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Journal of Mathematical Physics

Biorthonormal eigenbasis of a Markovian master equation for the quantum Brownian motion

Buang Ann Tay, Tomio Yamakoshi Petrosky

Published Nov 1, 2008• 17 citations
Publisher

Abstract

The solution to a quantum Markovian master equation of a harmonic oscillator weakly coupled to a thermal reservoir is investigated as a non-Hermitian eigenvalue problem in space coordinates. In terms of a pair of quantum action-angle variables, the equation becomes separable and a complete set of biorthogonal eigenfunctions can be constructed. Properties of quantum states, such as the change in the quantum coherence length, damping in the motion, and disappearance of the spatial interference pattern, can then be described as the decay of the nonequilibrium modes in the eigenbasis expansion. It is found that the process of gaining quantum coherence from the environment takes a longer time than the opposite process of losing quantum coherence to the environment. An estimate of the time scales of these processes is obtained.

DOI
10.1063/1.3005968

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The solution to a quantum Markovian master equation of a harmonic oscillator weakly coupled to a thermal reservoir is investigated as a non-Hermitian eigenvalue problem in space coordinates. In terms of a pair of quantum action-angle variables, the equation becomes separable and a complete set of biorthogonal eigenfunctions can be constructed. Properties of quantum states, such as the change in the quantum coherence length, damping in the motion, and disappearance of the spatial interference pattern, can then be described as the decay of the nonequilibrium modes in the eigenbasis expansion. It is found that the process of gaining quantum coherence from the environment takes a longer time than the opposite process of losing quantum coherence to the environment. An estimate of the time scales of these processes is obtained.
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The eigenvalue problem of Kossakowski-Linblad’s kinetic equation associated with the reduced density matrix of a harmonic oscillator interacting with a thermal bath in equilibrium is solved. The solution gives rise to a complete orthogonal eigenbasis endowed with Hilbert space structure that has a weighted norm. We find that the eigenfunctions at finite temperature can be obtained from the eigenfunction at zero temperature through a hyperbolic rotation on the position variables. This transformation enables the extension of the simple harmonic oscillator density matrix to that of a finite temperature. We further investigate the decay of these extended states under our dissipative kinetic equation. Furthermore, the Hilbert space structure enables the proof of a H-theorem in this system. We apply the eigenbasis expansion of an initial state to analyze decohorence as well as coherence processes. We find that coherence process occurs at a longer time scale compared to decoherence process. The time scales of both processes are estimated with the eigenbasis expansion. In the same way we analyze the evolution of the coherent state. We show that in addition to the ordinary decay time, we found another time scale which is defined by the time when the motion of the peak of the coherent state become comparative to the width of the coherent state. In contrast to the ordinary decay time this new relaxation time depends on the initial value of the momentum of the oscillator. We also find that our eigenbasis is applicable to a class of non-linear interactions, with a slight extension of the form of transport coefficients due to the non-linear interactions.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
Quantum Brownian motion is the random motion of quantum particles suspended in a field (or an effective field) resulting from their collision with fast-moving modes in the field. It provides us with a fundamental model to understand various physical features concerning open systems in chemistry, condensed-matter physics, biophysics, and optomechanics. In this paper, without either the Born-Markovian or rotating-wave approximation, we derive a master equation for a charged-Brownian particle in one dimension coupled with a thermal reservoir in electric fields. The effect of the reservoir and the electric fields is manifested as time-dependent coefficients and coherent terms, respectively, in the master equation. The two-photon correlation between the Brownian particle and the reservoir can induce nontrivial squeezing dynamics to the particle. We derive a current equation including the source from the driving fields, transient current from the system flowing into the environment, and the two-photon current caused by the non-rotating-wave term. The presented results then are compared with that given by the rotating-wave approximation in the weak-coupling limit, and these results are extended to a more general quantum network involving an arbitrary number of coupled-Brownian particles. The presented formalism might open a way to better understand exactly the non-Markovian quantum network.
We develop a non-Markovian extension to the caldeira-leggett master equation for quantum Brownian motion by using the timescale of the bath as a small parameter around which to perform a perturbative expansion. This framework allows us to deal directly with the time non-locality of the non-Markovian regime. We derive an exact description of the evolution of the reduced density matrix and obtain a new quantum master equa- tion with non-Markovian corrections added perturbatively to the standard Lindblad form. The resulting simulations show new dynamics and a strong deviation from Markovian behaviour. We observe that quantum coherences survive far longer than in the Marko- vian limit. In particular, when the system is fully non-Markovian, quantum phenomena experience a form of decoherence that behaves functionally like an inverse-power law. These results may have important implications in quantum technologies and biology as they suggest environments can be engineered to support long-lived quantum coherence.