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Physical Review

Wave-Mechanical Description of the Electron in a Homogeneous Time-Varying Electric Field

Robert H. Kohler

Published Nov 4, 1966• 5 citations
Publisher

Abstract

The nonrelativistic electron driven by a classical homogeneous time-varying field is given an exact wave-mechanical treatment. The problem is formulated and solved in two separate reference frames. One is a frame that accelerates like a classical electron that is in the same field, and here the wave mechanics is formally that of a free electron. The second frame is an inertial frame, and here the time-development operator is given two explicit forms. States of sharp but time-dependent momentum are found. Wave functions in both momentum and configuration spaces are given. Packets that move in the manner of a classical electron are produced conveniently. The physical interpretation of the wave-mechanical description is given graphical illustration in a phase-space plot. The circumstances where a purely classical description suffices are elucidated. It is shown that the wave-mechanical analysis based on a homogeneous electric field can be suitably applied to several physical situations as a good approximation. One situation is the electron in a propagating classical electromagnetic wave of arbitrary frequency. Another situation is an electron in transit through the fields in a microwave cavity. The wave mechanics of an electron plasma in a homogeneous time-dependent electric field is treated separately and yields some tangible information.

DOI
10.1103/physrev.151.165

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The nonrelativistic electron driven by a classical homogeneous time-varying field is given an exact wave-mechanical treatment. The problem is formulated and solved in two separate reference frames. One is a frame that accelerates like a classical electron that is in the same field, and here the wave mechanics is formally that of a free electron. The second frame is an inertial frame, and here the time-development operator is given two explicit forms. States of sharp but time-dependent momentum are found. Wave functions in both momentum and configuration spaces are given. Packets that move in the manner of a classical electron are produced conveniently. The physical interpretation of the wave-mechanical description is given graphical illustration in a phase-space plot. The circumstances where a purely classical description suffices are elucidated. It is shown that the wave-mechanical analysis based on a homogeneous electric field can be suitably applied to several physical situations as a good approximation. One situation is the electron in a propagating classical electromagnetic wave of arbitrary frequency. Another situation is an electron in transit through the fields in a microwave cavity. The wave mechanics of an electron plasma in a homogeneous time-dependent electric field is treated separately and yields some tangible information.
The quantal motion of a charged nonrelativistic particle in a uniform but time-varying electric field is discussed. It is pointed out that states of definite but variable momentum exist in this case and are, in a way, the analog of the coherent states of the harmonic oscillator. The gauge invariance of the theory is illustrated, and the results are related to the description of the motion in an accelerated reference frame. A brief discussion of the propagation function and of the evolution operator is also presented.
We derive a useful expression for the time-development operator for quantum wave functions, exp(−iĤt/ℏ), for the case of a particle subject to a constant force. We apply it, in both position and momentum space, to construct wave packets that exhibit uniform acceleration. We use these results to generate quantum wave packets corresponding to the motion of a charged particle in a uniform electric field in two different gauges, explicitly demonstrating the change in phase of the wave function under a gauge transformation. The more standard description of the time dependence of accelerating wave packets using the formalism of propagators is briefly reviewed in an Appendix for comparison.
Essentially, we solve the particle-field equations obtained in the matter distribution quantum mechanics. In the framework of this theory, a particle is described by a density amplitude function, we call wave function, as a packet of waves with the time dependent phases proportional to the relativistic Lagrangian. The mass quantization of such a particle, as a distribution of matter, is obtained from the equality of the spatial integral of the density with the mass as a characteristic of the relativistic dynamics of this matter. The particle dynamics, as a motion of a mass spatial distribution, is obtained from the equality of the wave propagation velocities with the distribution coordinate velocities. This description is a physical one, compared to the Schrödinger-Heisenberg description leading to unphysical results as a null velocity for the kinetic energy as a constant of motion, or Zitterbewegung. The description of a particle interaction with an electromagnetic field by additional Lagrangian terms, with a vector potential conjugated to coordinates, as in the Aharonov-Bohm effect, and an electric potential conjugated to time, leads to the Lorentz force, and the Maxwell equations. In the two conjugated spaces, of the coordinates and of the momentum, the dynamics of a quantum particle is described by propagation operators, depending on the coordinate-momentum product, applied to time dependent wave functions satisfying matter-field equations. Unlike the standard Schrödinger or Schrödinger-Dirac equations, depending only on the Hamiltonian operator, instead of the Hamiltonian these equations contain the Lagrangian, which, besides the Hamiltonian, include additional terms with an explicit dependence on velocity, as it is expected in a relativistic theory. We obtain the wave function of a particle-antiparticle system interacting with an electromagnetic field, as a wave packet of spinors propagating in space with finite dimensions, given by the finite definition domain of the density function, in the space of the matter-field momentum, as a constant of motion. We show that an electrically charged quantum particle, rotating in a central electric field, generates a vector potential with a magnetic field perpendicular to the rotational plane and an electric field in this plane. By a quantum transition, a photon is emitted in the particle rotational plane, with the magnetic field perpendicular to this plane, and the electric field contained in this plane. In this framework, the vector potential rotation is correlated to a particle momentum rotation, for the canonical matter-field momentum as a constant of motion, without any electromagnetic field radiated outside.
