As a consequence of the Heisenberg uncertainty any quantum physics system inescapably undergoes relaxation towards thermal equilibrium, thus towards maximum entropy. The non-dissipative states have probability measure zero and cannot exist in nature. The impact these results have on chaotic behavior of quantum systems will be discussed, as well as the difference between quantum and classical systems, which have vanishing uncertainty.
As a consequence of the Heisenberg uncertainty any quantum physics system inescapably undergoes relaxation towards thermal equilibrium, thus towards maximum entropy. The non-dissipative states have probability measure zero and cannot exist in nature. The impact these results have on chaotic behavior of quantum systems will be discussed, as well as the difference between quantum and classical systems, which have vanishing uncertainty.
A compact description of the evolution of a many-body quantum system, e.g., a dilute gas, is provided by the generalization of the usual reaction U matrix to a system U matrix. Using this tool, it is demonstrated that in such systems (i) time-reversal-invariant states are unstable and cannot exist in nature or be ``constructed in the laboratory;'' (ii) the time-reversal invariance of the Hamiltonian leads inexorably to relaxation towards thermal equilibrium of arbitrary nonequilibrium states, i.e., to dissipation, which thus allows the definition of a quantum arrow of time; (iii) the second law of thermodynamics, and hence the complete field of thermodynamics, is a consequence of quantum physics. These results have at their basis the hermiticity of the Hamiltonian and the Heisenberg uncertainty relations.
This work proposes a conceptual and ontological reformulation of classical dynamics, thermodynamics, and quantum mechanics based on a single postulate: dissipation is a fundamental property of all physical processes. Traditional dynamics relies on the idealization of isolated, reversible systems, yet no real physical system satisfies such conditions. By introducing an intrinsic dissipative energy term into the equations of motion, we suggest that dissipation entails an irreversible loss of physical information, from which a classical uncertainty principle naturally follows. Stationary states are reinterpreted as zero‑dissipation configurations, lacking internal temporal evolution, thereby offering an ontological basis for quantization, non‑locality, and the Heisenberg uncertainty principle. Quantum mechanics can thus be viewed as the mathematical description of these stationary states and of the dissipative transitions connecting them. The framework is conceptually consistent with fluctuation‑dissipation theory, open‑system quantum dynamics, decoherence theory, and relaxation phenomena in NMR spectroscopy. Several experimental proposals are outlined to discriminate this ontological model from both classical mechanics and standard quantum mechanics.
We consider the temporal evolution of an isolated system of particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to the unexpected result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, which could not irreversibly change from S′ to S max by entropy production P > 0. This contradicts the second law of thermodynamics. The paradoxial result can be traced back to the Liouville theorem. To overcome this difficulty, we introduce the t–P space. The time t and the entropy production P are observables in quantum thermodynamics. They are defined by the eigenvalue equations t|t〉 = t|t〉 and P|P〉 = P|P〉. The operators t and P do not commute. We have a non-vanishing commutator, [t,P] = ik, and consequently a t–P uncertainty relation, ΔtΔP ≥ k/2. The Boltzmann constant k is characteristic of quantum thermodynamics and represents the atomic entropy unit. — The time evolution operator U(τ) = exp[−(i/k)τP] shifts the time t by τ, U(τ)|t〉 = |t + τ〉. The generator of τ is the operator P of entropy production. Then the eigenvector |P〉 is also an eigenket of U(t), and it follows with progressing time τ ≥ 0 that τP ≥ 0 and hence P = dS/dt ≥ 0. This is the second law of thermodynamics, which is correctly reproduced in quantum thermodynamics. — Exchanging −τ for +τ replaces the equations of forward time +τ by the equations of backward time −τ. Independent of the direction of the arrow of time, the entropy of the system always increases or remains constant in the limit of the equilibrium state, dS ≥ 0. This is characteristic of irreversibility, for the system does not return to its initial state on time reversal. — The t–P uncertainty relation allows to discuss the temporal evolution of the expectation value 〈P〉 of entropy production and the lifetime Δt of the transient states, the system passes through on approaching the equilibrium state. In case of a non-equilibrium state 〈P〉, ΔP, and Δt are finite. On approaching the equilibrium state, 〈P〉 and ΔP decrease, consequently Δt increases. Finally, in the case of equilibrium (eq), we have 〈P〉eq = 0, ΔP eq = 0, and Δt eq → ∞. The lifetime of the equilibrium state is unlimited, because the entropy production 〈P〉 and the uncertainty of entropy production ΔP exactly vanish. The temporal evolution of the system can be described by means of a phenomenological equation.
