An exact derivation of the angular momentum fluctuations for quantum mechanical systems with two-body interactions is given under suitable cluster conditions. The deviation from the classical result in the presence of a phase transition is discussed.
The magnitude of the angular momentum (J2) in quantum mechanics is larger than expected from a classical model. We explain this deviation in terms of quantum fluctuations. A standard quantum mechanical calculation gives the correct interpretation of the components of the angular momentum in the vector model in terms of projections and fluctuations. We show that the addition of angular momentum in quantum mechanics gives results consistent with the classical intuition in this vector model.
Angular momentum is one of the more abstract topics in quantum mechanics. This chapter begins with a review of classical angular momentum. Quantum-mechanical angular momentum is then introduced by obtaining operators from their classical counterparts. The commutation relations amongst those operators and the corresponding uncertainty relations then follow. Eigenstates and eigenvalues of the angular momentum operators are then introduced (but not derived). From these follow the raising and lowering operators. Physical meaning is imparted to quantum angular momentum by considering predictions for sequential measurements, and by comparing the conceptual pictures of angular momentum in classical and quantum mechanics. Finally, quantum spin and orbital angular momenta, and the deep differences between them, are discussed.
The quantum mechanical two-body problem is analyzed. Separating the center of mass from the relative motion Hamiltonian and focusing on “central potentials,” the stationary Schrödinger equation for the relative motion in spherical coordinates is split into radial and angular equations. The universal angular equation is identified as the eigenvalue equation of the angular momentum operator, whose proper solutions are the spherical harmonics. For fixed interparticle distance, the two-body system is mapped on a “rigid rotor” Hamiltonian, whose eigenstates coincide with the angular momentum eigenstates. In diatomic molecules, timescale separation between fast vibrations (radial motion) and slow rotations (angular motion) enables one to invoke a rigid rotor approximation for interpreting rotational absorption spectrum in the microwave regime. Deviations from the predictions of the rigid rotor model and their manifestation in experiments are analyzed by explicit solution of the stationary Schrödinger equation for two particles in the presence of vibration–rotation coupling.
We propose a simple approach to predict the angular momentum I ground state (I g.s.) probabilities of many-body systems that does not require the diagonalization of Hamiltonians with random interactions. This method is found to be applicable to all cases that have been discussed: even and odd fermion systems (both in single-j and many-j shells), and boson (both sd and sdg) systems. A simple relation for the highest angular momentum g.s. probability is found. Furthermore, it is suggested for the first time that the 0 g.s. dominance in boson systems and in even-fermion systems is given by two-body interactions with specific features.