A generalization of the Bloch equations for a spin ½ particle to those valid for any multipole is obtained by use of tensor operator techniques. As an application of the Bloch-type formalism, we discuss the interaction of coherent and incoherent light with a gas in a magnetic field as contrasted with the description of a Zeeman laser.
Description of detailed temporal excitation dyanmics for coherent excitation, such as is produced by idealized laser radiation, contrasts with evaluation of rate coefficients by means of generalized Golden Rule procedures; it requires an appropriate time-dependent Schroedinger equation. When the atom undergoing excitation is also affected by incoherent processes, such as collisions, this equation no longer suffices. The Heisenberg equations, or equivalent density-matrix equations, permit treatment in which coherence and incoherence play comparable roles in the excitation dynamics. Unlike rate equations, such equations must incorporate complexities that originate in the orientation degeneracy expressed by magnetic quantum numbers. In simple cases of coherent excitation, both for single-photon and multiphoton excitation, the sublevels merely require an average of 2J+1 independent Schroedinger equations. Relaxation couples the independent equations. It has been known for some time that appropriate state-multipole operators can simplify the description of many phenomena connected with optical pumping. This memo discusses application of these multipole operators to the description of Raman (or more general multiphoton) coherent excitation. In some simple limiting cases the equations simplify, but in general one has a hierarchy of coupled multipole polarizations and coherences in place of the populations and coherences that occur as variables in nondegenerate systems. 28 refs., 4 figs.
A quantum theory of nonlinear phenomena is considered in which account is taken of all contributions from electric and magnetic multipoles, without any multipolar approximation. Exact closed analytical expressions for the multipoles are first obtained from quantum electrodynamics by applying a generalization of the Power-Zienau transformation. The standard procedure is invoked to calculate general electromagnetic susceptibility tensors ${\ensuremath{\chi}}_{\ensuremath{\mu}\ensuremath{\nu}{\ensuremath{\alpha}}_{1}{\ensuremath{\beta}}_{1}\ensuremath{\cdots}{\ensuremath{\alpha}}_{n}{\ensuremath{\beta}}_{n}}^{[n]}$ (${\ensuremath{\omega}}_{1}, \dots{}, {\ensuremath{\omega}}_{n}$). Such a tensor is a shorthand for the electric and magnetic susceptibilities as well as mixed susceptibilities. By considering a relativistic theory based on the Dirac equation, the spin susceptibilities are automatically included. The formalism in this way allows for the computation of a wide range of electro- and magneto-optical effects to any order of perturbation and to any order of multipolar approximation.
The laser gain equation is derived in two ways. First, the optical Bloch equations are derived, based upon a semiclassical treatment of a two-level atomic system and a radiation field. As a visualization aid, there follows a discussion of the formally identical classical Bloch equations, which describe the behavior of a magnetic moment in a combined static and rotating magnetic field. It is shown that laser gain is proportional to the imaginary part of the linear susceptibility, which is obtained from the semiclassical treatment. The second viewpoint uses a slightly modified form of Einstein’s A and B coefficients adapted to describing interactions between atoms and monochromatic fields. Various damping and broadening mechanisms are introduced in a reasonable but non-rigorous fashion, and the crucial distinction between homogeneous and inhomogeneous broadening is introduced.
Generalized Bloch equations for laser-excited semiconductors are derived applying quantum-mechanical projection-operator techniques. The equations include phase-space filling and the many-body Coulomb effects. The coherent part of the equations is evaluated for the regime of ultrafast-pump-probe excitation and shown to reduce to the inhomogeneously broadened two-level Bloch equations for the different momentum states if the proper Coulomb enhancement in the density of states is taken into account. For the high-excitation quasithermal regime a generalization of the Elliott formula for the absorption spectrum is derived which is valid not only for bulk semiconductors, but also for quantum-well structures and other systems with reduced spatial dimensions.
After publishing the derivation from the classical Bloch equation to the quantum von Neumann equation to the Schrdinger-Pauli equation for spin-21, we proposed renaming the Bloch equation to the Majorana-Bloch equation because Majorana's work predated Bloch's in the presentation of the Bloch equation by 14 years. Here, we first generalize our previous derivation to higher spins or angular momenta in coherent pure states. Using the polynomial representation of the coherent-state projector, we derive an invertible mapping from the Majorana-Bloch equation to the von Neumann equation, establishing a one-to-one correspondence between these two formalisms. Application of the Ehrenfest theorem also shows that expectation values in these states reproduce the classical equation of motion as expected. Then, we obtain arbitrary spin-s states by symmetrizing tensor products of spin-21 primitives, in accordance with the Majorana construction or the Schur-Weyl duality.