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Japanese Journal of Applied Physics

Measurement of Ground-State Population in Ruby under Optical Pumping

Toshizo Nakaya

Published Jan 1, 1966• 3 citations
Publisher

Abstract

Depopulation of ground-state Cr ions in ruby (DGS) under optical pumping with a Xe flash light has been measured as a function of time. Experiments have been made by means of measuring the decrease in absorbing power for a probe light (5790 Å or 5461 Å) from a Hg lamp. DGS reaches its maximum value after some delay from the peak of Xe light, and decreases after discontinuation of optical pumping with a time constant of 3.4 ms, which is the lifetime of metastable-state 2E. During laser oscillation mean value of DGS is forced to take a constant value, which varies with the condition of laser oscillation. So long as the input energy to the Xe lamp is not altered, the shorter the duration of Xe flash light is, the higher becomes the maximum value of DGS. On the basis of the rate equation, these experimental results have been explained.

DOI
10.1143/jjap.5.79

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Absorption transitions between two excited optical states in ruby have been studied by comparing the absorption coefficients measured under optically pumped and unpumped conditions. The spectrum has been determined in the π-and σ-polarizations in the photon energy range from 5,500 to 45,000 cm -1 . Several absorption bands have been found which arise from the transitions from the excited states t 2g 3 2 E g and t 2g 3 2 T 1g of the Cr 3+ ion. From the locations and intensities of these bands, the terminal states of the observed transitions are assigned to the charge transfer state, the t 2g 3 2 T 2g state, and the doublet states belonging to the electron configuration t 2g 3 e g . Calculated energies between these states and the metastable states, t 2g 3 2 E g and t 2g 3 2 T 1g , are in good agreement with the peak energies of the observed absorption bands. The present experiment gives new information inaccessible by the ordinary ground state absorption measurement, such as the locations of several doublet states with the configuration t 2g 2 e g and the intensities of doublet-doublet transitions in ruby.

Journal of the Physical Society of Japan•Jul 1, 1966•52 citations
Depopulation of ground-state Cr ions in ruby (DGS) under optical pumping with a Xe flash light has been measured as a function of time. Experiments have been made by means of measuring the decrease in absorbing power for a probe light (5790 Å or 5461 Å) from a Hg lamp. DGS reaches its maximum value after some delay from the peak of Xe light, and decreases after discontinuation of optical pumping with a time constant of 3.4 ms, which is the lifetime of metastable-state 2E. During laser oscillation mean value of DGS is forced to take a constant value, which varies with the condition of laser oscillation. So long as the input energy to the Xe lamp is not altered, the shorter the duration of Xe flash light is, the higher becomes the maximum value of DGS. On the basis of the rate equation, these experimental results have been explained.
The degree of the decrease in the population of ground-state Cr ions in ruby brought about by optical pumping with Xe flash light has been measured as a function of time under Q-switching operation. The measurement has been made by observing the decrease in absorbing power of the ruby crystal for a probe light (Hg 5461Å), (γ), while Q-switching with a rotating prism or saturable absorber (Cryptocyanine). Observations of rapid change of (γ) due to the emission of giant pulse laser light have been carried out, with the very satisfactory results. At the occurrence of a giant pulse, the higher the initial value of (γ) is, the lower becomes the final value of (γ).
The absorption cross sections of the Cr3+{\mathrm{Cr}}^{3+}Cr3+ ion in the metastable states 2E(E‾and2A‾)^{2}E (\overline{E} \mathrm{and} 2\overline{A})2E(Eand2A) of lightly doped ruby (\ensuremath{\sim}0.01%) have been measured as a function of polarization at temperatures of 30, 105, and 296\ifmmode^\circ\else\textdegree\fi{}K in the region from 2300 to 7000 \AA{}. The lifetime of these states was measured by observing the decay rate of the excited-state absorption, and agreed with the value of the measured fluorescence decay rate at various temperatures. The population of the excited states was measured by the change of the area under the first two vibronic sidebands at low temperatures. At room temperature the population was measured by the change of transmitted intensity of a ruby laser.
Several experiments on optically excited ruby are described. First, absorption transitions initiated from the metastable states,t\min{2}\max{3}2Eandt\min{2}\max{3}2T1, are investigated in the photon energy range from 5500 to 45 000 cm-1. The absorption spectrum of these excited states is determined in both\pi-and σ-polarizations and assignments for the observed absorption bands are achieved. Obtained results are compared with other experiments reported in the literature. Next, emission properties of pink ruby are studied in the region near theRlines. The emission spectrum is determined point by point by means of intense flash excitation. The observed weak bands are ascribed to theR'and phonon assistedRtransitions. Laser actions in these bands are discussed and experimental results on phonon terminated laser amplification are presented. An experiment using a giant pulse as an excitation source reveals that the transition time fromt\min{2}\max{3}2Etot\min{2}\max{3}2T1is shorter than a fraction of 1μs at room temperature.
A time varying macroscopic magnetization of ruby is observed at room temperature by selectively exciting the Cr 3+ ions with a right- and a left circularly polarized light of a Q -switched ruby laser from one of the ground 4 A 2 multiplets to a proper component of the upper \bar E ( 2 E ) multiplets. Dependence of such a magnetization in the Z -direction on the irradiation power, the ellipticity and the magnetic field was measured with a pick-up coil. The signal had a value of 1.7×10 -4 emu/g at the irradiation of 67 mJ. The relaxation time of the ground state was estimated from the decay to be about 180 ns in zero magnetic field. The signal changed with the ellipticity of the exciting light, and the amplitude of the signal was always proportional to the intensity of the excitation. These experimental results were quantitatively explained by a theoretical analysis for the time varying optically induced magnetization.
Absorption transitions between two excited optical states in ruby have been studied by comparing the absorption coefficients measured under optically pumped and unpumped conditions. The spectrum has been determined in the π-and σ-polarizations in the photon energy range from 5,500 to 45,000 cm -1 . Several absorption bands have been found which arise from the transitions from the excited states t 2g 3 2 E g and t 2g 3 2 T 1g of the Cr 3+ ion. From the locations and intensities of these bands, the terminal states of the observed transitions are assigned to the charge transfer state, the t 2g 3 2 T 2g state, and the doublet states belonging to the electron configuration t 2g 3 e g . Calculated energies between these states and the metastable states, t 2g 3 2 E g and t 2g 3 2 T 1g , are in good agreement with the peak energies of the observed absorption bands. The present experiment gives new information inaccessible by the ordinary ground state absorption measurement, such as the locations of several doublet states with the configuration t 2g 2 e g and the intensities of doublet-doublet transitions in ruby.