The relationship between classical and quantum mechanics is explored in an intuitive manner by the exercise of constructing a wave in association with a classical particle. Using special relativity, the time coordinate in the frame of reference of a moving particle is expressed in terms of the coordinates in the laboratory frame of reference in order to provide an initial spatiotemporal function to work from in initiating the development of a quantum wave. When temporal periodicity is ascribed to the particle, a provisional spatiotemporal function for a particle travelling at constant velocity manifests itself as an running wave characterized by parameters associated with the moving particle. A wave description for bidirectional motion is generated based on an average time coordinate for a combination of oppositely directed elementary running waves, and the resulting spatiotemporal function exhibits wave behavior characteristic of a standing wave. Ascribing directional orientation to the intrinsic periodicity of the particle introduces directional sub-states; variations in the relative number of sub-states as a function of angle in combined states lead to spatially varying magnitudes for the associated waves. Further analysis leads to full mathematical expression for all waves representing free particle motion. A generalization for particles subject to force fields enables us to develop a governing differential equation identical in form to the Schroedinger equation.
The transient picture for a Bloch electron accelerating in an arbitrarily time-dependent homogeneous electric field is developed. The temporal sequence for the analysis includes the instant after electron injection, followed by the time required for a small change in electron wavenumber away from initial injection, leading to the final time evolution over many Bloch periods. The time-dependent behavior is studied using the properties of the Schrödinger equation. The electric field is described through the vector potential gauge, and the instantaneous eigenstates of the Bloch, electric-field-dependent Hamiltonian are used as basis states in describing the Bloch dynamics in the electric field. For each temporal sequence considered, the solution to the Schrödinger equation is established and comparatively discussed. The expectation value of the momentum is obtained for the special case of first order in a constant electric field; the resulting velocity derived is a field-dependent generalization of the natural Zitterbewegung-like behavior discussed in the recent literature. The early-time and long-time limits of the momentum expectation value and its time derivative demonstrate that the resistance to Bloch acceleration after initial band injection varies from real mass to effective mass dynamics as the electron accelerates through the band under the influence of electric field. This changing inertia from early injection of a free-mass electron is the result of the {\it real mass} electron {\it dressing-up} into the states of the crystal to become {\it an effective mass} electron. The ramifications of this temporal {\it dressing} behavior are discussed in considering the general dynamics of Bloch electrons subject to ultrastrong electric fields.
Physical processes are usually described using four-dimensional vector quantities - coordinate vector, momentum vector, current vector. But at the fundamental level they are characterized by spinors - coordinate spinors, momentum spinors, spinor wave functions. The propagation of fields and their interaction takes place at the spinor level, and since each spinor uniquely corresponds to a certain vector, the results of physical processes appear before us in vector form. For example, the relativistic Schrödinger equation and the Dirac equation are formulated by means of coordinate vectors, momentum vectors and quantum operators corresponding to them. In the Dirac equation a step forward is taken and the wave function is a spinor with complex components, but still coordinates and momentum are vectors. For a closed description of nature using only spinor quantities, it is necessary to have an equation similar to the Dirac equation in which momentum, coordinates and operators are spinors. It is such an equation that is presented in this paper. Using the example of the interaction between an electron and an electromagnetic field, we can see that the spinor equation contains more detailed information about the interaction than the vector equations. This is not new for quantum mechanics, since it describes interactions using complex wave functions, which cannot be observed directly, and only when measured goes to probabilities in the form of squares of the moduli of the wave functions. In the same way spinor quantities are not observable, but they completely determine observable vectors. In Section 2 of the paper, we analyze the quadratic form for an arbitrary four-component complex vector based on Pauli matrices. The form is invariant with respect to Lorentz transformations including any rotations and boosts. The invariance of the form allows us to construct on its basis an equation for a free particle combining the properties of the relativistic wave equation and the Dirac equation. For an electron in the presence of an electromagnetic potential it is shown that taking into account the commutation relations between the momentum and coordinate components allows us to obtain from this equation the known results describing the interactions of the electron spin with the electric and magnetic field. In the presence of a potential the momentum components cease to commute with each other. To neutralize this effect, the Schrödinger equation is supplemented by several equations with mixed derivatives on coordinates. In section 3 of the paper this quadratic form is expressed through momentum spinors, which makes it possible to obtain an equation for the spinor wave function in spinor coordinate space by replacing the momentum spinor components by partial derivative operators on the corresponding coordinate spinor component. Section 4 presents a modification of the theory of the path integral, which consists in considering the path integral in the spinor coordinate space. The Lagrangian densities for the scalar field and for the electron field, along with their corresponding propagators, are presented. An equation of motion for the electron is proposed that is relativistically invariant, in contrast to the Dirac equation, which lacks this invariance. This novel equation permitted the construction of an actually invariant procedure for the second quantization of the fermion field in spinor coordinate space. Furthermore, it is demonstrated that the field operators are a combination of plane waves in spinor or vector space, with the coefficients of which being pseudospinors or pseudovectors. Each of these pseudovectors or pseudospinors corresponds to one of the particles presented in the theory of electrodynamics. Furthermore, each plane wave possesses an additional coefficient in the form of a creation or annihilation operator. In vector space, these operators commute, whereas in spinor space they anticommutate. The paper presents the spinor and vector representations of the field operators in explicit form, comprising sets of 16 pseudospinors or 4 pseudovectors corresponding to particles represented in electrodynamics. An explicit form of the symmetric traceless tensor with spin two, zero mass and two polarizations is presented, which can serve as a model of the graviton. The results obtained may prompt changes in some aspects of the construction of Feynman diagrams. Among other things, it presents a purely mathematical derivation of Maxwell's inhomogeneous equations without reference to empirical data on the action of electric current, which is usually referred to when deriving equations.