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Physical Review A

Minimal irreversible quantum mechanics: The mixed states and the diagonal singularity

Roberto Laura, Mario Castagnino

Published Jun 1, 1998• 51 citations
Publisher

Abstract

A formalism for minimal irreversible quantum mechanics is extended from pure states to mixed states. In the latter case the problem of their diagonal singularity is explained and solved. In addition to the pure and mixed states of the usual approach, more general states are obtained. The Friedrichs model is studied. Decoherence is found and decoherence characteristic times are computed.

DOI
10.1103/physreva.57.4140

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•Jan 1, 2002•2 citations
A formalism for minimal irreversible quantum mechanics is extended from pure states to mixed states. In the latter case the problem of their diagonal singularity is explained and solved. In addition to the pure and mixed states of the usual approach, more general states are obtained. The Friedrichs model is studied. Decoherence is found and decoherence characteristic times are computed.
It is demonstrated that, making minimal changes in ordinary quantum mechanics, a reasonable irreversible quantum mechanics can be obtained. This theory has a more general spectral decomposition, with eigenvectors corresponding to unstable states that vanish when $t\ensuremath{\rightarrow}\ensuremath{\infty}.$ These Gamov vectors have zero norm, in such a way that the norm and the energy of the physical states remain constant. The evolution operator has no inverse, showing that we are really dealing with a time-asymmetric theory. Using the Friedrichs model, reasonable physical results are obtained, e.g., the remnant of an unstable decaying state reappears, in the continuous spectrum of the model, with its primitive energy.
A recent proposal of Sjoqvist et.al. to extend Pancharatnam's criterion for phase difference between two different pure states to the case of mixed states in quantum mechanics is analyzed and the existence of phase singularities in the parameter space of an interference experiment with particles in mixed states pointed out. In the vicinity of such singular points the phase changes sharply and precisely at these points it becomes undefined. A closed circuit in the parameter space around such points results in a measurable phase shift equal to 2nπ, where n is an integer. Such effects have earlier been observed in interference experiments with pure polarization states of light, a system isomorphic to the spin-1/2 system in quantum mechanics. Implications of phase singularities for the interpretation of experiments with partially polarized and unpolarized neutrons are discussed. New kinds of topological phases involving variables representing decoherence (depolarization) of pure states are predicted and experiments to verify them suggested.
It is demonstrated that, making minimal changes in ordinary quantum mechanics, a reasonable irreversible quantum mechanics can be obtained. This theory has a more general spectral decompositions, with eigenvectors corresponding to unstable states that vanish when t→∞.t \to \infty .t→∞. These ''Gamov vectors'' have zero norm, in such a way that the norm and the energy of the physical states remain constant. The evolution operator has no inverse, showing that we are really dealing with a time-asymmetric theory. Using Friedrichs model reasonable physical results are obtained, e. g. : the remaining of an unstable decaying state reappears, in the continuous spectrum of the model, with its primitive energy.
Nelson's stochastic interpretation of quantum mechanics is extended from the case of pure states to that of mixed states. It is shown that a pure probabilistic formalism, which applies the Newton-Nelson law to the initial position and velocity distributions, does not reproduce the time evolution predicted by quantum mechanics. In order to recover the latter, a new notion must be introduced, that of pure quantum states, over which the mixture has to be decomposed, and which then satisfy the Newton-Nelson law independently.
The compatibility of irreversibility, as expressed by the second law of thermodynamics, with ordinary quantum mechanics requires an extension of the latter. Such an extension of a reversible formalism is made possible by the presence of self-energy processes (already found in quantum electrodynamics), which allows for the widening of the dynamics through the introduction of specific additional variables leading to the recognition of such processes. A projection technique modeled on that introduced long ago by the Brussels group defines a subdynamics that is shown to contain the starting formulation in its entirety. (It corresponds to a restricted class of initial conditions, namely the reversible ones.) A new kinetic description is obtained in which, e.g., collision processes for privileged components arise from the original interaction. This method is applied successively to various models, and we focus in this paper on the possible presence of temporal behaviour excluded in ordinary quantum mechanics. Among the differences between this framework and that of ordinary quantum mechanics, the possibility appears for the purely exponential decay of a particle, while ordinary quantum mechanics requires long time tails associated with the finite lower bound in the spectrum of the Hamiltonian.
The problem investigated in this paper is einselection, i. e. the selection of mutually exclusive quantum states with definite probabilities through decoherence. Its study is based on a theory of decoherence resulting from the projection method in the quantum theory of irreversible processes, which is general enough for giving reliable predictions. This approach leads to a definition (or redefinition) of the coupling with the environment involving only fluctuations. The range of application of perturbation calculus is then wide, resulting in a rather general master equation. Two distinct cases of decoherence are then found: (i) A ``degenerate'' case (already encountered with solvable models) where decoherence amounts essentially to approximate diagonalization; (ii) A general case where the einselected states are essentially classical. They are mixed states. Their density operators are proportional to microlocal projection operators (or ``quasi projectors'') which were previously introduced in the quantum expression of classical properties. It is found at various places that the main limitation in our understanding of decoherence is the lack of a systematic method for constructing collective observables.