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Physical Review

Theory of a Three-Level Maser

Ali Javan

Published Sep 15, 1957• 258 citations
Publisher

Abstract

In a three-level maser, a transition between two energy levels is saturated in order to produce an induced emission of power at a lower frequency corresponding to a transition between an intermediate energy level and one or the other of the two saturated levels. In this paper, certain effects are discussed which cannot be predicted from a theory in which the population differences alone are considered in this process. For instance, it is shown that, in some cases it is possible to obtain for the same system an induced emission of power at two frequencies given by the resonances between the intermediate energy level and both of the saturated levels. Also, it is shown that, even in the absence of inhomogeneous broadening of the spectral line, one can obtain a net induced emission at some portions of a resonant line and a net absorption at other frequencies within the line widths. Such effects become important even in early stages of saturation in cases where ${T}_{1}={T}_{2}$ which is true for ordinary gaseous systems and individual spin systems in a majority of very dilute paramagnetic solids. A complete theory is discussed for a gaseous system and extended to two limiting cases of paramagnetic materials with ${T}_{1}={T}_{2}$ and ${T}_{2}\ensuremath{\ll}{T}_{1}$ for each individual spin system. Furthermore, it is shown that for a saturating field of fixed frequency, the integral of induced power over the entire line is in full agreement with the results of a semiclassical treatment in which the population differences alone are considered. Some remarks are made as to the practicability of certain systems of this type.

DOI
10.1103/physrev.107.1579

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Bell System Technical Journal•Mar 1, 1959•25 citations
In a three-level maser, a transition between two energy levels is saturated in order to produce an induced emission of power at a lower frequency corresponding to a transition between an intermediate energy level and one or the other of the two saturated levels. In this paper, certain effects are discussed which cannot be predicted from a theory in which the population differences alone are considered in this process. For instance, it is shown that, in some cases it is possible to obtain for the same system an induced emission of power at two frequencies given by the resonances between the intermediate energy level and both of the saturated levels. Also, it is shown that, even in the absence of inhomogeneous broadening of the spectral line, one can obtain a net induced emission at some portions of a resonant line and a net absorption at other frequencies within the line widths. Such effects become important even in early stages of saturation in cases where T1=T2{T}_{1}={T}_{2}T1​=T2​ which is true for ordinary gaseous systems and individual spin systems in a majority of very dilute paramagnetic solids. A complete theory is discussed for a gaseous system and extended to two limiting cases of paramagnetic materials with T1=T2{T}_{1}={T}_{2}T1​=T2​ and T2\ensuremath≪T1{T}_{2}\ensuremath{\ll}{T}_{1}T2​\ensuremath≪T1​ for each individual spin system. Furthermore, it is shown that for a saturating field of fixed frequency, the integral of induced power over the entire line is in full agreement with the results of a semiclassical treatment in which the population differences alone are considered. Some remarks are made as to the practicability of certain systems of this type.
The multiple quantum process in the off-resonant condition of the three-level gas maser is discussed. The intensity of the emission produced by this process is calculated by a perturbation theory and also by a more general treatment which is the application of Javan's theory to the off-resonant case. Some graphical representations of the signal line under off-resonant pumping are given for the purpose of comparison with experiment. The Doppler effect in three-level maser action is analyzed from both semiclassical and quantum mechanical points of view under the presence of collision relaxation. It was shown that in a saturation process between two levels, Doppler effect behaves as to contribute to both line-width and relaxation time for the transition, and that under strong pumping, Doppler effect in pumping transition has a marked influence on both intensity and shape of the signal line through the effect of multiple quantum transition.
An analysis of a three-level system using time-dependent perturbation theory shows that two distinct photon-emission processes take place within such a system when stimulated optical emission occurs: one-and two-photon transitions. The two-photon transition consists of the emission of a stimulated photon followed by the absorption of a coherent pump photon.In three-level systems which possess a narrow pump level, two-photon transitions are dominant at high pump powers while the maser line is split into two lines due to the modulation of the wave function at an angular frequency determined by the rate of pumping. This might lead to the possibility of frequency-modulating the maser line. These results are extended qualitatively to include optical masers which possess broad pump-bands.
An analysis of a three-level system using time-dependent perturbation theory shows that two distinct photon-emission processes take place within such a system when stimulated optical emission occurs: one-and two-photon transitions. The two-photon transition consists of the emission of a stimulated photon followed by the absorption of a coherent pump photon. In three-level systems which possess a narrow pump level, two-photon transitions are dominant at high pump powers while the maser line is split into two lines due to the modulation of the wave function at an angular frequency determined by the rate of pumping. This might lead to the possibility of frequency-modulating the maser line. These results are extended qualitatively to include optical masers which possess broad pump-bands.
An analysis of a three-level system using time-dependent perturbation theory shows that two distinct photon-emission processes take place within such a system when stimulated optical emission occurs: one-and two-photon transitions. The two-photon transition consists of the emission of a stimulated photon followed by the absorption of a coherent pump photon. In three-level systems which possess a narrow pump level, two-photon transitions are dominant at high pump powers while the maser line is split into two lines due to the modulation of the wave function at an angular frequency determined by the rate of pumping. This might lead to the possibility of frequency-modulating the maser line. These results are extended qualitatively to include optical masers which possess broad pump-bands.
The density matrix describing a paramagnetic ion subjected to both pump and signal fields is calculated. It is used to determine the fractional population differences, magnetic polarization densities, susceptibility tensors and power dissipation densities at both the pump and signal frequencies. There are six relaxation parameters of prime significance: the spin-spin relaxation times, the spin-lattice relaxation times and the Overhauser parameters for both the pump and signal transitions. The spin-spin relaxation times control the low-level absorption. The spin-lattice relaxation times control the completely saturated absorption. The Overhauser parameters control the absorption by one transition when the other transition is partially or completely saturated.
The three-level excitation method for solid state masers, including some background material on paramagnetic resonance, is reviewed. With respect to the experimental application of the maser material, two cases can be distinguished, In the first, maser action is based mainly on a favorable relaxation time ratio in signal and idler transitions. It is shown that the relaxation time ratio can be changed artificially by a doping technique. Experimental evidence is presented for two such doping techniques, one self-doping, the other impurity doping. In the second case, maser action is based primarily on a favorable frequency ratio of signal and idler transitions. Maser experiments using this approach are described. In addition, excitation of unidirectional gain and attenuation by circular polarization is discussed. Properties of practical isolator materials are surveyed; they include high-concentration paramagnetic and polycryslolline ferrimagnetic materials.