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Journal of Mathematical Physics

Equilibrium states for the infinite ideal Bose gas

R. P. Moya

Published Jan 1, 1975• 3 citations
Publisher

Abstract

We construct a set of equilibrium states for the ideal Bose gas at temperature β−1 and chemical potential μ. Our choice for the equilibrium states is based on the Kubo−Martin−Schwinger conditions. In particular, we define ℰβ,μ to be the set of states which satisfy the KMS conditions suitably defined. In the condensed phase a certain subset Δβ,μ of ℰβ,μ correspond to states whose mean local densities are not uniformly bounded with respect to the volume. We, therefore, propose that ℰβ,μ Δβ,μ ≡ ?β,μ corresponds to the set of equilibrium states. Then it is shown that ?β,μ contains, as special cases, the equilibrium states obtained via thermodynamical limit arguments by Araki−Woods and Lewis−Pulé. The extremal elements of the convex set ℰβ,μ are obtained explicitly.

DOI
10.1063/1.522392

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•Dec 9, 2025•0 citations
We construct a set of equilibrium states for the ideal Bose gas at temperature β−1 and chemical potential μ. Our choice for the equilibrium states is based on the Kubo−Martin−Schwinger conditions. In particular, we define ℰβ,μ to be the set of states which satisfy the KMS conditions suitably defined. In the condensed phase a certain subset Δβ,μ of ℰβ,μ correspond to states whose mean local densities are not uniformly bounded with respect to the volume. We, therefore, propose that ℰβ,μ Δβ,μ ≡ ?β,μ corresponds to the set of equilibrium states. Then it is shown that ?β,μ contains, as special cases, the equilibrium states obtained via thermodynamical limit arguments by Araki−Woods and Lewis−Pulé. The extremal elements of the convex set ℰβ,μ are obtained explicitly.
In this paper, first of all, we proved if the ideal Bose gas with a finite volume and number of particles has a non-degenerate single-particle energy level n, the chemical potential μ can take the value μn = n and there is a phase transition temperature Tp,n, where n = 0,1,2 Taking 0 ≤ n Tp,n+1. When the temperature T > Tp,n or T ≤ Tp,n+1, μ # n and the most probable occupation number Nn = 0. In the temperature interval Tp,n ≥ T > Tp,n+1, μ = n and 0 ≤ Nn = N - NjsupNn, where Nj is the most probable occupation number in the degenerate level j. Thus, if the finite ideal Bose gas has some non-degenerate single-particle levels, there exists a characteristic temperature Tp = Tp,0. The chemical potential μ is quantized when T ≤ Tp, and this leads to the creation of a macroscopic quantum state (pure state) or Bose-Einstein condensation phase. Tp = Tp,0 is a first-order phase transition point, Tp,n#0 is a zero-order phase transition point. Next, we obtained a new expression of the most probable distribution of the finite ideal Bose gas. In this expression Nj is directly proportional to gj - 1, where gj and Nj are, respectively, the degeneracy and the most probable occupation number in the degenerate level j. This property agrees with what chemical potential can be quantized if there is a non-degenerate level for the finite ideal Bose gas. Finally, using this expression, we defined a micro-partition function M, obtained the statistical expressions of some thermodynamical quantities.
Calculations of chemical potentials for ideal monatomic gases with Bose-Einstein and Fermi-Dirac statistics as functions of temperature, across the temperature region that is typical for the collective quantum degeneracy effect, are presented. Numerical calculations are performed without any additional approximations, and explicit dependences of the chemical potentials on temperature are constructed at a fixed density of gas particles. Approximate polynomial dependences of chemical potentials on temperature are obtained that allow for the results to be used in further studies without re-applying the involved numerical methods. The ease of using the obtained representations is demonstrated on examples of deformation of distribution for a population of energy states at low temperatures, and on the impact of quantum statistics (exchange interaction) on the equations of state for ideal gases and some of the thermodynamic properties thereof. The results of this study essentially unify two opposite limiting cases in an intermediate region that are used to describe the equilibrium states of ideal gases, which are well known from university courses on statistical physics, thus adding value from an educational point of view.
The generating functional of the cyclic representation of the canonical commutation relations (CCR) representation for the thermodynamic limit of the grand canonical ensemble of the free Bose gas with attractive boundary conditions is rigorously computed. We use it to study the condensate localization as a function of the homothety point for the thermodynamic limit using a sequence of growing convex containers. The Kac function is explicitly obtained proving nonequivalence of ensembles in the condensate region in spite of the condensate density being zero locally.
In the paper4 the notion of local KMS condition, introduced in Ref. 3 and extended in Ref. 2, was shown to open new possibilities in the study of the problem of Bose–Einstein Condensation (BEC). In this paper we analyze the general structure of states on the CCR algebra over a pre-Hilbert space that satisfies the local KMS condition with respect to a free Hamiltonian [Formula: see text] and to a given inverse temperature function [Formula: see text]. The replacement of Hilbert space by a pre-Hilbert space allows one to deal with test functions more singular than those usually considered in the theory of distributions (thus allowing e.g., fractal critical surfaces) and is equivalent (in the language of Weyl algebras) to consider a degenerate symplectic form. It is precisely this degeneracy that allows one to introduce in an intrinsic way the notions of [Formula: see text]-critical subspace (resp. [Formula: see text]-critical surface) and of states exhibiting BEC, independently of infinite volume limits and of boundary conditions. We prove that the covariance of any local KMS state is uniquely determined by the pair [Formula: see text], through a nonlinear extension of the Planck factor. For a large class of such states (including all known examples) the covariance splits into a sum of two mutually singular terms: one corresponding to a regular state, the other one with support on a critical surface (or more generally a critical subspace) uniquely determined by [Formula: see text] and [Formula: see text]. In particular we prove that, if such a state is gauge invariant Gaussian (quasi-free), then the [Formula: see text]-equilibrium condition uniquely determines the regular part of the state, while the singular part is arbitrary.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2L^2L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01\textit{Full-text embargoed until: 2026-01-01}Full-text embargoed until: 2026-01-01