoir states through the coherent state path integrals. The renormalized system Hamiltonian is characterized by the renormalized system energy levels and interactions, corresponding to the quantum work done by the system. The renormalized temperature is introduced to characterize the entropy production counting the heat transfer between the system and the reservoir. We further find that only with the renormalized system Hamiltonian and other renormalized thermodynamic quantities can the exact steady state of the system be expressed as the standard Gibbs state. Consequently, the corresponding exact steady-state particle occupations in the renormalized system energy levels obey the Bose-Einstein and the Fermi-Dirac distributions for bosonic and fermionic systems, respectively. In the very weak system-reservoir coupling limit, the renormalized system Hamiltonian and the renormalized temperature are reduced to the original bare Hamiltonian of the system and the initial temperature of the reservoir. Thus, the conventional statistical mechanics and thermodynamics are thereby rigorously deduced from quantum dynamical evolution. In the last, this nonperturbative renormalization method is also extended to general interacting open quantum systems.

R. C. Dynes