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Journal of Physics A Mathematical and General

Relations between Cartesian and spherical components of irreducible Cartesian tensors

J -M Normand, Jacques Raynal

Published May 1, 1982• 22 citations
Publisher

Abstract

Explicit formulae that relate Cartesian and spheric components of irreducible Cartesian tensors are derived. For the description of spin-s particles, explicit formulae for the Cartesian tensors and the spherical tensors are given in terms of symmetrised products of spin operators.
DOI
10.1088/0305-4470/15/5/008

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We develop a systematic approach to deriving addition theorems for, and some other bilocal sums of, spin spherical harmonics. In this first part we establish some necessary technical results. We discuss the factorization of orbital and spin degrees of freedom in certain products of Clebsch-Gordan coefficients, and obtain general explicit results for the matrix elements in configuration space of tensor products of arbitrary rank of the position and angular-momentum operators. These results are the basis of the addition theorems for spin spherical harmonics obtained in part II.
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A geometric theory of the irreducible tensor operators of quantum spin systems. It is based upon the Maxwell-Sylvester geometric representation of the multipolar electrostatic potential. In the latter, an order-ℓ\ellℓ multipolar potential is represented by a collection of ℓ\ellℓ equal length vectors, i.e. by ℓ\ellℓ points on a sphere, instead of by its components on some fixed (but arbitrary) basis. The geometric representation offers a much more appropriate tool for getting physical insight on specific characteristics of a multipole, such as its symmetries, or its departure from ideal symmetry. We derive explicit expressions enabling to perform any calculations we may need to perform on multipoles. All relevant quantities are eventually expressed in terms of scalar products of pairs of vectors (i.e., in terms of geometric quantities such as lengths and angles). The whole formalism is entirely independent of any particular choice of coordinate, and needs no use of the somehow abstract formalism traditionally used when dealing with angular momenta. The formalism is then applied to treat the problem of the irreducible tensor operators of quantum spin systems. It enables to completely dispense with the calculation and use of the Stevens operators, which can be quite complicated even for moderate values of ℓ\ellℓ. Explicit expressions for the calculation of expectations values of physical observables are derived. They essentially consist in combinations of scalar products of vector pairs. Together with the coherent state representation of the quantum states of spin systems, this provides a complete geometric, coordinate-free, description of the states, dynamics and physical properties of these systems.