Understanding the far-from-equilibrium dynamics of dissipative quantum systems, where dissipation and decoherence coexist with unitary dynamics, is an enormous challenge with immense rewards. Often, the only realistic approach is to forgo a detailed microscopic description and search for signatures of universal behavior shared by collections of many distinct, yet sufficiently similar, complex systems. Quantum chaos provides a powerful statistical framework for addressing this question, relying on symmetries to obtain information not accessible otherwise. This thesis examines how to reconcile chaos with dissipation, proceeding along two complementary lines. In Part I, we apply non-Hermitian random matrix theory to open quantum systems with Markovian dissipation and discuss the relaxation timescales and steady states of three representative examples of increasing physical relevance: single-particle Lindbladians and Kraus maps, open free fermions, and dissipative Sachdev-Ye-Kitaev (SYK) models. In Part II, we investigate the symmetries, correlations, and universality of many-body open quantum systems, classifying several models of dissipative quantum matter. From a theoretical viewpoint, this thesis lays out a generic framework for the study of the universal properties of realistic, chaotic, and dissipative quantum systems. From a practical viewpoint, it provides the concrete building blocks of dynamical dissipative evolution constrained by symmetry, with potential technological impact on the fabrication of complex quantum structures. (Full abstract in the thesis.)
Abstract We consider the temporal evolution of an isolated system of N particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy, S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to dS/dt = 0: The entropy S does not change in time t. Thereby it is irrelevant, whether we consider a non-equilibrium state or an equilibrium state. Consequently, the system cannot irreversibly change by entropy production dS/dt > 0 from S′ to S max. This is a paradoxial result, which contradicts the experience. It can be traced back to the von Neumann equation, which in principle describes reversible processes and hence is unsuitable for calculating the irreversible evolution of the entropy S in time t. Each irreversible process is accompanied by a positive entropy production P = dS/dt ≥ 0 inside the system, which only vanishes in case of the equilibrium state. In order to overcome the above mentioned difficulties, we assign an operator P to the entropy production P, which is defined by the eigenvalue equation P |u〉 = P|u〉 with the state vector |u〉 of the N-particle system. There was an extensive discussion about the relation between the production of entropy P on one hand and the progression of time t on the other. Making use of this concept, we combine the operator of entropy production P with the time-development operator U (t, t 0) of the system and finally deduce the infinitesimal unitary operator U (t+τ,t) = 1 + (i/k)τ P by means of very general assumptions. Here P means the generator of the infinitesimal progression of time τ = t − t 0 and k the Boltzmann constant, representing the atomic entropy unit. Similarly to P we also treat the time t as an observable, defined by t |u〉 = t|u〉. We apply the infinitesimal time-evolution operator U (t+τ,t) to the operator of time t and finally obtain the P – t commutation relation i[ P , t ] = k, which is independent of τ. It shows that the operators P and t do not commute, and hence P and t are not sharply defined simultaneously. Instead we have uncertainties ΔP and Δt on measuring P and t, which are given by the P–t uncertainty relation ΔPΔt ≥ k/2. It readily allows a discussion of the evolution of the entropy S of the isolated system in time t from S′ to S max. Now, the irreversible steps are correctly described by the entropy production P = dS/dt > 0, while the thermal equilibrium is given by P = 0, ΔP = 0, and thus the lifetime of the equilibrium state Δt = ∞. According to the P–t uncertainty relation, the Boltzmann constant k is similarly important to the quantum thermodynamics of irreversible processes like Planck′s constant h to usual quantum mechanics.
In classical statistical mechanics there is a clear correlation between relaxation to equilibrium and chaos. In contrast, for isolated quantum systems this relation is--to say the least--fuzzy. In this work we try to unveil the intricate relation between the relaxation process and the transition from integrability to chaos. We study the approach to equilibrium in two different many-body quantum systems that can be parametrically tuned from regular to chaotic. We show that a universal relation between relaxation and delocalization of the initial state in the perturbed basis can be established regardless of the chaotic nature of system.