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Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Classical model of intermediate statistics

G. Kaniadakis

Published Jun 1, 1994• 13 citations
Publisher

Abstract

In this work we present a classical kinetic model of intermediate statistics. In the case of Brownian particles we show that the Fermi-Dirac (FD) and Bose-Einstein (BE) distributions can be obtained, just as the Maxwell-Boltzmann (MB) distribution, as steady states of a classical kinetic equation that intrinsically takes into account an exclusion-inclusion principle. In our model the intermediate statistics are obtained as steady states of a system of coupled nonlinear kinetic equations, where the coupling constants are the transmutational potentials ${\mathrm{\ensuremath{\eta}}}_{\mathrm{\ensuremath{\kappa}}\mathrm{\ensuremath{\kappa}}\ensuremath{'}}$. We show that, besides the FD-BE intermediate statistics extensively studied from the quantum point of view, we can also study the MB-FD and MB-BE ones. Moreover, our model allows us to treat the three-state mixing FD-MB-BE intermediate statistics. For boson and fermion mixing in a D-dimensional space, we obtain a family of FD-BE intermediate statistics by varying the transmutational potential ${\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}$. This family contains, as a particular case, when ${\mathrm{\ensuremath{\eta}}}_{\mathrm{B}\mathrm{F}=0}$, the quantum statistics recently proposed by L. Wu, Z. Wu, and J. Sun [Phys. Lett. A 170, 280 (1992)]. When we consider the two-dimensional FD-BE statistics, we derive an analytic expression of the fraction of fermions. When the temperature T\ensuremath{\rightarrow}\ensuremath{\infty}, the system is composed by an equal number of bosons and fermions, regardless of the value of ${\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}$. On the contrary, when T\ensuremath{\rightarrow}0, ${\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}$ becomes important and, according to its value, the system can be completely bosonic or fermionic, or composed both by bosons and fermions.

