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Progress of Theoretical Physics

Adiabatic Viewpoint for the WKB Treatment of Coupled Channel System: Appearance of the Berry Phase and Another Extra Phase Accompanying the Adiabatic Motion

Kazuhiro Yabana, H. Horiuchi

Published Mar 1, 1986• 20 citations
Publisher
DOI
10.1143/ptp.75.592

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In the WKB approximation for coupled channel equations, it has been pointed out by Yabana and Horiuchi that the semi-classical quantization condition should be modified by Berry's phase and another extra phase. Recently Littlejohn and Flynn have rederived them in a quite elegant way. We concentrate on this extra phase in this paper, and derive it for a simple model by means of the path integral method in the generalized coherent state representation. It is shown that it appears as a quantum fluctuation around classical orbits.
A quasi-static, WKB-type treatment accounts well for the surprising phase jumps that are odd multiples of π, (1 + 2 n )π, found as a molecular system journeys adiabatically in a configuration coordinate plane that contains several points of degeneracies. We show that the number n in the phase jump is an integer close to | n '| that appears in the expression for the complex wavefunction amplitude valid (approximately) for times close to when the phase jump occurs: (δ T is a shifted and rescaled trajectory-time parameter and θ is a numerical fraction (<1) which depends on the adiabaticity of the motion.) The central quantity n ' is local, i.e., depends on the values of the parameters in the Hamiltonian only at the beginning of the trajectory and at the instant of the phase jump.