The extra photon echo decay due to ion-ion, velocity-changing collisions is computed. The strong velocity dependence of the collision frequency is shown to decrease the decay constant by 30%.
The effect of velocity-changing collisions in an extended-pulse photon echo is studied. In an extended-pulse photon echo, the second excitation pulse has a duration comparable with the relaxation time of an atomic system. We present an analytic solution of the quantum-mechanical transport equation in the perturbation-theory limit and apply it to the extended-pulse photon echo. It is found that the decay rate of the echo signal due to velocity-changing collisions is significantly modified by the variation of the second pulse's duration. The results are compared with those of conventional theories of two- and three-pulse echoes using temporally narrow excitation pulses. A physical interpretation of the results is given using both time- and frequency-domain arguments.
The interaction between an intense radiation field and atoms that undergo collisions in an atomic vapor is studied. With the assumption that velocity-changing collisions are state independent and weak, we obtain an analytic expression for the time-dependent density-matrix elements by solving a quantum-mechanical transport equation using a dressed-state approach. Our analytical calculation is used to predict the form of the signal in an extended-pulse photon echo. The results show good agreement with an experiment carried out by Yodh et al. [Phys. Rev. Lett. 53, 659 (1984)]. It is found that the decay rate of the echo signal decreases rapidly with increasing duration of the second pulse in the pulse excitation sequence. A comparison between theory and experiment is presented and a physical interpretation of the results is given.
It is shown that the decay in photon-echo amplitude with interval T between pulses provides a new method for the determination of the small-angle dependence of the forward-elastic-scattering cross section $\ensuremath{\sigma}(V,\ensuremath{\theta})$, and that the experiment of Schmidt, Berman, and Brewer yields an analysis of $\ensuremath{\sigma}(V,\ensuremath{\theta})$ for CH3F collisions. The result is in agreement with the r3C interaction between molecules with permanent electric dipole moments.
We investigate a mechanism responsible for the observed very short times of the photon-echo decay (of the order of a few femtoseconds) in semiconductors. It is associated with the loss of phase memory as a result of the interaction of the interband mixed state with an unscreened random Coulomb potential of the photocarriers and/or charged impurities. A time characteristic of a system of interacting electrons is found. This is the time of phase breaking ${\mathrm{\ensuremath{\tau}}}_{\mathit{c}\mathit{p}\mathit{h}\mathit{i}}$, which we calculate within the eikonal approximation using diagrammatic techniques. ${\mathrm{\ensuremath{\tau}}}_{\mathit{c}\mathit{p}\mathit{h}\mathit{i}}$ is shown to be typically much shorter than both the time of electron-electron collisions and the period of plasma oscillations. We demonstrate that the screening of Coulomb potential cannot be built up during this time. ${\mathrm{\ensuremath{\tau}}}_{\mathit{c}\mathit{p}\mathit{h}\mathit{i}}$ is proportional to ${\mathit{n}}^{\mathrm{\ensuremath{-}}1/\mathit{d}}$ (where n is the carrier concentration and d the dimensionality of a system), which is consistent with the experimental results. The derived law of echo decay of the form exp[-(\ensuremath{\tau}/${\mathrm{\ensuremath{\tau}}}_{\mathit{c}\mathit{p}\mathit{h}\mathit{i}}$)d] agrees with the results of numerical simulation, although it does not agree with the existing results of physical experiment. We believe that such a disagreement is of a fundamental nature and manifests a basic need for further experimental and theoretical work.
Photon-echo measurements in atomic Na perturbed by He provide the first demonstration of the contribution of velocity-changing-like effects to the transverse relaxation of atoms in superposition of two states even when the states follow different post-collision trajectories. The apparent anomaly that broadening cross sections derived from either absorption line widths or photon-echo relaxation measurements are smaller than the total cross section for scattering of atoms in either pure state is explained.