DOI
10.1103/physreve.49.5111

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In this work we present a classical kinetic model of intermediate statistics. In the case of Brownian particles we show that the Fermi-Dirac (FD) and Bose-Einstein (BE) distributions can be obtained, just as the Maxwell-Boltzmann (MB) distribution, as steady states of a classical kinetic equation that intrinsically takes into account an exclusion-inclusion principle. In our model the intermediate statistics are obtained as steady states of a system of coupled nonlinear kinetic equations, where the coupling constants are the transmutational potentials \ensuremathη\ensuremathκ\ensuremathκ\ensuremath′{\mathrm{\ensuremath{\eta}}}_{\mathrm{\ensuremath{\kappa}}\mathrm{\ensuremath{\kappa}}\ensuremath{'}}\ensuremathη\ensuremathκ\ensuremathκ\ensuremath′​. We show that, besides the FD-BE intermediate statistics extensively studied from the quantum point of view, we can also study the MB-FD and MB-BE ones. Moreover, our model allows us to treat the three-state mixing FD-MB-BE intermediate statistics. For boson and fermion mixing in a D-dimensional space, we obtain a family of FD-BE intermediate statistics by varying the transmutational potential \ensuremathηBF{\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}\ensuremathηBF​. This family contains, as a particular case, when \ensuremathηBF=0{\mathrm{\ensuremath{\eta}}}_{\mathrm{B}\mathrm{F}=0}\ensuremathηBF=0​, the quantum statistics recently proposed by L. Wu, Z. Wu, and J. Sun [Phys. Lett. A 170, 280 (1992)]. When we consider the two-dimensional FD-BE statistics, we derive an analytic expression of the fraction of fermions. When the temperature T\ensuremath{\rightarrow}\ensuremath{\infty}, the system is composed by an equal number of bosons and fermions, regardless of the value of \ensuremathηBF{\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}\ensuremathηBF​. On the contrary, when T\ensuremath{\rightarrow}0, \ensuremathηBF{\mathrm{\ensuremath{\eta}}}_{\mathrm{BF}}\ensuremathηBF​ becomes important and, according to its value, the system can be completely bosonic or fermionic, or composed both by bosons and fermions.
In a previous work [Phys. Rev. E 48, 4263 (1993)] we have derived a nonlinear one-dimensional kinetic equation for the distribution function of particles obeying an exclusion principle. In the present work, on the same grounds, we extend this kinetics to D-dimensional continuous or discrete space, in order to study the distribution function of particles obeying a generalized exclusion-inclusion Pauli principle (EIP). This exclusion or inclusion principle is introduced into the classical transition rates by means of an inhibition or an enhancement factor, which contains a parameter \ensuremath{\kappa}, whose values range between -1 and +1 and can balance the effect of the full or partial validity of EIP. After deriving the kinetic equation we obtain a general expression of the stationary distribution function, depending on the value we give to the parameter \ensuremath{\kappa}. When we limit ourselves to Brownian particles, we derive exactly for \ensuremath{\kappa}=-1 the Fermi-Dirac (FD) distribution, for \ensuremath{\kappa}=0 the Maxwell-Boltzmann distribution, and for \ensuremath{\kappa}=1 the Bose-Einstein (BE) distribution. When \ensuremath{\kappa} assumes an intermediate value, except zero, between the extreme values -1 and +1, we obtain statistical distributions different from the FD and BE ones. We attribute to the parameter \ensuremath{\kappa} the meaning of the degree of indistinguishability of identical particles, the degree of antisymmetrization, or the symmetrization of the wave function of the particle system.
The reply by Sands & Dunning-Davies [3] to my paper [1] is acknowledged concerning the distribution functions. Keywords: Maxwell-Boltzmann distribution, Bose-Einstein distribution, classical ensembles, state functions In my paper ‘Are there physical systems obeying the Maxwell-Boltzmann statistics?’[1] I have written down the well-known probabilities of the 4 possible results of one fair toss of 2 fair coins according to the Maxwell-Boltzmann (MB), Bose-Einstein (BE) and Fermi-Dirac (FD) statistics. The two results coin 1 = head, coin 2 = tail and coin 2 = head, coin 1 = tail are counting as different in MB and as one and the same in BE and in FD. Then, I have quoted Gibbs [2], that the interchange of two © 2011 C. Roy Keys Inc. — http://redshift.vif.comApeiron, Vol. 18, No. 1, January 2011 16
In a previous note (1) we argued that for a wavefunction W(x,t)= Sum over n an exp(iEnt) Wn(x), the entropy for a particle in a box with infinite potential walls from (2) is: S/(-k)= Sum over n |anan| ln |anan| ((1)) and should be modified to: S/(-k)= Sum over n |anan| ln|anan| + |anan| Sp(n,L) + |anan| Sx(L) ((2)) where Sp and Sx are the pure state momentum and spatial entropies i.e Sp/-k = Integral dp an(p)an(p) ln|an(p)an(p)| and Sx/(-k) = Integral dx W*n(x)Wn(x) ln[Wn*Wn|. In (2) the Clausius relationship: dQ/T = dS is used where dQ = Sum over n En d|anan| and T is temperature to find an expression for |anan|. In general this would be: |anan| = exp(-En/T) , but with ((2)) we find: |anan| = exp(-En/kT) exp(-1-B(n)) ((3)) where B(n)= Sp(n)+Sx. L portions form Sp and Sx cancel so there is no L dependence, L being the size of the box. Given the different form ((3)) we suggest that the Fermi-Dirac (FD) and Bose-Einstein (BE) distributions may change if one uses the grand partition function approach. For example, exp(-ni ei/kT) is replaced by: exp(-ni ei/kT) exp(-ni(1+B(n)). This leads to changes in the FD and BD distributions: zexp(-Ei/kT)exp(-1-B(i) / [1 +/- exp(-u/kT) exp(-ei/kT) exp(-1-B(i))] where z=exp(u/kT), u being the chemical potential. In the high n limit B(n)--> constant (3) so the Maxwell-Boltzmann (MB) distribution remains unchanged. The MB distribution has been verified to high precision and so modifications related to 1+B(n) might have been noticed had B(n) remained a function of n.
This chapter reviews the techniques of the grand canonical ensemble to give an exact treatment for both Bose and Fermi particles. It looks at the results of Maxwell-Boltzmann statistics for the average number of particles in sufficiently high temperatures and in a single-particle state for both fermions and bosons. It also examines the exclusion principle in Fermi particles, which means that there cannot be two particles in the same single-particle state, while there is no such restriction for Bose particles. The chapter clarifies that the resulting formulae for the average number of particles in a single-particle state are different at low temperatures. It describes Fermi particles at low temperatures that have a large kinetic energy, an energy which can be much larger than the interaction between particles.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed